辐射诱导合成水凝胶及其处理重金属废水的研究进展*

陈玉伟 王建龙

化学进展 ›› 2009, Vol. 21 ›› Issue (10) : 2250-2256.

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化学进展 ›› 2009, Vol. 21 ›› Issue (10) : 2250-2256.
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陈玉伟 王建龙. 辐射诱导合成水凝胶及其处理重金属废水的研究进展*[J]. 化学进展, 2009, 21(10): 2250-2256
Chen Yuwei Wang Jianlong. The Radiation-Induced Synthesis of Hydrogels and Their Application for Removal of Heavy Metal Ions from Aqueous Solution[J]. Progress in Chemistry, 2009, 21(10): 2250-2256
综述与评论

辐射诱导合成水凝胶及其处理重金属废水的研究进展*

  • 陈玉伟;王建龙**
作者信息 +

The Radiation-Induced Synthesis of Hydrogels and Their Application for Removal of Heavy Metal Ions from Aqueous Solution

  • Chen Yuwei; Wang Jianlong**
Author information +
文章历史 +

摘要

水凝胶是一种经适度交联而具有三维网络结构的新型功能高分子材料。制备水凝胶因操作简单、无须添加交联剂和引发剂等优点而受到关注。传统的处理重金属废水的方法或成本较高,或效率低,利用水凝胶处理重金属废水成为一种新的颇具潜力的方法。本文综述了辐射法制备水凝胶及其在重金属吸附去除方面的研究进展包括材料的制备、改性、去除重金属性能等方面的研究进展,并指出了水凝胶去除重金属的发展前景和今后的研究方向。

Abstract

Hydrogels are cross-linked functional polymers with three-dimensional networks. Preparation of hydrogels by radiation-induced polymerization has received increasing attention in recent years due to easy process control, no necessity to add any initiators, crosslinkers, etc. Traditional processes for the treatment of heavy metal-containing wastewater encounter some disadvantages such as higher operational cost or low removal efficiency. It is a new promising method for the removal of heavy metals from aqueous solution using hydrogels. In this paper, recent advances in research on the radiation-induced synthesis of hydrogels and their application in the removal of heavy metals are reviewed including the preparation and modification of hydrogels and the performances of the adsorption of heavey metas. The perspects of this technology and the future directions are also proposed.

Contents
1 Introduction
2 Radiation-induced synthesis of hydrogels
2.1 Radiation-induced polymerization of solid polymers
2.2 Radiation-induced polymerization of aqueous solutions of polymers
2.3 Radiation treatment of monomers
2.4 Preparation of copolymer hydrogels by radiation treatment
3 Radiation-induced synthesis of hydrogels for the removal of heavy metal ions
3.1 Hydrogels based on synthetic polymers for the adsorption of heavy metals
3.2 Hydrogels based on natural polymers for the adsorption of heavy metals
3.3 Hydrogels loaded metal ions for the adsorption of heavy metals
3.4 Hydrogels loaded microorganisms for the adsorption of heavy metals
3.5 Desorption and recovery of heavy metals
4 Conclusion

关键词

水凝胶 / 交联聚合物 / 辐射聚合 / 重金属废水 / 吸附

Key words

hydrogels / cross-linked polymers / radiation-induced polymerization / heavy metal-containing wastewater / absorption

中图分类号: X703    O648.17   

参考文献

[ 1 ]  顾蓉(Gu R) , 朱育平(Zhu Y P) . 凝胶化学(Chemical Gel) .北京: 化学工业出版社(Beijing: Chemical Industry Press) ,2005. 1 —12
[ 2 ]  邹新禧( Zou X X) . 超强吸水剂( Superabsorbents) . 第二版(Second Edition) 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 2002. 36 —635
[ 3 ]  吴季怀(Wu J H) , 林建明(Lin J M) , 魏月琳(Wei Y L) 等.高吸水保水材料(High Water-absorbent material) . 北京: 化学工业出版社(Beijing: Chemical Industry Press) , 2005. 1 —12
[ 4 ]  Güven O , Sen M, Karadaɡ E , et al . Radiat . Phys. Chem. , 1999 ,56 : 381 —386
[ 5 ]  翟茂林(Zhai M L) , 哈鸿飞(Ha H F) . 大学化学(Chemistry of the University) , 2001 , 16 (5) : 22 —27
[ 6 ]  李谦(Li Q) , 李东辉(Li D H) , 全寿益(Quan S Y) 等. 辐射研究与辐射工艺学报( Radiation Research and Radiation Processing) , 1984 , 2 (2) : 12 —16
[ 7 ]  Molina MJ , Gomez-Anton M R , Rivas B L , et al . J . Appl . Polym.Sci . , 2001 , 79 (8) : 1467 —1475
[ 8 ]  Salih B , Pekel N , Guven O. J . Appl . Polym. Sci . , 2001 , 82 (2) :446 —453
[ 9 ]  王建龙(Wang J L) . 生物固定化技术与水污染控制(Microbial Immobilization Techniques and Water Pollution Control) . 北京: 科学出版社(Beijing: Sceince Press) , 2002
[10 ]  Wang J L , Chen C. Biotechnol . Adv. , 2006 , 24 : 427 —451
[11 ]  Abd E1-Rehim H A , Hegazy E A , El-Hag Ali A. React . Funct .Polym. , 2000 , 34 : 105 —116
[12 ]  Rosiak J M, Ulański P. Radiat . Phys. Chem. , 1999 , 55 : 139 —151
[13 ]  Abdel-Aal S E , Hegazy E A , Abou Taleb M F , et al . J . Appl .Polym. Sci . , 2008 , 107 : 1759 —1776
[14 ]  Bodugêz H , Pekel N , Güven O. Radiat . Phys. Chem. , 1999 , 55 :667 —671
[15 ]  Ajji Z. Radiat . Phys. Chem. , 2005 , 74 : 36 —41
[16 ]  Ajji Z. Nucl . Instrum. Methods Phys. Res. B , 2007 , 265 : 179 —182
[17 ]  El-Hag Ali A , Shawky H A , Abd El-Rehim H A , et al . Eur.Polym. J . , 2003 , 39 : 2337 —2344
[18 ]  Essawy H A , Ibrahim H S. React . Funct . Polym. , 2004 , 61 :421 —432
[19 ]  Francis S , Varshney L , Tirumalesh K. Radiat . Phys. Chem. ,2006 , 75 : 747 —754
[20 ]  Ajji Z, Ali A M. Nucl . Instrum. Methods Phys. Res. B , 2005 ,236 : 580 —586
[21 ]  Kawaguchi H , Hoshino H J . Colloid Interface Sci . , 1984 , 97 (2) :465 —475
[22 ]  Kamel A A , Ma C M, El-Aasser M S , et al . J . Dispersion Sci .Technol . , 1981 , 2 : 315 —330
[23 ]  Schiller M,Suen TJ . Ind. Engng. Chem. , 1956 , 48 : 2132 —2137
[24 ]  Kasgêz H , ; zgümüs S , Orbay M. Polymer , 2003 , 44 : 1785 —1793
[25 ]  郭宝春(Guo B C) , 邱清华(Qiu Q H) , 贾德民(Jia D M) . 功能材料(Journal of Functional Materials) , 2000 , 31 : 29 —32
[26 ]  Chauhan G S , Guleria L , Mahajan S. Desalination , 2001 , 14 :125 —329
[27 ]  Chauhan G S , Singh B , Chauhan S , et al . Desalination , 2005 ,181 : 217 —224
[28 ]  Piron E , Domard A. Int . J . Biol . Macromol . , 1998 , 22 : 33 —40
[29 ]  Bassi R , Prasher S O , Simpson B K. Sep. Sci . Technol . , 2000 ,35 : 547 —560
[30 ]  Muzzarelli R A A , Tanfani T, Emanuelli M. Carbohydr. Res. ,1982 , 107 (2) : 199 —214
[31 ]  Zhao L , Mitomo H , Nagasawa N , et al . Carbohydr. Polym. , 2003 ,51 (2) : 169 —178
[32 ]  Wasikiewicz J M, Nagasawa N , Tamada M, et al . Nucl . Instrum.Methods Phys. Res. B , 2005 , 236 : 617 —623
[33 ]  Wang M, Xu L , Zhai ML , et al . Carbohydr. Polym. , 2008 , 74 :498 —503
[34 ]  Gad Y H. Radiat . Phys. Chem. , 2008 , 77 : 1101 —1107
[35 ]  Nizam El-Din H M, Abou Taleb M F , El-Naggar A W M. Nucl .Instrum. Methods Phys. Res. B , 2008 , 266 : 2607 —2613
[36 ]  Abou Taleb M F , Elsigeny S M, Ibrahim M M. Radiat . Phys.Chem. , 2007 , 76 : 1612 —1618
[37 ]  Chang J S , Huang J C. Biotechnol . Prog. , 1998 , 14 : 735 —741
[38 ]  Fernández Degiorgi C , Pizarro R A , Smolko E E. Radiat . Phys.Chem. , 2002 , 63 : 109 —113
[39 ]  Dêker S , μelikb¥?ak ; , Doˇgan M, et al . Microchem. J . , 2006 ,84 : 80 —87
[40 ]  Dêker¥?S , Malc¥S , Doˇgan M. Anal . Chim. Acta , 2005 , 553 :        73 —82
[41 ]  K¥l¥?A G, Malc¥S , μelikb¥?ak ; . Anal . Chim. Acta , 2005 , 547 :18 —25
[42 ]  Wasikiewicz J M, Mitomo H , Seko N , et al . J . Appl . Polym. Sci . ,2007 , 104 : 4015 —4023

基金

国家自然科学基金


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