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化学进展 2010, Vol. 22 Issue (10): 1921-1928 前一篇   后一篇

• 综述与评论 •

功能离子液体/氧化硅基多孔复合材料*

陈传东1   翟尚儒1**   翟滨1**  武贺娟1    安庆大1    孙予罕2   

  1. (1. 化工与材料学院 大连工业大学 大连 116034； 2. 中国科学院山西煤炭化学研究所 煤转化国家重点实验室 太原 030001)
  • 收稿日期:2010-01-07 修回日期:2010-04-26 出版日期:2010-10-24 发布日期:2010-10-20
  • 通讯作者: 翟尚儒 E-mail:zhai_shangru@yahoo.com.cn
  • 基金资助:

    国家重点基础研究发展计划

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Functional Ionic liquids/Porous Silica Compostes

Chen Chuandong1  Zhai Shangru1**   Zhai Bin1**  Wu Hejuan1 An Qingda1  Sun Yuhan2   

  1. (1. Faculty of Chemical Engineering and Material, Dalian Polytechnic University, Dalian 116034, China; 2. State Key Laboratory of Coal Conversion, Institute of Coal Chemistry, the Chinese Academy of Sciences, Taiyuan 030001, Shanxi)
  • Received:2010-01-07 Revised:2010-04-26 Online:2010-10-24 Published:2010-10-20
  • Contact: Zhai Shangru E-mail:zhai_shangru@yahoo.com.cn

利用有巨大界面特征和发达孔道结构的氧化硅基多孔材料作为功能离子液体的载体，不仅可实现离子液体的固相化从而解决均相离子液体分离难的瓶颈，而且也可增加离子液体的比表面积进而提高离子液体的使用效率和稳定性；探索结合离子液体和氧化硅基多孔材料双重优点的目标功能材料的制备及应用成为近年来的一个研究热点。本文综述了离子液体/氧化硅基多孔复合材料的最新研究进展，探讨了其合成手段的有效性，并对其应用前景进行了展望。

关键词： 离子液体, 介孔, SiO2, 合成, 应用

The popularity of ionic liquids has significantly increased over the last decade. Among reported studies on ionic liquids, the preparation and application of supported ionic liquid are of great importance due to the combination of both advabntages of  ionic liquids and those of hetergeneous support materials. The viability of this concept has recently confirmed by many studies which have successfully supported various ionic liquids on the surface of porous silicas and explored their potential applications in various fields. The  preparation of these compostes was mainly achieved by using two kinds of silica-based materals,namely  xerogels and ordered mesostructures,via two different immobilization approaches of covalent  attachment and simple deposit. Utilizing and application of ionic liquids/porous silicas associated with dual advantages is an attractive research direction, recently. In this respect, the recent research progress on the objective composites are summarized on the basis of the effectiveness of the synthesis pathways. Meanwhile, the potential applications are also prospected.

Contents
1 Introduction
2 Preparation and applications of supported ionic liquids/silica-xerogel catalysts
3 Preparation and application of supported ionic liquids/OMS(ordered mesoporous silicas) catalytic materials
3.1 Directly used as catalysts in various reactions
3.2 Supports for active metal nanoparticles or metal complex
4 Conclusions

 

Key words: ionic liquids, mesoporous, silicas, synthesis, application
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