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化学进展 2009, Vol. 21 Issue (10): 2188-2198 前一篇   后一篇

• 综述与评论 •

“双亲性”嵌段共聚物胶束形貌调控的研究*

梅爱雄;杨雍;徐君庭;杜滨阳**   

  1. (浙江大学高分子科学与工程学系 高分子合成与功能构造教育部重点实验室 杭州 310027)
  • 收稿日期:2008-10-16 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 杜滨阳 E-mail:duby@zju.edu.cn
  • 基金资助:

    国家自然科学基金

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The Morphological Study of Amphiphilic Block Copolymer Micelles

Mei Aixiong; Yang Yong; Xu Junting; Du Binyang**   

  1. (Key Laboratory of Macromolecular Synthesis and Functionalization, Ministry of Education, Department of Polymer Science & Engineering, Zhejiang University, Hangzhou 310027, China)
  • Received:2008-10-16 Online:2009-10-24 Published:2009-10-09
  • Contact: Du Binyang E-mail:duby@zju.edu.cn
  • Supported by:

    National Natural Science Foundation of China

本文综述了“双亲性”嵌段共聚物在选择性溶剂中胶束行为和胶束形貌的主要影响因素，包括溶液温度、选择性溶剂种类、嵌段长度、链段结晶、链段与溶剂间氢键作用以及共聚物浓度对胶束最终形貌产生影响的因素；系统介绍了对嵌段共聚物胶束形貌进行调控的实验方法；在此同时介绍了对环境刺激如温度和pH变化等具有响应性能的“双亲性”嵌段共聚物在选择性溶剂中胶束行为研究的最新进展；最后提出了该研究领域目前存在的问题和今后的可能发展方向。

关键词： “双亲性”嵌段共聚物, 胶束, 形貌调控

In this paper, the main factors which may influence the micelle morphology and behavior of amphiphilic block copolymers in selective solvents are reviewed. These factors mainly include the solution temperature, the type of selective solvents, the lengths of blocks, the crystalline block, the hydrogen-bond interaction between the blocks and the solvent as well as the concentration of the block copolymers. The experimental methods for controlling the micelle morphology of amphiphilic block copolymers in selective solvents are then summarized. The recent advances in the micellar behaviors of a special type of amphiphilic block copolymers in selective solvents, which are capable to response to the external stimuli such as the environmental temperature and pH value, were also presented. Finally, the existing problems and future possible development directions of this research field are discussed.

Contents
1 Introduction
2 Micellar morphologies of “amphiphilic” block copolymer in selective solvent and their influenced factors
2.1 Temperature
2.2 Copolymer concentration
2.3 Solvent
2.4 Block length
2.5 Hydrogen bond
2.6 Crystallization
2.7 Cooperative effect of several factors
3 Micellar behavior of stimulus-responsive block copolymers
4 Existing problems and prospects

Key words: amphiphilic block copolymer, micelles, morphology controlling

中图分类号: 

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