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化学进展 2009, Vol. 21 Issue (10): 2132-2152 前一篇   后一篇

• 综述与评论 •

联三吡啶配体组装及其金属络合物性能*

苑嗣纯1,2**;陈海波2;王惠川1**   

  1. (1. 北京农学院基础科学系  北京  102206；2. 北京大学化学与分子工程学院  教育部生物有机化学与分子工程重点实验室  北京  100871)
  • 收稿日期:2008-10-21 修回日期:2008-11-13 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 苑嗣纯;王慧川 E-mail:ysc2007@sina.com;whch56221@sohu.com
  • 基金资助:

    国家自然科学基金

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Assembly and Metal Complex Properties of Terpyridine Ligands

Yuan Sichun1,2**;  Chen Haibo2;  Wang Huichuan1**   

  1. (1. Department of Fundamental Science, Beijing University of Agriculture, Beijing  102206, China; 2. Key Laboratory of Bioorganic and Molecular Engineering of Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing  100871, China)
  • Received:2008-10-21 Revised:2008-11-13 Online:2009-10-24 Published:2009-10-09
  • Contact: Yuan Sichun;Wang Huichuan E-mail:ysc2007@sina.com;whch56221@sohu.com
  • Supported by:

    National Natural Science Foundation of China

金属-配体间的配位作用是超分子化学中最重要的相互作用之一，寡聚吡啶配体可以与许多过渡金属离子配位，形成具有独特磁、光物理和电化学性质的过渡金属配合物，因此联三吡啶配体过渡金属配合物性能研究引起化学家的广泛关注。本文系统综述了联三吡啶配体及其衍生物的组装策略及其过渡金属配合物的光化学与光物理性能，包括单极、二极及多极配体以及由这类配体组装得到的各种拓扑结构的单核、多核过渡金属配合物，如线型金属寡聚物、金属聚合物、金属大环化合物、有机金属树枝状化合物等，并介绍这些配合物在该领域研究和应用前景。

关键词： 联三吡啶配体, 组装, 过渡金属配合物, 光物理与光化学性能

Metal-ligand coordination is one of the most important interactions used in supramolecular chemistry. Oligopyridine ligands can coordinate with many transition metal ions and form stable complexes with unique magnetic, photophysical and electrochemical properties, so transition metal complexes based on terpyridine ligands have been attracting considerable attention. This review systematically summarizes the assembly methodologies for terpyridine ligand and its derivatives and the photophysical and photochemical properties of terpyridine transition metal complexes, including monotopic, ditopic and multitopic terpyridine ligands and mononuclear, multinuclear complexes with various topologic structures, such as linear metal oligomers, metallopolymers, metallomacrocyclic compounds and organic-metal dendrimers. Meanwhile, the perspectives in their applications and studies are also emphasized.

Contents
1 Introduction
2 Mononuclear metal complexes
2.1 Assembly strategies and physical properties of mononuclear metal complexes
2.2 Assembly of mononuclear Ru(Ⅱ) complexes
2.3 Photophysical properties of mononuclear Ru(Ⅱ) complexes
2.4 Photophysical properties of other mononuclear metal complexes
3 Multinuclear metal complexes
3.1 Multinuclear linear metallo-oligomers
3.2 Metallopolymers
3.3 Metallopolygons
3.4 3-Dimensional metallomacromolecules
4 Research situations in China
5 Conclusion

Key words: terpyridine ligands, assembly, transition metal complexes, photophysical and photochemical properties

中图分类号: 

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