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化学进展 2010, Vol. 22 Issue (10): 2060-2070 前一篇   后一篇

• 综述与评论 •

纳米微晶纤维素制备*

李伟  王锐  刘守新**   

  1. (东北林业大学 生物质材料教育部重点实验室 哈尔滨 150040)
  • 收稿日期:2010-01-28 修回日期:2010-03-12 出版日期:2010-10-24 发布日期:2010-10-20
  • 通讯作者: 李伟 E-mail:xinyang19820927@163.com
  • 基金资助:

    黑龙江省杰出青年基金;中央高校基本科研业务专项资金杰出青年科研人才基金;东北林业大学优秀博士学位论文培育计划

Preparation of Nanocrystalline Cellulose

Li Wei   Wang Rui   Liu Shouxin**   

  1. (Key Laboratory of Biological Materials of Ministry of Education , Northeast Forestry University , Harbin 150040 , China)
  • Received:2010-01-28 Revised:2010-03-12 Online:2010-10-24 Published:2010-10-20
  • Contact: Li Wei E-mail:xinyang19820927@163.com

纳米微晶纤维素(NCC)由于其大量、可再生、可生物降解以及优良的力学性能,成为纳米技术领域研究的热点。文章综述了NCC的制备方法,并对化学和机械法制备NCC纤维素作了重点介绍。同时对NCC的表面改性进行了综述。并对NCC在制备纳米复合材料领域的应用进行了总结,对其在增强复合材料中的应用作了较详细的介绍。最后对NCC未来的发展进行了展望。

Nanocrystalline cellulose has become a hotspot in nanotechnology field for its advantages of abundant, renewable, biodegradable and excellent mechanical properties. The preparation methods of NCC are summarized, especially introducing the chemical and mechanical preparation methods. Meanwhile the surface modification of NCC is reviewed, also the application of the NCC for preparing nanocomposites are summarized and the application of NCC on reinforcing composites are reviewed in detail. Finally, the future development of NCC is prospected.

Contents
1 Introduction
2 Preparation of NCC
2.1 Chemical method
2.2 Mechanical method
2.3 Biologic method
2.4 Solvent method
2.5 Electrospinning method
2.6 Ionic liquid method
3 Surface modification of NCC
3.1 Sulfonation
3.2 Carboxylation
3.3 Grafting
3.4 Acetylation
3.5 Silanization
3.6 Surfactant treatment
3.7 Polyelectrolyte treatment
4 Applications of NCC in composites
4.1 High qualities reinforcement composites and film materials
4.2 Medical materials
4.3 Optical materials
4.4 Template materials
4.5 Other applications
5 Outlook

()

[1 ] Wegner T H,Jones P E. Cellulose,2006,13: 115—118
[2 ] Lahiji R R,Reifenberger R,Raman A,Rudie A,Moon R J.
NSTI Nanotechnology Conference and Trade Show
Nanotechnology,2008,2: 704—707
[3 ] Pandey J K, Chu W S, Kim C S, Lee C S, Ahn S H.
Composites: Part B,2009,40: 676—680
[4 ] Lima M M D S,Borsali R. Macromol. Rapid Commun. ,2004,
25: 771—787
[5 ] Helbert W, Sugiyama J, Ishira M, Yamanaka S. J.
Biotechnol. ,1997,57(1 /3) : 29—37
[6 ] Hamad W. The Canadian Journal of Chemical Engineering,
2006,84(10) : 513—519
[7 ] Sturcova A,Davies G R,Eichhorn S J. Biomacromolecules,
2005,6: 1055—1061
[8 ] Orts W J,Shey J,Imam S H,Glenn G M,Guttman M E,Revol
J F. J. Polymers Environ. ,2005,13(4) : 301—306
[9 ] Petersson L,Kvien I,Oksman K. Composites Sci. & Technol. ,
2007,67: 2535—2544
[10] Noorani S,Simonsen J,Atre S. Cellulose,2007,14: 577—584
[11] Dalmas F,Chazeau L,Gauthier C,Cavaille J Y,Dendievel R.
Polymer,2006,47(8) : 2802—2812
[12] Samir M A S A,Alloin F,Dufresne A. Biomacromolecules,
2005,6(2) : 612—626
[13] Revol J F,Bradford H,Giasson J,Marchessault R H,Gray D
G. Int. J. Biol. Macromol. ,1992,14: 170—172
[14] Fleming K,Gray D G,Matthews S. Chem. Eur. J. ,2001,7
(9) : 1831—1835
[15] Fleming K,Gray D G, Prasannan S,Matthews S. J. Am.
Chem. Soc. ,2000,122(21) : 5224—5225
[16] Battista O A,Coppick S,Howsmon J A,Morehead F F,Sisson
W A. Ind. Eng. Chem. ,1955,48: 333—335
[17] Marchessault R H,Morehead F F,Koch M J. J. Colloid Sci. ,
1961,16: 327—344
[18] Araki J,Wada M,Kuga S,Okano T. Colloid Surfaces A,1998,
142: 75—82
[19] Dong X M,Revol J F,Gray D G. Cellulose,1998,5: 19—32
[20] Grunert M,Winter W T. J. Polym. Environ. ,2002,10: 27—
30
[21] Favier V,Chanzy H,Cavaille J Y. Macromolecules,1995,28:
6365—6367
[22] Imai T, Boisset C, Samejima M, Igarashi K, Sugiyama J.
Federation of European Biochemical Societies Letters, 1998,
432: 113—116
[23] de Rodriguez N L G,Thielemans W,Dufresne A. Cellulose,
2006,13: 261—270
[24] Ranby B G. Discussions Faraday Society,1952,11: 158—164
[25] Beck-Candanedo S,Roman M,Gray D G. Biomacromolecules,
2005,6: 1048—1054
[26] Zhang J G,Elder T J,Pu Y Q,Ragauskas A J. Carbohydrate
Polymers,2007,69: 607—611
[27] Moran J I,Alvarez V A,Cyras V P,Vazquez A. Cellulose,
2008,15: 149—159
[28] Marchessault R H,Morehead F F,Koch M J. Colloid Sci. ,
1961,16: 327—344
[29] Bondeson D,Mathew A, Oksman K. Cellulose,2006,13:
171—180
[30] Filson P B,Dawson-Andoh B E. Bioresource Technology,2009,
100: 2259—2264
[31] Bai W,Holbery J,Li K C. Cellulose,2009,16: 455—465
[32] Ranby B G. Ark. Kemi. ,1952,4: 249—257
[33] Ranby B G. Ark. Kemi. ,1952,4: 241—248
[34] Terech P,Chazeau L,Cavaille J Y. Macromolecules,1999,32:
1872—1875
[35] Araki J,Kuga S. Langmuir,2001,17: 4493—4496
[36] Tokoh C,Takabe K,Fujita M,Saiki H. Cellulose,1998,5:
249—261
[37] Roman M,Winter W T. Biomacromolecules,2004,5: 1671—
1677
[38] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2004,78(4) : 547—552
[39] Chakraborty A,Sain M,Kortschot M. Holzforschung,2005,59
(1) : 102—107
[40] Iwamoto S,Nakagaito A N,Yano H,Nogi M. Appl. Phys. A,
2005,81: 1109—1112
[41] Bruce D M, Hobson R N, Farrent J W, Hepworth D G.
Composites Part A-Applied Sci. Manuf. , 2005, 36 ( 11 ) :
1486—1493
[42] Dinand E,Chanzy H,Vignon M R. Cellulose,1996,3: 183—
188
[43] Stenstad P,Andresen M,Tanem B S,Stenius P. Cellulose,
2008,15(1) : 35—45
[44] Bhantnagar A,Sain M J. Reinforced Plastics Composites,2005,
24(12) : 1259—1268
[45] Leitner J,Hinterstoisser B,Wastyn M,Keckes J,Gindl W.
Cellulose,2007,14: 419—425
[46] Dufresne A,Cavaille J Y,Vignon M R. J. Appl. Polym. Sci. ,
1997,64: 1185—1194
[47] Wagberg L,Decher G,Norgren M,Lindstrom T,Ankerfors M.
Langmuir,2008,24(3) : 784—795
[48] Paakko M,Ankerfors M,Kosonen H,Nykanen A,Ahola S,
Osterberg M,Ruokolainen J,Laine J,Larsson P Y,Ikkala Q,
Lindstrom Y. Biomacromol. ,2007,8(6) : 1934—1941
[49] Janardhnan S,Sain M. BioRes. ,2006,1(2) : 176—188
[50] Alemdar A,Sain M. Biores. Technol. ,2008,99 (6 ) : 1664—
1671
[51] Wang B,Sain M. Polymer International,2007,56 ( 4 ) : 538—
546
[52] Yamanaka S,Watanabe K,Kitamura N. Journal of Material
Science,1989,24: 3141—3145
[53] Ross P,Mayer R,Benziman M. Microbiological Reviews,1991,
55(1) : 35—58
[54] Uraki Y, Morito M, Kishimoto T, Sano Y. Holzforschung,
2002,56(4) : 341—347
[55] Bae S,Shoda M. Biotechnol. Prog. ,2004,20: 1366—1371
[56] Ishihara M,Matsunaga M,Hayashi N,Tisler V. Enzyme and
Microbial Technology,2002,31(7) : 986—991
[57] Oksman K,Mathew A P,Bondeson D,Kvien I. Composites Sci.
Technol. ,2006,66(15) : 2776—2784
[58] Nelson K,Deng Y L. Macromol. Mater. Eng. ,2007,292(10 /
11) : 1158—1163
[59] Kulpinski P. J. Appl. Polymer Sci. ,2005,98 ( 4 ) : 1855—
1859
[60] Kim C W,Kim D S,Kang S Y,Marquez M,Joo Y L. Polymer,
2006,47(14) : 5097—5107
[61] Olivier H. J. Mol. Catalysis A: Chemical,1999,146 ( 1 /2 ) :
285—289
[62] Gindl W,Keckes J. Polymer,2005,46(23) : 10221—10225
[63] Kilpelainen I,Xie H,King A,Granstrom M,Heikkinen S,
Argyropoulos D S. J. Agric. Food Chem. ,2007,55 ( 22 ) :
9142—9148
[64] Sui X,Yuan U,Yuan W,Zhou M. Chemistry Letters,2008,37
(1) : 114—115
[65] Wgberg L,Decher G,Norgren M,Lindstrom T,Ankerdors M,
Axnas K. Langmuir,2008,24(3) : 784—795
[66] Montanari S,Rountani M,Heux L,Vignon M R. Macromol. ,
2005,38(5) : 1665—1671
[67] Saito T,Kimura S,Nishiyama Y, Isogai A. Biomacromol. ,
2007,8(8) : 2485—2491
[68] Habibi Y,Chanzy H,Vignon M R. Cellulose,2006,13 ( 6 ) :
679—687
[69] Mishra S,Naik J B. Polymer-Plastics Technol. Eng. ,2005,44
(4) : 663—675
[70] Nenkova S, Dobrilova C, Natov M, Vasileva S, Velev P.
Polym. and Polym. Comp. ,2006,14(2) : 185—194
[71] Kamel S,Adel A M,El-Sakhawy M,Nagieb Z A. J. Appl.
Polymer Sci. ,2008,107(2) : 1337—1342
[72] Stenstad P,Andresen M,Tanem B S,Stenius P. Cellulose,
2008,15(1) : 35—45
[73] Hubbe M A,Wagle D G,Ruckel E R. US 5958180,1999
[74] Matuana L M,Woodhams R T,Balatinecz J J, Park C B.
Polymer Composites,1998,19(4) : 446—455
[75] Habibi Y,Dufresne A. Biomacromol. ,2008,9 ( 7 ) : 1974—
1980
[76] Cai X L,Riedl B,Ait-Kadi A. J. polymer Sci. B-Polymer
Phy. ,2003,41(17) : 2022—2032
[77] Dou H J,Yang W H,Sun K. Chem. Lett. ,2006,35 ( 12 ) :
1374—1375
[78] Li X,Tabil L G,Panigrahi S. J. Polym. Environ. ,2007,15:
25—33
[79] Caulfield D F,Koutsky J A,Quillen D T. Forest Prod. Soc. ,
1993,128—134
[80] Mwaikambo L Y, Ansell M P. Angew. Makormol. Chem. ,
1999,272: 108—116
[81] Kim D Y,Nishiyama Y,Kuga S. Cellulose,2002,9 ( 3 ) :
361—367
[82] Ifuku S,Nogi M,Abe K,Handa K,Nakatsubo F,Yano H.
Biomacromol. ,2007,8(6) : 1973—1978
[83] Gousse C,Chanzy H,Cerrada M L,Fleury E. Polymer,2004,45(5) : 1569—1575
[84] Panaitescu D M,Donescu D,Brecu C,Vuluga D M,Iorga M,
Ghiurea M. Polymer Eng. Sci. ,2007,47(8) : 1228—1234
[85] Castellano M,Gandini A,Fabbri P,Belgacem M N. J. Colloid
Interface Sci. ,2004,273(2) : 505—511
[86] Gradwell S E,Renneckar S,Esker A R,Heinze T,Gatenholm
P,Vaca-Garcia C,Glasser W. Comptes Rendus Biol. ,2004,
327(9 /10) : 945—953
[87] Ljungberg N, Bonini C, Bortolussi F, Boisson C,Heux L,
Cavaille J Y. Biomacromol. ,2005,6(5) : 2732—2739
[88] Ahola S,Osterberg M, Laine J. Cellulose,2008,15 ( 2 ) :
303—314
[89] Hubbe M A. J. Pulp Paper Sci. ,2005,31(4) : 159—166
[90] Hajji P,Cavaille J Y,Favier V,Gauthier C,Vigier G. Polymer
Composites,1996,17(4) : 612—619
[91] Ruiz M M,Cavaille J Y,Dufresne A,Graillat C,Gerard J F.
Macromol. Symp. ,2001,169: 211—222
[92] Bhatnagar A,Sain M J. Reinforced Plastics Composites,2005,
24(12) : 1259—1268
[93] Wu Q,Henrihsson M,Liu X,Berglund L A. Biomacromol. ,
2007,8(12) : 3687—3692
[94] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2004,78(4) : 547—552
[95] Nakagaito A N,Iwamoto S,Yano H. Appl. Phys. A- Mater.
Sci. Proc. ,2005,80(1) : 93—97
[96] Nakagaito A N,Yano H. Appl. Phys. A-Mater. Sci. Proc. ,
2005,80(1) : 155—159
[97] Wang B,Sain M. Composites Sci. Technol. ,2007,67 ( 11 /
12) : 2521—2527
[98] Favier V,Canova G R,Cavaille J Y,Chanzy H,Dufresne A,
Gauthier C. Polymer Adv. Tech. ,1995,6(5) : 351—355
[99] Noorani S,Simonsen J,Atre S. Cellulose,2007,14: 577—584
[100] Cao X D,Dong H,Li C M. Biomacromol. ,2007,8(3) : 899—
904
[101] Pu Y Q, Zhang J G, Elder T, Deng Y L, Gatenholm P,
Ragauskas A J. Composites Part B: Engineering,2007,38:
360—366
[102] Dufresne A,Cavaille J Y,Helbert W. Polymer Composites,
1997,18(2) : 198—210
[103] Dong S P,Roman M. J. Am. Chem. Soc. ,2007,129 ( 45 ) :
13810—13811
[104] Czaja W K, Young D J, Kawecki M, Brown R W.
Biomacromol. ,2007,8(1) : 1—12
[105] Millon L E,Wan W K. J. Biomed. Mater. Res. Part B—Appl.
Biomater. ,2006,79B(2) : 245—253
[106] Bodin A,Backdahl H,Risberg B,Gatenholm P. Tissue Eng. ,
2007,13(4) : 885—885
[107] Nogi M,Ifuku S,Abe K,Handa K,Nakagaito A N,Yano H.
Appl. Phys. Lett. ,2006,88(13) : art. no. 133124
[108] Nogi M,Abe K,Handa K,Nakatsubo F,Ifuku S,Yano H.
Appl. Phys. Lett. ,2006,89(23) : art. no. 233123
[109] Bochek A M,Ten'kovtsev A V,Dudkina M M,Lukoshkin V N,
Matneeva G N,Sukhanova T E. Polymer Sci. Ser. B,2004,46
(3 /4) : 109—112
[110] Cranston E D,Gray D G. Biomacromol,2006,7 ( 9 ) : 2522—
2530
[111]Wang N,Ding E Y,Cheng R S. Langmuir,2008,24(1) : 5—
8
[112] Dujardin E,Blaseby M,Mann S J. Mater. Chem. ,2003,13
(4) : 696—699
[113] Shin Y,Exarhos G J. Mater. Lett. ,2007,61(11 /12) : 2594—
2597
[114] Shin Y,Blackwood J M,Bea I T,Arey B W,Exarhos G J.
Materials Letter,2007,61: 4297—4300
[115] Zhou Y,Ding E Y,Li W D. Materials Letters,2007,61:
5050—5052
[116] Agarwal M,Lvov Y,Varahramyan K. Nanotechnol. ,2006,17
(21) : 5319—5325
[117] Van den Berg O,Schroeter M,Capadona J R,Weder C. J.
Mater. Chem. ,2007,17(26) : 2746—2753
[118] Kim J,Yun S. Macromolecules,2006,39(12) : 4202—4206
[119] Nickerson R F,Habrle J A. Ind. Eng. Chem. ,1947,39:
1507—1512
[120] Matsumura H,Sugiyama J,Glasser W G. J. Appl. Polymer
Sci. ,2000,78(13) : 2242—2253

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摘要

纳米微晶纤维素制备*