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化学进展 2010, Vol. 22 Issue (10): 1901-1910 前一篇   后一篇

• 综述与评论 •

特殊形貌CdSe纳米晶的制备*

张居正1  高善民1,2   黄柏标2   戴瑛2  王菊1  卢娟1   

  1. (1. 鲁东大学化学与材料科学学院 烟台264025； 2. 山东大学晶体材料国家重点实验室 济南 250100)
  • 收稿日期:2010-01-13 修回日期:2010-03-09 出版日期:2010-10-24 发布日期:2010-10-20
  • 通讯作者: 高善民 E-mail:gaosm@ustc.edu
  • 基金资助:

    国家重点基础研究发展计划;山东省中青年科学家科研奖励基金;山东省教育厅科研计划

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Preparation of CdSe Nanocrystals with Special Morphologies

Zhang Juzheng1  Gao Shanmin1,2**  Huang Baibiao2   Dai Ying2   Wang Ju1   Lu Juan1   

  1. (1.School of Chemistry and Materials Science, Ludong University, Yantai 264025, China; 2. State Key Lab of Crystal Materials, Shandong University, Jinan 250100, China)
  • Received:2010-01-13 Revised:2010-03-09 Online:2010-10-24 Published:2010-10-20
  • Contact: Gao Shanmin E-mail:gaosm@ustc.edu

CdSe纳米晶是II-VI族半导体中研究最多的材料之一，由于其发射波长随纳米晶的尺寸而改变，从而可以覆盖从绿到红的宽光谱范围，因此CdSe纳米晶可以应用于生物标记和荧光显示等领域，各种制备CdSe纳米晶的方法也应运而生。因制备方法的不同，所得CdSe纳米晶的粒径、相结构及形貌也不同，进而影响CdSe纳米晶的性质。本文归纳了7种典型的制备一些特殊形貌的CdSe纳米晶的最新方法，并对各种方法的优缺点作了简单评价。最后，对这一领域未来的研究和发展方向作了展望。

关键词： CdSe, 纳米晶, 制备, 形貌

As an important II-VI group semiconductor material, CdSe nanocrystals have drawn much attention recently due to its unique size-dependent fluorescence tunable across the visible spectrum. CdSe semiconductor nanocrystals exhibit great potential used as a new type of fluorescence materials and labeling material for biological research. Various preparation methods have been developed to synthesize differently size and morphology CdSe nanocrystals. With the different preparing methods, the diameter, phase structure, morphologies uniformity, and properties are also different accordingly. In this paper, the seven typical methods of preparation and control of morphology of CdSe nanocrystals are summarized in detail. Meanwhile, their corresponding strongpoints and weaknesses are also reviewed. The challenges about preparing CdSe nanocrystals are figured out and the future directions are also proposed.

Contents
1　Introduction
2　Preparation methods of CdSe nanocrystals
2.1 Organic liquid synthesis method
2.2 Low temperature water solution method
2.3 Template electrochemical deposition method
2.4 Vapor deposition method
2.5 Hydrothermal and solvothermal methods
2.6 Irradiation chemical method
2.7 Self-assembly technology
3　Conclusions and prospects

Key words: CdSe, nanocrystals, preparation, morphology
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摘要

特殊形貌CdSe纳米晶的制备*