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化学进展 2009, Vol. 21 Issue (09): 1980-1986 前一篇   后一篇

• 综述与评论 •

MEMS微型燃料电池*

刘晓为1,2;张博1**;张宇峰1;张鹏1   

  1. (1. 哈尔滨工业大学MEMS中心   |哈尔滨150001; 2. 微系统与微结构制造教育部重点实验室   |哈尔滨 150001)
  • 收稿日期:2008-09-11 修回日期:2008-12-01 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 张博 E-mail:edchang@126.com
  • 基金资助:

    863项目;国家自然科学基金

MEMS-Based Micro Fuel Cells

Liu Xiaowei1, 2 ;  Zhang Bo1** ;  Zhang Yufeng1 ; |Zhang Peng1   

  1. (1.MEMS Center, Harbin Institute of Technology, Harbin 150001, China;2.Key Laboratory of Micro-Systems and Micro-structures Manufacturing, Ministry of Education, Harbin Institute of Technology, Harbin 150001, China)
  • Received:2008-09-11 Revised:2008-12-01 Online:2009-09-24 Published:2009-09-15
  • Contact: Zhang Bo E-mail:edchang@126.com

随着微能源技术的迅速发展和市场需求的不断增大,基于微机电系统(microelectromechanical systems,MEMS)技术的微型燃料电池由于其巨大应用前景逐渐得到社会的更多关注。本文详细介绍了国外微型燃料电池的应用概况,简要论述了将MEMS技术应用于微型燃料电池制作的可行性以及MEMS微型燃料电池的类型特点,并结合关键组件极板和膜电极,系统地总结了近几年来MEMS微型燃料电池的研究进展和成果,最后分析了目前存在的问题和发展趋势以及我国大力发展MEMS微型燃料电池的迫切需求。

With the rapid development and increasing market demand in the field of micro power sources, micro fuel cells based on microelectromechanical systems (MEMS) technology have been attracting more and more social attentions due to the great application prospects in the future. In this paper, the general situation of the overseas applications of micro fuel cells is introduced in detail. The feasibility of micro fuel cells fabrication using MEMS technology and characteristics of different types of MEMS-based micro fuel cells are briefly discussed. Combining with the critical components including the monopolar plate and membrane electrode assembly (MEA), the latest research progress of MEMS-based micro fuel cells are also summarized systematically. Finally, the existing problems and development trend are analyzed, and the urgent demand for developing MEMS-based micro fuel cells in our country is demonstrated.

Contents
1 Introduction
2 General situation of the overseas applications of micro fuel cells
2.1 General situation of the military applications
2.2 General situation of the civil applications
3 Research progress of MEMS-based micro fuel cells
3.1 The monopolar plate
3.2 The membrane electrode assembly (MEA)
4 Existing problems and prospects analysis of MEMS-based micro fuel cells
4.1 The monopolar plate materials
4.2 The MEA fabrication methods
4.3 The system design
5 Conclusions

中图分类号: 

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[ 1 ]  王观成(Wang G C) . 电池工业( Chinese Battery Industry) ,2005 , 10 (1) : 36 —37
[ 2 ]  [2008208201 ] . http://www.fuelcelltoday.com
[ 3 ]  衣宝廉(Yi B L) . 燃料电池———原理·技术·应用(Fuel Cells: Principle , Technology and Application) . 北京: 化学工业出版社(Beijing: Chemical Industry Press) , 2003
[ 4 ]  [2008208201 ] . http://www.neahpower.com
[ 5 ]  刘路(Liu L) , 解晶莹(Jie J Y) . 电源技术(Chinese Journal of Power Sources) , 2002 , 26 (6) : 470 —474
[ 6 ]  [2008-08-01 ] . http://www.ultracellpower.com
[ 7 ]  [2008-08-01 ] . http://www.mtimicrofuelcells.com
[ 8 ]  [2008-08-01 ] . http://www.protonex.com/products/index.aspx
[ 9 ]  [2008-08-01 ] . http://it.sohu.com/20070713/n251041604.shtml
[10 ]  [2008-08-01 ] . http://www.medistechnologies.com
[11 ]  [2008-08-01 ] . http://arch.pconline.com.cn/notebook/news/10303/138366.html
[12 ]  [2008-08-01 ] . http://china.nikkeibp.com.cn
[13 ]  [2008-08-01 ] . http://www.antig.com/products/products-modules.htm
[14 ]  Kelly S C , Deluga GA , Smyrl W H. J . Electrochemical Solid State Letters , 2000 , 3 (9) : 407 —409
[15 ]  Kelly S C , Deluga GA , Smyrl W H. J . AICHEJournal , 2002 , 48 :1071 —1082
[16 ]  Maynard HL , Meyers J P. Proceedings of the 2nd Annual Small Fuel Cells and Battery Technologies for Portable Power Applications International Symposium. New Orleans , 2000
[17 ]  Meyers J P , Maynard H L. J . Power Sources , 2002 , 109 : 76 —88
[18 ]  Lee S J , Chang-Chien A , Cha SW, et al . J . Power Sources , 2002 ,112 : 410 —418
[19 ]  Yu J R , Cheng P , Ma Z Q , et al . J . Power Sources , 2003 , 124 :40 —46
[20 ]  Lu G Q , Wang C Y, Yen T J , et al . Electrochimica Acta , 2004 ,49 : 821 —828
[21 ]  Kim J Y, Kwon O J , Hwang S M, et al . J . Power Sources , 2006 ,161 : 432 —436
[22 ]  Yu J R , Cheng P , Ma Z Q , et al . J . Electrochimica Acta , 2003 ,48 : 1537 —1541
[23 ]  王涛(Wang T) , 陈聪(Chen C) , 李巨峰(Li J F) 等. 高等学校化学学报(Chemical Journal of Chinese Universities) , 2004 , 25(10) : 1928 —1930
[24 ]  李巨峰(Li J F) , 王涛(Wang T) , 夏保佳(Xia B J ) . 电池(Battery Bimonthly) , 2005 , 35 (1) : 21 —22
[25 ]  郑丹(Zheng D) , 张熙贵(Zhang X G) , 张鲲(Zhang K) 等. 应用化学(Chinese Journal of Applied Chemistry) , 2007 , 24 (6) :723 —725
[26 ]  Zhang X G, Zheng D , Wang T, et al . J . Power Sources , 2007 ,166 : 441 —444
[27 ]  Cao J Y, Zou Z Q , Huang Q H , et al . J . Power Sources , 2008 ,185 : 433 —438
[28 ]  王晓红(Wang X H) , 谢克文(Xie KW) , 姜英琪(Jiang Y Q)等. 半导体学报(Chemical Journal of Semiconductors) , 2005 , 26(7) : 1437 —1441
[29 ]  钟凌燕(Zhong L Y) , 王晓红(Wang X H) , 姜英琪(Jiang YQ)等. 传感技术学报(Chemical Journal of Sensors and Actuators) ,2006 , 19 (5) : 2163 —2166
[30 ]  Zhong L Y, Wang X H , Jiang Y Q , et al . Sensors and Actuators A ,2008 , 143 : 70 —76
[31 ]  Hahn R , Wagner S , Schmitz A , et al . J . Power Sources , 2004 ,131 : 73 —78
[32 ]  Lu G Q , Wang C Y. J . Power Sources , 2005 , 144 : 141 —145
[33 ]  Lee S J , Chen Y P , Huang C H. J . Power Sources , 2005 , 145 :369 —375
[34 ]  Lee S J , Lee YM, Lee C Y. J . Power Sources , 2007 , 171 : 148 —154
[35 ]  Wong C W, Zhao T S , Ye Q , et al . J . Electrochemical Society ,2005 , 152 (8) : A1600 —A1605
[36 ]  Yang H , Zhao T S , Ye Q. J . Power Sources , 2005 , 139 : 79 —90
[37 ]  Yang H , Zhao T S. Electrochimica Acta , 2005 , 50 : 3243 —3252
[38 ]  Wong C W, Zhao T S , Ye Q , et al . J . Power Sources , 2006 , 155 :291 —296
[39 ]  Chen R , Zhao T S , Liu J G. J . Power Sources , 2006 , 157 : 351 —357
[40 ]  Xu C , Zhao T S. Electrochemistry Communications , 2007 , 9 : 497 —503
[41 ]  Chan Y H , Zhao T S , Chen R , et al . J . Power Sources , 2008 ,178 : 118 —124
[42 ]  Hsieh S S , Huang C F , Feng C L. Micron , 2008 , 39 : 263 —268
[43 ]  Shah K, Shin W C , Besser R S. Sensors and Actuators B , 2004 ,97 : 157 —167
[44 ]  Cha H Y, Choi H G, NamJ D , et al . Electrochimica Acta , 2004 ,50 : 795 —799
[45 ]  Cha S W, Hayre R O , Park Y I , et al . J . Power Sources , 2006 ,161 : 138 —142
[46 ]  Chan S H , Nguyen N T, Xia Z, et al . J . Micromech. Microeng. ,2005 , 15 : 231 —236
[47 ]  Ito T, Kunimatsu M. Electrochemistry Communications , 2006 , 8 :91 —94
[48 ]  Maranzana G, Lottin O , Colinart T, et al . J . Power Sources , 2008 ,180 : 748 —754
[49 ]  Pichonat T, Gauthier-Manuel B , Hauden D. Chem. Eng. J . , 2004 ,101 : 107 —111
[50 ]  Pichonat T, Gauthier-Manuel B. Microsyst . Technol . , 2006 , 12 :330 —334
[51 ]  Pichonat T, Gauthier-Manuel B. J . Micromech. Microeng. , 2005 ,15 : S179 —S184
[52 ]  Gold S , Chu K L , Lu C , et al . J . Power Sources , 2004 , 135 :198 —203
[53 ]  Yamazaki Y. J . Electrochimica Acta , 2004 , 50 : 663 —666
[54 ]  刘晓为(Liu X W) , 索春光(Suo C G) , 张宇峰(Zhang Y F)等. 传感技术学报(Chemical Journal of Sensors and Actuators) ,2006 , 19 (5) : 2167 —2170
[55 ]  郑丹(Zheng D) , 田娟(Tian J ) , 张熙贵(Zhang X G) 等. 无机材料学报(Journal of Inorganic Materials) , 2006 , 21 (6) : 1367 —1372
[56 ]  Guo DJ , Li HL. J . Electroanalytical Chemistry , 2004 , 573 : 197 —202
[57 ]  He Z B , Chen J H , Liu D Y, et al . Materials Chemistry and Physics , 2004 , 85 : 396 —401
[58 ]  He Z B , Chen J H , Liu D Y, et al . Diamond &Related Materials ,2004 , 13 : 1764 —1770
[59 ]  Jeng K T, Chien C C , Hsu N Y, et al . J . Power Sources , 2006 ,160 : 97 —104
[60 ]  Lo M Y, Liao I H , Huang C C. International J . Hydrogen Energy ,2007 , 32 : 731 —735
[61 ]  Tang H , Chen J H , Huang Z P , et al . Carbon , 2004 , 42 : 191 —197
[62 ]  黄辉(Huang H) , 张文魁(Zhang W K) , 马淳安(Ma C A) 等.应用化学(Chinese Journal of Applied Chemistry) , 2002 , 19 (8) :759 —763
[63 ]  Li W, Liang C , Xin Q , et al . J . Phys. Chem. B , 2003 , 107 (26) :6292 —6299
[64 ]  Rajalakshmi N , Ryu H , Shaijumon M M, et al . J . Power Sources ,2005 , 140 : 250 —257
[65 ]  Reshetenko T V , Kim H T, Kweon H J . Electrochimica Acta , 2008 ,53 : 3043 —3049
[66 ]  Motokawa S , Mohamedi M, Momma T, et al . Electrochemistry Communications , 2004 , 6 : 562 —565
[67 ]  Han S , Lee J W, Kwak C , et al . J . Power Sources , 2007 , 167 :74 —78
[68 ]  Zhang Y, Lu J , Shimano S , et al . Electrochemistry Communications ,2007 , 9 : 1365 —1368
[69 ]  王诚(Wang C) , 毛宗强(Mao Z Q) , 陈荣华(Chen R H) 等.化学进展(Progress in Chemistry) , 2006 , 18 (1) : 30 —35
[70 ]  Guo Z, Cao Y. J . Power Sources , 2004 , 132 : 86 —91
[71 ]  Yang Y, Liang Y C. J . Power Sources , 2007 , 165 : 185 —195

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摘要

MEMS微型燃料电池*