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化学进展 2009, Vol. 21 Issue (10): 2183-2187 前一篇   后一篇

• 综述与评论 •

低表面能侧基含氟聚合物*

王琼燕; 张庆华; 詹晓力**; 陈丰秋   

  1. （浙江大学联合化学反应工程研究所 杭州 310027）
  • 收稿日期:2008-11-04 修回日期:2009-02-17 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 詹晓力 E-mail:xlzhan@zju.edu.cn
  • 基金资助:

    国家自然科学基金

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Low Surface Energy Polymer with Fluorinated Side Group

Wang Qiongyan;  Zhang Qinghua;  Zhan Xiaoli**;  Chen Fengqiu   

  1. （UNILAB Research Center of Chemical Reaction Engineering, Zhejiang University, Hangzhou 310027, China）
  • Received:2008-11-04 Revised:2009-02-17 Online:2009-10-24 Published:2009-10-09
  • Contact: Zhan Xiaoli E-mail:xlzhan@zju.edu.cn
  • Supported by:

    National Natural Science Foundation of China

含氟聚合物材料具有优异的热稳定性、极低的表面能、强化学稳定性和生物相容性等，在功能涂料、织物整理、微电子、汽车以及航空航天等领域具有很好的应用前景。本文综述了侧基含氟聚合物的主链、全氟烷基链、主链与全氟烷基链段间连接基团的结构对聚合物表面性能的影响，并总结了环境友好型低表面能侧基含氟聚合物的研究进展。

关键词： 含氟聚合物, 低表面能, 表面性能

Polymers with fluorinated side groups have attracted much attention due to their unique properties, such as high chemical and thermal stability, low surface free energy, and outstanding biocompatibility. Therefore, fluoropolymers are used prevalently in functional coating, textile finishing, and aeronautics and astronautics industries. The relationship between the structures of fluorinated polymers (including the structures of the main chains, the perfluorinated alkyl groups, and the spacer groups between them) and their surface properties is reviewed in this paper. Finally, the research progress of environmentally friendly low surface energy polymers with fluorinated side groups is introduced.

Contents
1 Introduction
2 The relationship between structures and surface properties of polymers with fluorinated side groups
2.1 Structures of main chain
2.2 Structures of perfluoroalkyl chain
2.3 Spacer groups between the main chain and perfluoroalkyl chain
3 Environmentally friendly perfluoroalkyl polymers
4 Conclusion and prospects

Key words: fluorinated polymers, low surface energy, surface properties

中图分类号: 

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摘要

低表面能侧基含氟聚合物*