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化学进展 2009, Vol. 21 Issue (10): 2219-2228 前一篇   后一篇

• 综述与评论 •

硼氢化钠催化水解制氢*

梁艳;王平;戴洪斌**   

  1. ( 中国科学院金属研究所 沈阳材料科学国家（联合）实验室  沈阳 110016 )
  • 收稿日期:2008-10-29 修回日期:2008-11-17 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 戴洪斌 E-mail:hbdai@imr.ac.cn
  • 基金资助:

    863项目;中科院创新工程

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Hydrogen Generation from Catalytic Hydrolysis of Sodium Borohydride Solution

Liang Yan;  Wang Ping;  Dai Hongbin**   

  1. (Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Science, Shenyan 110016, China)
  • Received:2008-10-29 Revised:2008-11-17 Online:2009-10-24 Published:2009-10-09
  • Contact: Dai Hongbin E-mail:hbdai@imr.ac.cn

硼氢化钠（NaBH4）催化水解制氢是一项具备车载氢源应用前景的储氢/制氢一体化技术。本文介绍了该技术催化水解制氢的原理，综述了制氢催化剂、反应动力学、反应机理、反应装置的设计和反应副产物回收利用的最新研究进展，讨论了该技术研发中需解决的问题。水解制氢系统的实际应用需研发高效、耐久性负载型催化剂。制氢装置的设计应考虑反应热的综合利用、燃料电池产生的水循环利用及膜分离技术的应用。NaBH4的高效再生将降低其生产成本，实现NaBH4基水解制氢系统的商业化应用。

关键词： 硼氢化钠, 储氢/制氢, 催化剂, 反应动力学, 制氢装置

Hydrogen generation (HG) from catalytic hydrolysis of sodium borohydride (NaBH4) solution is a promising integrated technology for on-board hydrogen storage/generation. In this perspective, we present the principle of HG from NaBH4 solution, and review the current progresses in catalysts, reaction kinetics, reaction mechanism, design of reaction generator and recycle of hydrolysis production, and then discuss some remaining problems in the development of NaBH4-based HG system. Supported catalyst with high-activity and durability is desirable in developing the HG system for practical application. The design of hydrogen generator should focus on the utilization of reaction heat to preheat fuel, the recycle of water from the fuel cell and the technology of separation by the membrane. The highly efficient regeneration of NaBH4 can reduce its cost, thus promoting the commercial applications of the NaBH4-based HG system.

Contents
1 Introduction
2 The current status and progress of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.1 The principle of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.2 The development of catalyst of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.3 Study of reaction kinetics of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.4 Study of reaction mechanism of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.5 Design of reaction generator of hydrogen generation from catalytic hydrolysis of NaBH4 solution
2.6 Regeneration of NaBH4 from the hydrolysis production (NaBO2)
3 Conclusion and outlook

Key words: sodium borohydride, hydrogen storage/generation, catalysts, reaction kinetics, hydrogen generator

中图分类号: 

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摘要

硼氢化钠催化水解制氢*