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化学进展 2009, Vol. 21 Issue (10): 2001-2008 前一篇   后一篇

• 综述与评论 •

绿色化学原则在发展*

蔡卫权1**;程蓓2;张光旭1;刘小平1   

  1. (1. 武汉理工大学化学工程学院 武汉 430070；2. 武汉理工大学材料科学与工程学院 武汉 430070)
  • 收稿日期:2009-01-06 修回日期:2009-02-09 出版日期:2009-10-24 发布日期:2009-10-09
  • 通讯作者: 蔡卫权 E-mail:wqcai@home.ipe.ac.cn
  • 基金资助:

    省级资助

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Developing the Green Chemistry Principles

Cai Weiquan1**;  Cheng Bei2;  Zhang guangxu1;  Liu Xiaoping1   

  1. (1. School of Chemical Engineering, Wuhan University of Technology, Wuhan 430070, China；2. School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China)
  • Received:2009-01-06 Revised:2009-02-09 Online:2009-10-24 Published:2009-10-09
  • Contact: Cai Weiquan E-mail:wqcai@home.ipe.ac.cn

从源头上减少或消除化学污染是绿色化学的理想，而绿色化学原则是对绿色化学内涵的最好诠释。自Anastas等人在1998年提出12条绿色化学原则以来，Anastas本人和Winterton又从技术、经济和商业等角度出发，分别提出了另12条绿色化学补充原则。但这些原则中缺乏清晰地反映与环境影响高度相关的概念，绿色工程的概念和绿色工程原则由此应运而生。Tang等人随后将Anastas等人提出的绿色化学原则和绿色工程原则简化为“IMPROVEMENTS PRODUCTIVELY”中字母表示的24条原则，以便于记忆、交流和推广。然而，上述原则主要是直觉和常识的结晶，难以清晰地反映绿色化学的目标和相关研究领域的内在联系。预计，从绿色的认定，原子经济性和有效质量收率等的兼顾，生命周期评价数据的采集，催化剂的性质及其反应、分离和循环使用的一体化以及绿色程度评价指标和评价方法的优化与平衡等几方面发展和凝炼绿色化学原则将是长期的研究课题。

关键词： 绿色化学, 绿色工程, 原则, 可持续发展

To reduce or eliminate chemical pollution in origin is the ideal of green chemistry, while its principles are the best elucidation for its essence. Based on the 12 well-known principles proposed by Anastas et al in 1998, the 12 more principles were complemented by Anastas himself and Winterton, respectively from technical, economic and commercial considerations. Unfortunately, these principles don’t explicitly include concept which is highly relevant to environmental impact. As a result, the concept of green engineering and its principles were proposed. Tang et al subsequently simplified the original 12 green chemistry and 12 green engineering principles proposed by Anastas et al as the mnemonic, communicative and popularized “IMPROVEMENTS PRODUCTIVELY”. However, the principles are still intuitive and commonsensible and thus can’t explicitly reflect the inherent relationships between the goal and related research fields of green chemistry. It is estimated that the green chemistry principles which are centered around designation of green, coordination of Atom Economy and Effective Mass Yield etc., data collection of life-cycle assessment, integration of properties of catalyst with reaction, separation and recycling use, and the optimization and balance of evaluation metrics and methods to greenness etc. still need to be developed and upgraded over a long period of time.

Contents
1 Proposition of the green chemistry principles
2 Development of the green chemistry principles
3 From the green chemistry principles to the green engineering principles
4 Several considerations for developing the green chemistry principles
4.1 Looking before you leap while labeling the green
4.2 Coordination of Atom Economy and Effective Mass Yield etc.
4.3 Data collection of life-cycle assessment
4.4 Integrating properties of catalyst with reaction, separation and recycle
4.5 Optimization and balance of evaluation metrics and methods to greenness

Key words: green chemistry, green engineering, principles, sustainable development

中图分类号: 

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摘要

绿色化学原则在发展*