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化学进展 2011, Vol. 23 Issue (9): 1871-1882 前一篇   后一篇

• 综述与评论 •

基于离子型铱配合物的发光电化学池

周丽霞, 刘淑娟, 赵强*, 凌启淡, 黄维*   

  1. 南京邮电大学信息材料与纳米技术研究院 有机电子与信息显示 国家重点实验室培育基地 南京 210046
  • 收稿日期:2010-10-01 修回日期:2011-01-01 出版日期:2011-09-24 发布日期:2011-09-02
  • 通讯作者: 赵强, 黄维 E-mail:iamqzhao@njupt.edu.cn; wei-huang@njupt.edu.cn
  • 基金资助:

    国家重大科学研究计划(973)项目(No. 2009CB930601)、国家自然科学基金(No. 50803028, 20804019)、江苏省高校自然科学基础研究项目(No. 10KJB430010)、江苏省基础研究计划(No. BK2009427)、南京邮电大学攀登计划(NY210029, NY208405)资助

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导出 被引次数 ( 4 | 2 )

Light-Emitting Electrochemical Cells Based on Ionic Iridium(Ⅲ) Complexes

Zhou Lixia, Liu Shujuan, Zhao Qiang*, Ling Qidan, Huang Wei*   

  1. Key Laboratory for Organic Electronics & Information Displays (KLOEID) and Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications (NUPT), Nanjing 210046, China
  • Received:2010-10-01 Revised:2011-01-01 Online:2011-09-24 Published:2011-09-02

基于离子型过渡金属配合物的发光电化学池在信息显示和固体照明方面极具应用前景,因此其相关材料的设计、开发和器件性能的提高等工作在近几年引起了人们广泛的研究兴趣。在各类离子型过渡金属配合物中,离子型铱配合物由于发光效率高,发光颜色容易调节等优点而受到广泛关注。本文综述了近几年来离子型铱配合物在发光电化学池中的应用进展,重点评述了不同发光颜色的发光电化学池的制备和器件的高性能化等方面的研究进展,并展望了基于离子型铱配合物的发光电化学池这一研究领域的发展前景。

关键词： 离子型铱配合物, 发光电化学池, 电致发光, 磷光

In recent years, light-emitting electrochemical cells (LECs) based on ionic transition metal complexes (iTMCs) with phosphorescent emission have attracted considerable interest because of their great potentials in display and lighting applications. Among all the iTMCs, ionic iridium(Ⅲ) complexes are one of the best phosphorescent materials because of their advantageous emission properties, such as high luminescent efficiency and tunable emission colors. This review summarized the recent research progress of ionic iridium(Ⅲ) complexes applied in light-emitting electrochemical cells, mainly focusing on the development of LECs with different light-emitting colors and the improvement of device performances. In addition, the future directions in this field are also discussed.

Contents
1 Introduction
2 Mechanism of LECs
3 Iionic Ir(Ⅲ) complexes-based LECs with different light-emitting colors
3.1 Blue-green-emitting ionic Ir(Ⅲ) complexes-based LECs
3.2 Red-emitting ionic Ir(Ⅲ) complexes-based LECs
3.3 Yellow-emitting ionic Ir(Ⅲ) complexes-based LECs
3.4 White-emitting ionic Ir(Ⅲ) complexes-based LECs
4 Optimization of ionic Ir(Ⅲ) complexes-based LECs performances
4.1 Decreasing the turn-on time of ionic Ir(Ⅲ) complexes-based LECs
4.2 Improving the stability of ionic Ir(Ⅲ) complexes-based LECs
4.1 Increasing the efficiency of ionic Ir(Ⅲ) complexes-based LECs
5 Conclusion and outlook

 

 

Key words: ionic iridium(Ⅲ) complexes, light-emitting electrochemical cells, electroluminescence, phosphorescence

中图分类号: 

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