English
往期目录
新闻公告
More
化学进展 2011, Vol. 23 Issue (9): 1929-1935 前一篇   后一篇

• 综述与评论 •

有机染料及其在染料敏化太阳电池中的应用

武国华, 孔凡太, 翁坚, 戴松元*, 奚小网, 张昌能   

  1. 中国科学院新型薄膜太阳电池重点实验室 中国科学院等离子体物理研究所 合肥 230031
  • 收稿日期:2010-11-01 修回日期:2011-01-01 出版日期:2011-09-24 发布日期:2011-09-02
  • 通讯作者: 戴松元 E-mail:sydai@ipp.ac.cn
  • 基金资助:

    国家重点基础研究发展计划(973)项目(No.2011CBA00700)、国家自然科学基金项目(No.21003130)和安徽省自然科学基金项目(No.090414174)资助。

下载PDF ( 1651 ) 引用
导出 被引次数 ( 19 | 3 )

Organic Dye Sensitizers and Their Application in Dye-Sensitized Solar Cell

Wu Guohua, Kong Fantai, Weng Jian, Dai Songyuan*, Xi Xiaowang, Zhang Changneng   

  1. Key Laboratory of Novel Thin Film Solar Cells, Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031, China
  • Received:2010-11-01 Revised:2011-01-01 Online:2011-09-24 Published:2011-09-02

在染料敏化太阳电池中,染料敏化剂分成无机染料与有机染料两大类。无机染料受稀有金属钌的制约而成本较高,开发有机染料是降低染料敏化太阳电池成本的有效手段,成为目前研究的热点。本文从有机染料敏化剂的分子设计入手,简述了染料敏化太阳电池中有机染料敏化剂的基本结构,将有机染料敏化剂分为吲哚啉类染料、香豆素类染料、三苯胺类染料、菁类染料、方酸类染料、二烷基苯胺类染料、咔唑类染料、芴类染料、二萘嵌苯类染料、四氢喹啉类染料、卟啉类染料及酞菁类染料等,详细评述了这些有机染料敏化剂及多种染料协同敏化的最新研究进展,并对有机染料的发展前景进行了展望。

关键词： 有机染料, 染料敏化, 敏化剂, 协同敏化, 太阳电池

In dye-sensitized solar cell (DSC), dye sensitizer is the key for the light harvesting in the visible light region, whose performance determines the efficiency of DSC to some extent. Up to now, two kinds of dyes, namely inorganic dyes and organic dyes, have been widely investigated as sensitizers of DSC. In this paper, the basic molecular structures as well as the molecular design for organic dyes are introduced. Organic dyes are divided into indoline dyes, coumarin dyes, triphenylamine dyes and other organic dyes. The newest research progress of these organic dyes and the co-sensitization of different dyes is reviewed in details. The forecast to the future developments of organic dye sensitizers is also discussed.

Contents
1 Introducation
2 Basic molecular structure of organic dye sensitizers and their molecular design
3 Developing progress of organic dye sensitizers
3.1 Indoline dyes
3.2 Coumarin dyes
3.3 Triphenylamine dyes
3.4 Other organic dyes
4 Co-sensitization of different dyes
5 Conclusions and outlook

Key words: organic dye, dye-sensitize, sensitizer, co-sensitization, solar cells

中图分类号: 

()

[1] Oregan B, Grätzel M.Nature, 1991, 353 (6346): 737-740
[2] 郭磊(Guo L), 潘旭(Pan X), 戴松元(Dai S Y).化学进展(Progress in Chemistry), 2008, 20(10): 1595-1605
[3] 朱俊(Zhu J), 戴松元(Dai S Y), 张耀红(Zhang Y H).化学进展(Progress in Chemistry), 2010, 22(5): 822-828
[4] 梁茂(Liang M), 陶占良(Tao Z L), 陈军(Chen J).化学通报(Chemistry), 2005, (12): 889-896
[5] Nazeeruddin M K, De Angelis F, Fantacci S, Selloni A, Viscardi G, Liska P, Ito S, Takeru B, Grätzel M.J.Am.Chem.Soc., 2005, 127 (48): 16835-16847
[6] Chiba Y, Islam A, Watanabe Y, Komiya R, Koide N, Han L Y.Jpn.J.Appl.Phys., Part 2, 2006, 45(25): L638-L640
[7] Gao F, Wang Y, Shi D, Zhang J, Wang M, Jing X, Humphry-Baker R, Wang P, Zakeeruddin S M, Grätzel M.J.Am.Chem.Soc., 2008, 130 (32): 10720-10728
[8] Ferrere S, Zaban A, Gregg B A.J.Phys.Chem.B, 1997, 101 (23): 4490-4493
[9] Hara K, Horiguchi T, Kinoshita T, Sayama K, Sugihara H, Arakawa H.Sol.Energy Mater.Sol.Cells, 2000, 64 (2): 115-134
[10] 孔凡太(Kong F T), 戴松元(Dai S Y).化学进展(Progress in Chemistry), 2006, (11): 1409-1424
[11] Kim S, Lee J K, Kang S O, Ko J, Yum J H, Fantacci S, Angelis F D, Censo D D, Nazeeruddin M K, Grätzel M.J.Am.Chem.Soc., 2006, 128 (51): 16701-16707
[12] 郑冰(Zheng B), 牛海军(Niu H J), 白续铎(Bai X D).化学进展(Progress in Chemistry), 2008, 20(6): 828-840
[13] 宋晓睿(Song X R), 王雪松(Wang X S), 张宝文(Zhang B W).化学进展(Progress in Chemistry), 2008, 20(10): 1524-1533
[14] Thomas K R J, Lin J T, Hsu Y C, Ho K C.Chem.Commun., 2005, 4098-4100
[15] Robertson N.Angew.Chem.Int.Ed., 2006, 45(15): 2338-2345
[16] Mishra A, Fischer Markus K R, Bäuerle P.Angew.Chem.Int.Ed., 2009, 48 (14): 2474-2499
[17] Zeng W, Cao Y, Bai Y, Wang Y, Shi Y, Zhang M, Wang F, Pan C, Wang P.Chem.Mater., 2010, 22 (5): 1915-1925
[18] Horiuchi T, Miura H, Uchida S.Chem.Commun., 2003, 3036-3037
[19] Schmidt-Mende L, Bach U, Humphry-Baker R, Horiuchi T, Miura H, Ito S, Uchida S, Grätzel M.Adv.Mater., 2005, 17 (7): 813-815
[20] Horiuchi T, Miura H, Sumioka K, Uchida S.J.Am.Chem.Soc., 2004, 126 (39): 12218-12219
[21] Ito S, Zakeeruddin S M, Humphry-Baker R, Liska P, Charvet R, Comte P, Nazeeruddin M K, Péchy P, Takata M, Miura H, Uchida S, Grätzel M.Adv.Mater., 2006, 18 (9): 1202-1205
[22] Ito S, Miura H, Uchida S, Takata M, Sumioka K, Liska P, Comte P, Pechy P, Grätzel M.Chem.Commun., 2008, 5194-5196
[23] Kuang D, Uchida S, Humphry-Baker R, Zakeeruddin Shaik M, Grätzel M.Angew.Chem.Int.Ed., 2008, 47(10): 1923-1927
[24] Howie W H, Claeyssens F, Miura H, Peter L M.J.Am.Chem.Soc., 2008, 130 (4): 1367-1375
[25] Hara K, Sayama K, Arakawa H, Ohga Y, Shinpo A, Suga S.Chem.Commun., 2001, 569-570
[26] Hara K, Sato T, Katoh R, Furube A, Ohga Y, Shinpo A, Suga S, Sayama K, Sugihara H, Arakawa H.J.Phys.Chem.B, 2003, 107 (2): 597-606
[27] Hara K, Tachibana Y, Ohga Y, Shinpo A, Suga S, Sayama K, Sugihara H, Arakawa H.Sol.Energy Mater.Sol.Cells, 2003, 77 (1): 89-103
[28] Hara K, Kurashige M, Dan-oh Y, Kasada C, Shinpo A, Suga S, Sayama K, Arakawa H.New J.Chem., 2003, 27 (5): 783-785
[29] Wang Z-S, Hara K, Dan-oh Y, Kasada C, Shinpo A, Suga S, Arakawa H, Sugihara H.J.Phys.Chem.B, 2005, 109 (9): 3907-3914
[30] Hara K, Wang Z-S, Sato T, Furube A, Katoh R, Sugihara H, Dan-oh Y, Kasada C, Shinpo A, Suga S.J.Phys.Chem.B, 2005, 109 (32): 15476-15482
[31] Koops S E, Barnes P R F, O'Regan B C, Durrant J R.J.Phys.Chem.C, 2010, 114 (17): 8054-8061
[32] Wang Z-S, Cui Y, Dan-oh Y, Kasada C, Shinpo A, Hara K.J.Phys.Chem.C, 2007, 111 (19): 7224-7230
[33] Wang Z-S, Cui Y, Dan-oh Y, Kasada C, Shinpo A, Hara K.J.Phys.Chem.C, 2008, 112 (43): 17011-17017
[34] Wang Z-S, Cui Y, Hara K, Dan-oh Y, Kasada C, Shinpo A.Adv.Mater., 2007, 19 (8): 1138-1141
[35] Sayama K, Tsukagoshi S, Hara K, Ohga Y, Shinpou A, Abe Y, Suga S, Arakawa H.J.Phys.Chem.B, 2002, 106 (6): 1363-1371
[36] Velusamy M, Justin Thomas K R, Lin J T, Hsu Y-C, Ho K-C.Org.Lett., 2005, 7(10): 1899-1902
[37] Moon S-J, Yum J-H, Humphry-Baker R, Karlsson K M, Hagberg D P, Marinado T, Hagfeldt A, Sun L, Graätzel M, Nazeeruddin M K.J.Phys.Chem.C, 2009, 113 (38): 16816-16820
[38] Liang Y, Peng B, Liang J, Tao Z, J Chen.Org.Lett., 2010, 12 (6): 1204-1207
[39] Xu W, Peng B, Chen J, Liang M, Cai F.J.Phys.Chem.C, 2008, 112 (3): 874-880
[40] Kitamura T, Ikeda M, Shigaki K, Inoue T, Anderson N A, Ai X, Lian T, Yanagida S.Chem.Mater., 2004, 16 (9): 1806-1812
[41] Hagberg D P, Edvinsson T, Marinado T, Boschloo G, Hagfeldt A, Sun L.Chem.Commun., 2006, 2245-2247
[42] Hwang S, Lee J H, Park C, Lee H, Kim C, Park C, Lee M-H, Lee W, Park J, Kim K, Park N G, Kim C.Chem.Commun., 2007, 4887-4889
[43] Bonhote P, Moser J-E, Humphry-Baker R, Vlachopoulos N, Zakeeruddin S M, Walder L, Grätzel M.J.Am.Chem.Soc., 1999, 121: 1324-1336
[44] Li G, Jiang K J, Li Y F, Li S L, Yang L M.J.Phys.Chem.C, 2008, 112 (30): 11591-11599
[45] Yen Y-S, Hsu Y-C, Lin J T, Chang C W, Hsu C P, Yin D J.J.Phys.Chem.C, 2008, 112 (32): 12557-12567
[46] Shi D, Cao Y, Pootrakulchote N, Yi Z, Xu M, Zakeeruddin S M, Graätzel M, Wang P.J.Phys.Chem.C, 2008, 112 (44): 17478-17485
[47] Xu M, Li R, Pootrakulchote N, Shi D, Guo J, Yi Z, Zakeeruddin S M, Graätzel M, Wang P.J.Phys.Chem.C, 2008, 112 (49): 19770-19776
[48] Li R, Lv X, Shi D, Zhou D, Cheng Y, Zhang G, Wang P.J.Phys.Chem.C, 2009, 113 (17): 7469-7479
[49] Zhang G, Bala H, Cheng Y, Shi D, Lv X, Yu Q, Wang P.Chem.Commun., 2009, 2198-2200
[50] Li R, Liu J, Cai N, Zhang M, Wang P.J.Phys.Chem.B, 2010, 114 (13): 4461-4464
[51] Liang M, Xu W, Cai F, Chen P, Peng B, Chen J, Li Z.J.Phys.Chem.C, 2007, 111 (11): 4465-4472
[52] 裴娟(Pei J), 梁茂(Liang M), 陈军(Chen J), 陶占良(Tao Z L), 许炜(Xu W).物理化学学报(Acta Phys.-Chim.Sin.), 2008, 24(11): 1950-1956
[53] Pei J, Peng S, Shi J, Liang Y, Tao Z, Liang J, Chen J.J.Power Sources, 2009, 187 (2): 620-626
[54] Shi J, Wang L, Liang Y, Peng S, Cheng F, Chen J.J.Phys.Chem.C, 2010, 114 (14): 6814-6821
[55] Tian H, Yang X, Chen R, Zhang R, Hagfeldt A, Sun L.J.Phys.Chem.C, 2008, 112 (29): 11023-11033
[56] Wiberg J, Marinado T, Hagberg D P, Sun L, Hagfeldt A, Albinsson B.J.Phys.Chem.C, 2009, 113 (9): 3881-3886
[57] Mikroyannidis J A, Suresh P, Roy M S, Sharma G D.J.Power Sources, 2010, 195 (9): 3002-3010
[58] Wang Z S, Li F Y, Huang C H.J.Phys.Chem.B, 2001, 105 (38): 9210-9217
[59] Sayama K, Hara K, Sugihara H, Arakawa H, Mori N, Satsuki M, Suga S, Tsukagoshi S, Abe Y.Chem.Commun., 2000, (13): 1173-1174
[60] Chen Y-S, Li C, Zeng Z H, Wang W B, Wang X-S, Zhang B-W.J.Mater.Chem., 2005, 15 (16): 1654-1661
[61] Alex S, Santhosh U, Das S.J.Photochem.Photobiol.A., 2005, 172 (1): 63-71
[62] Yum J-H, Walter P, Huber S, Rentsch D, Geiger T, Nüesch F, De Angelis F, Grätzel M, Nazeeruddin M K.J.Am.Chem.Soc., 2007, 129 (34): 10320-10321
[63] Kim S, Mor G K, Paulose M, Varghese O K, Baik C, Grimes C A.Langmuir, 2010, 26 (16): 13486-13492
[64] Hara K, Kurashige M, Ito S, Shinpo A, Suga S, Sayama K, Arakawa H.Chem.Commun., 2003, (2): 252-253
[65] Li S L, Jiang K J, Shao K F, Yang L M.Chem.Commun., 2006, (26): 2792-2794
[66] Koumura N, Wang Z-S, Mori S, Miyashita M, Suzuki E, Hara K.J.Am.Chem.Soc., 2006, 128 (44): 14256-14257
[67] Zhang X H, Wang Z S, Cui Y, Koumura N, Furube A, Hara K.J.Phys.Chem.C, 2009, 113 (30): 13409-13415
[68] Wang Z S, Koumura N, Cui Y, Miyashita M, Mori S, Hara K.Chem.Mater., 2009, 21 (13): 2810-2816
[69] Choi H, Lee J K, Song K, Kang S O, Ko J.Tetrahedron, 2007, 63 (15): 3115-3121
[70] Jung I, Lee J K, Song K H, Song K, Kang S O, Ko J.J.Org.Chem., 2007, 72 (10): 3652-3658
[71] Kim C, Choi H, Kim S, Baik C, Song K, Kang M-S, Kang S O, Ko J.J.Org.Chem., 2008, 73 (18): 7072-7079
[72] Choi H, Baik C, Kang S, Ko J, Kang M.S, Nazeeruddin M, Grätzel M.Angew.Chem.Int.Ed., 2008, 47 (2): 327-330
[73] Kim S, Kim D, Choi H, Kang M S, Song K, Kang S O, Ko J.Chem.Commun., 2008, 4951-4953
[74] Kim J-J, Choi H, Lee J-W, Kang M-S, Song K, Kang S O, Ko J.J.Mater.Chem., 2008, 18 (43): 5223-5229
[75] Xu M, Wenger S, Bala H, Shi D, Li R, Zhou Y, Zakeeruddin S M, Graätzel M, Wang P.J.Phys.Chem.C, 2009, 113 (7): 2966-2973
[76] Edvinsson T, Li C, Pschirer N, Schöneboom J, Eickemeyer F, Sens R, Boschloo G, Herrmann A, Müllen K, Hagfeldt A.J.Phys.Chem.C, 2007, 111 (42): 15137-15140
[77] Li C, Yum J H, Moon S J, Herrmann A, Eickemeyer F, Pschirer N, Erk P, Schöneboom J, Müllen K, Grätzel M, Nazeeruddin M.ChemSusChem, 2008, 1 (7): 615-618
[78] Chen R, Yang X, Tian H, Sun L.J.Photochem.Photobiol.A, 2007, 189 (2/3): 295-300
[79] Chen R, Yang X, Tian H, Wang X, Hagfeldt A, Sun L.Chem.Mater., 2007, 19 (16): 4007-4015
[80] Hao Y, Yang X, Cong J, Tian H, Hagfeldt A, Sun L.Chem.Commun., 2009, 4031-4033
[81] Cherian S, Wamser C C.J.Phys.Chem.B, 2000, 104 (15): 3624-3629
[82] Ma T L, Inoue K, Yao K, Noma H, Shuji T, Abe E, Yu J H, Wang X S, Zhang B W.J.Electroanal.Chem., 2002, 537 (1/2): 31-38
[83] Balanay M P, Dipaling C V P, Lee S H, Kim D H, Lee K H.Sol.Energy Mater.Sol.Cells, 2007, 91 (19): 1775-1781
[84] Wang Q, Carnpbell W M, Bonfantani E E, Jolley K W, Officer D L, Walsh P J, Gordon K, Humphry-Baker R, Nazeeruddin M K, Gratzel M, J.Phys.Chem.B, 2005, 109 (32): 15397-15409
[85] Campbell W M, Jolley K W, Wagner P, Wagner K, Walsh P J, Gordon K C, Schmidt-Mende L, Nazeeruddin M K, Wang Q, Grätzel M, Officer D L.J.Phys.Chem.C, 2007, 111 (32): 11760-11762
[86] Bessho T, Zakeeruddin S, Yeh C Y, Diau E G, Grätzel M.Angew.Chem.Int.Ed., 2010, 49 (37): 6646-6649
[87] Ehret A, Stuhl L, Spitler M T.J.Phys.Chem.B, 2001, 105 (41): 9960-9965
[88] Sayama K, Tsukagoshi S, Mori T, Hara K, Ohga Y, Shinpou A, Abe Y, Suga S, Arakawa H.Sol.Energy Mater.Sol.Cells, 2003, 80 (1): 47-71
[89] 方靖淮(Fang J H), 张向阳(Zhang X Y), 吴敬文(Wu J W), 毛海舫(Mao H F), 沈耀春(Shen Y C), 陆祖宏(Lu Z H).太阳能学报(Acta Energiae Solaris Sinica), 1997, 18(2): 164-167
[90] 张莉(Zhang L), 杨迈之(Yang M Z), 乔学斌(Qiao X B), 郝彦忠(Hao Y Z), 高恩勤(Gao E Q), 蔡生民 (Cai S M), 孟凡顺(Meng F S), 田禾(Tian H).应用化学(Chinese Journal of Applied Chemistry), 1999, 16(4): 1-5
[91] 邓慧华(Deng H H), 毛海舫(Mao H F), 沈耀春(Shen Y C), 陆祖宏(Lu Z H), 许慧君(Xu H J).化学学报(Acta Chim.Sinica), 1999, 57: 1199-1205
[92] Zhao W, Hou Y J, Wang X S, Zhang B W, Cao Y, Yang R, Wang W B, Xiao X R.Sol.Energy Mater.Sol.Cells, 1999, 58 (2): 173-183
[93] 李超(Li C), 张宝文(Zhang B W), 王雪松(Wang X S).感光科学与光化学(Photographic Science and Photochemistry), 2005, 23(4): 314-314
[94] 郝彦忠(Hao Y Z), 武文俊(Wu W J), 戴松元(Dai S Y).化学学报(Acta Chim.Sinica), 2006, 64(7): 667-671
[95] 沈小林(Shen X L), 徐卫林(Xu W L), 杨红军(Yang H J).太阳能学报(Acta Energiae Solaris Sinica), 2007, 28(7): 706-710
[96] Inakazu F, Noma Y, Ogomi Y, Hayase S.Appl.Phys.Lett., 2008, 93 (9): 093304-3
[97] Ogura R Y, Nakane S, Morooka M, Orihashi M, Suzuki Y, Noda K.Appl.Phys.Lett., 2009, 94: 073308
[1] 陆峰, 赵婷, 孙晓军, 范曲立, 黄维. 近红外二区发光稀土纳米材料的设计及生物成像应用[J]. 化学进展, 2022, 34(6): 1348-1358.
[2] 韩文亮, 董林洋. 基于硫酸根自由基的先进氧化活化方法及其在有机污染物降解上的应用[J]. 化学进展, 2021, 33(8): 1426-1439.
[3] 彭会荣, 蔡墨朗, 马爽, 时小强, 刘雪朋, 戴松元. 全无机钙钛矿太阳电池的制备及稳定性[J]. 化学进展, 2021, 33(1): 136-150.
[4] 郑超, 戴一仲, 陈铃峰, 李明光, 陈润锋, 黄维. 敏化型电致发光器件原理与技术[J]. 化学进展, 2020, 32(9): 1352-1367.
[5] 沈赵琪, 程敬招, 张小凤, 黄微雅, 温和瑞, 刘诗咏. P3HT/非富勒烯受体异质结有机太阳电池[J]. 化学进展, 2019, 31(9): 1221-1237.
[6] 谭远铭, 孟皓, 张霞. 功能化MOFs及MOFs/聚合物复合膜在有机染料和重金属离子吸附分离中的应用[J]. 化学进展, 2019, 31(7): 980-995.
[7] 李晓茵, 周传聪, 王英华, 丁菲菲, 周华伟, 张宪玺. 锡基钙钛矿太阳电池光吸收材料[J]. 化学进展, 2019, 31(6): 882-893.
[8] 单雪燕, 王时茂, 孟钢, 方晓东. 钙钛矿太阳电池电子传输层与光吸收层的界面工程[J]. 化学进展, 2019, 31(5): 714-722.
[9] 王露, 霍志鹏, 易锦馨, Ahmed Alsaedi, Tasawar Hayat, 戴松元. 有机-无机杂化钙钛矿太阳电池中的钙钛矿层功能添加剂[J]. 化学进展, 2017, 29(8): 870-878.
[10] 李炎平, 於黄忠, 董一帆, 黄欣欣. 溶液法制备有机太阳电池阳极界面修饰层MoO3[J]. 化学进展, 2016, 28(8): 1170-1185.
[11] 姜玲, 阙亚萍, 丁勇, 胡林华, 张昌能, 戴松元. 上/下转换材料在染料敏化太阳电池中的应用进展[J]. 化学进展, 2016, 28(5): 637-646.
[12] 阙亚萍, 翁坚, 胡林华, 戴松元. 二氧化钛在钙钛矿太阳电池中的应用[J]. 化学进展, 2016, 28(1): 40-50.
[13] 刘超, 谭瑞琴, 曾俞衡, 王维燕, 黄金华, 宋伟杰. 硅纳米晶的制备及其在太阳电池中的应用研究[J]. 化学进展, 2015, 27(9): 1302-1312.
[14] 赵响, 赵宗彦. 四元化合物半导体Cu2ZnSnS4:结构、制备、应用及前景[J]. 化学进展, 2015, 27(7): 913-934.
[15] 王桂强, 段彦栋, 张娟, 林原, 禚淑萍. 染料敏化太阳能电池掺杂TiO2纳晶光阳极[J]. 化学进展, 2014, 26(07): 1255-1264.