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化学进展 2009, Vol. 21 Issue (09): 1969-1979 前一篇   后一篇

• 综述与评论 •

一维纳米材料在染料敏化太阳电池中的应用*

盛显良1;刘娜仁1;翟锦2**;安丽平1   

  1. （1 内蒙古农业大学理学院    |呼和浩特 010018|2 中国科学院化学研究所   |北京 100086）
  • 收稿日期:2008-10-27 修回日期:2008-11-14 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 翟锦 E-mail:zhaijin@iccas.ac.cn
  • 基金资助:

    省级资助

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Application of One-Dimensional Nanomaterials in Dye-Sensitized Solar Cells

Sheng Xianliang1; |Liu Naren1; |Zhai Jin2**; |An Liping1   

  1. (1. College of Science, Inner Mongolia Agriculture University, Hohhot 010018, China|2. Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China)
  • Received:2008-10-27 Revised:2008-11-14 Online:2009-09-24 Published:2009-09-15
  • Contact: Zhai Jin E-mail:zhaijin@iccas.ac.cn

一维纳米材料以无序或有序、单一或复合的形式被广泛应用于染料敏化太阳电池（dye-sensitized solar cells，DSSC）中，并展示其独特的电学和光学特性。基于一维纳米材料在DSSC中的应用而发展起来的“电子高速公路概念”越来越受到研究者的重视。本文综述了一维纳米材料在DSSC中的应用研究进展，重点介绍光阳极中一维纳米材料的电子学特性和合成方法、光阳极的制备特点、电池性能及其优缺点等，并就一维纳米材料在DSSC中的应用前景进行了展望。

关键词： 染料敏化太阳电池, 电子高速公路概念, 一维纳米材料, 有序和无序, 光阳极

One-dimensional nanomaterials are widely used in dye-sensitized solar cells (DSSC) in the form of ordered or disordered, single or composite structure and display their unique characteristics in electronics and optics. Researchers paid much more attention to “electron expressway concept” based on one-dimensional nanomaterials in DSSC. The progress of the application of one-dimensional nanomaterials in DSSC is reviewed in this paper. We mainly introduce the electronic traits and the synthetic methods of one-dimensional nanomaterials in photoanodes, the fabrication method of photoanodes, the performance of the solar cells and its advantages and disadvantages. The foreground of one-dimensional nanomaterials used in DSSC are discussed.

Contents
1 Introduction
2 Photoanodes with disordered one-dimensional nanomaterials
2.1 Composite photoanodes with disordered one-dimensional nanomaterials and nanoparticles
2.2 Photoanodes with single disordered one-dimensional TiO2 nanomaterials
3 Photoanodes with aligned and ordered one-dimensional nanomaterials
3.1 Photoanodes with aligned and ordered one-dimensional ZnO nanomaterials
3.2 Photoanodes with aligned and ordered one-dimensional TiO2 nanomaterials
4 Application of one-dimensional nanomaterials in other parts of DSSC
4.1 Application of one-dimensional nanomaterials in electrolytes
4.2 Application of one-dimensional nanomaterials in counter electrodes
5 Conclusion

Key words: dye-sensitized solar cells, electron expressway concept, one-dimensional nanomateials, ordered and disordered, photoanode

中图分类号: 

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[ 1 ] 　O’Regan B , Grøtzel M. Nature , 1991 , 353 (6346) : 937 —940
[ 2 ] 　Gr? tzel M. Nature , 2001 , 414 (6861) : 338 —334
[ 3 ] 　Solbrand A , Henningsson A , Hagfeldt A , et al . J . Phys. Chem. B ,1999 , 103 (7) : 1078 —1083
[ 4 ] 　Nakade S , Kambe S , Yanagida S , et al . J . Phys. Chem. B , 2001 ,105 (38) : 9150 —9152
[ 5 ] 　Kambe S , Nakade S , Yanagida S , et al . J . Phys. Chem. B , 2002 ,106 (11) : 2967 —2972
[ 6 ] 　Kopidakis N , Benksten KD , Frank AJ , et al . J . Phys. Chem. B ,2003 , 107 (41) : 11307 —11315
[ 7 ] 　Benkstein KD , Kopidakis N , Frank AJ , et al . J . Phys. Chem. B ,2003 , 107 (31) : 7759 —7757
[ 8 ] 　Bisquert J , Hodes C D , Ruhle S , et al . J . Phys. Chem. B , 2004 ,108 (24) : 8106 —8118
[ 9 ] 　Turner GM, Beard M C , Schmuttenmaer C A. J . Phys. Chem. B ,2002 , 106 (45) : 11716 —11719
[10 ] 　Kopidakis N , Schiff E A , Frank A J , et al . J . Phys. Chem. B ,2000 , 104 (16) : 3930 —3939
[11 ] 　Chen S J , Liu C L , Shao C L , et al . Adv. Mater. , 2005 , 17 (5) :586 —590
[12 ] 　Dresselhausa M S , Linb YM, Rabinc O , et al . Mater. Sci . Eng.C. , 2003 , 23 (1/2) : 129 —140
[13 ] 　Jiu J T, Isoda S , Adachi M, et al . J . Phys. Chem. B , 2006 , 110(5) : 2087 —2092
[14 ] 　Suzuki Y, Ngamsinlapasathian S , Yoshida R , et al . Cent . Eur. J .Chem. , 2006 , 4 (3) : 476 —488
[15 ] 　Asagoe K, Ngamsinlapasathian S , Suzuki Y, et al . Cent . Eur. J .Chem. , 2006 , 5 (2) : 605 —619
[16 ] 　Kim D , Ghicov A , Schmuki P , et al . J . Am. Chem. Soc. , 1993 ,130 (90) : 16454 —16455
[17 ] 　Yoon J H , Jang S R , Kim KJ , et al . J . Photochem. Photobio. A:Chem. , 2006 , 180 (1/2) : 184 —188
[18 ] 　Kymakis E , Alexandou I , Amaratunga G A. Synth. Met . , 2002 ,127 (1/3) : 59 —62
[19 ] 　Musa I , Baxendale M, Amaratunga GA , et al . Synth. Met . , 1999 ,102 (1/3) : 1250
[20 ] 　Haggenmueller R , Gommans H H , Fisher J E , et al . Chem. Phys.Lett . , 2000 , 330 (3P4) : 219 —225
[21 ] 　Llahaut E , Peigney A , Laurent C , et al . Acta Mater. , 2000 , 48(14) : 3803 —3812
[22 ] 　Ago H , Petrisch K, Shaffer M S , et al . Adv. Mater. , 1999 , 11(15) : 1281 —1285
[23 ] 　Jung K H , Hong J S , Kim KJ , et al . Chem. Lett . , 2002 , 31 (8) :864 —865
[24 ] 　Jung K H , Hong J S , Kim KJ , et al . Bull . Korean Chem. Soc. ,2003 , 24 (10) : 1501 —1504
[25 ] 　Jang S R , Vittal R , Kim K J , et al . Langmuir , 2004 , 20 (22) :9807 —9810
[26 ] 　Kim S L , Jang S R , Kim KJ , et al . J . Appl . Electrochem. , 2006 ,36 (12) : 1433 —1439
[27 ] 　Lee T Y, Alegaonkar P S , Yoo J B. Thin Solid Films , 2007 , 515(12) : 5131 —5135
[28 ] 　Lee K M, Hu C W, Ho K C , et al . Sol . Energy Mater. Sol . Cells ,2008 , 92 (12) : 1628 —1633
[29 ] 　Kongkanand A , Domníguez R M, Kamat P V. Nano Lett . , 2007 , 7(3) : 676 —680
[30 ] 　Kasuga T, Hiramatsu M, Hoson A , et al . Langmuir , 1998 , 14(11) : 3160 —3163
[31 ] 　Kasuga T, Hiramatsu M, Hoson A , et al . Adv. Mater. , 1999 , 11(15) : 1307 —1311
[32 ] 　Adachi M, Murata Y, Takao J , et al . J . Am. Chem. Soc. , 2004 ,126 (45) : 14943 —14949
[33 ] 　Kang S H , KimJ Y, Sung Y E , et al . J . Phys. Chem. C , 2007 ,111 (26) : 9614 —9623
[34 ] 　Ngamsinlapasathian S , Sakulkhaemaruethai S , Yoshikawa S , et al .J . Photochem. Photobio. A: Chem. , 2004 , 164 (1P3) : 145 —151
[35 ] 　Lin C J , Yu W Y, Chien S H , Appl . Phys. Lett . , 2007 , 91 (23) :art . no. 233120
[36 ] 　Dürr M, Schmid A , Nelles G, et al . Nat . Mater. , 2005 , 4 (8) :607 —611
[37 ] 　Pavasupree S , Ngamsinlapasathian S , Yoshikawa S , et al . J .Photochem. Photobio. A: Chem. , 2006 , 184 (1P2) : 163 —169
[38 ] 　Tang B , Wu Y Y. J . Phys. Chem. B , 2006 , 110 (32) : 15932 —15938
[39 ] 　Pan K, Zhang Q L , Bai YB , et al . Thin Solid films , 2007 , 515 (7/8) : 4085 —4091
[40 ] 　Chen Z G, Li F Y, Huang C H , et al . J . Power Sources , 2007 , 171(2) : 990 —998
[41 ] 　Pang S , Xie T F , Wang D J , et al . J . Phys. Chem. C , 2007 , 111(49) : 18417 —18422
[42 ] 　Zhao Y, Zhai J , Wei T X, et al . J . Mater. Chem. , 2007 , 17 (48) :5084 —5089
[43 ] 　Wang D A , Yu B , Liu W M, et al . Mater. Chem. Phys. , 2009 ,113 : 602 —606
[44 ] 　Uchida S , Chiba R , Tomiha M, et al . Electrochemistry , 2002 , 70(6) : 418 —420
[45 ] 　Adachi M, Murata Y, Yoshikawa S , et al . J . Electrochem. Soc. ,2003 , 150 (8) : G488 —G493
[46 ] 　Ohsaki Y, Masaki N , Yanagida S , et al . Phys. Chem. Chem.Phys. , 2005 , 7 (24) : 4157 —4163
[47 ] 　Wei M D , Konishi Y, Zhou H S , et al . J . Electrochem. Soc. ,2006 , 153 (6) : A1232 —A1236
[48 ] 　Kim G D , Seo H K, Shin H S , et al . Electrochem. Commun. ,2006 , 8 (11) : 961 —966
[49 ] 　Flores I C , Freitas J N , Nogueira A F , et al . J . Photochem.Photobio. A: Chem. , 2007 , 189 (2P3) : 153 —160
[50 ] 　Shen Q , Sato T, Toyoda T, et al . Thin Solid Films , 2006 , 499 (1/2) : 299 —305
[51 ] 　Jiu J T, Wang F M, Isoda S , et al . Chem. Lett . , 2005 , 34 (11) :1506 —1507
[52 ] 　Jiu J T, Isoda S , Adachi M, et al . J . Phys. Chem. B , 2006 , 110(5) : 2087 —2092
[53 ] 　Kang S H , Choi S H , Sung Y E , et al . Adv. Mater. , 2008 , 20(1) : 54 —58
[54 ] 　Yao Q H , Liu J F , Peng Q , et al . Chem. Asian J . , 2006 , 1 (5) :737 —741
[55 ] 　Adachi M, Murata Y, Takao J , et al . J . Am. Chem. Soc. , 2004 ,126 (45) : 14943 —14949
[56 ] 　Wang X Y, Kim Y G, Drew C , et al . Nano Lett . , 2004 , 4 (2) :331 —334
[57 ] 　Pinto N J , Johnson A T, MacDiarmid A G, et al . Appl . Phys.Lett . , 2003 , 83 (20) : 4244 —4246
[58 ] 　Schreuder2Gibson H , Gibson P , Senecal K, et al . J . Adv. Mater. ,2002 , 34 (1) : 44 —47
[59 ] 　Song M Y, Kim D K, Kim D Y, et al . Nanotechnology , 2004 , 15(12) : 1861 —1865
[60 ] 　Song M Y, Ahn Y R , Kim D Y, et al . Appl . Phys. Lett . , 2005 ,87 (11) : art . no. 113113
[61 ] 　Onozuka K, Ding B , Shiratori S , et al . Nanotechnology , 2006 , 17(4) : 1026 —1031
[62 ] 　Guo M, Diao P , Cai S M. Chin. Chem. Lett . , 2004 , 15 ( 9) :1113 —1116
[63 ] 　Martinson A B F , ElamJ W, Hupp J T, et al . Nano Lett . , 2007 , 7(8) : 2183 —2187
[64 ] 　Guo M, Diao P , Cai S M, et al . Appl . Sur. Sci . , 2005 , 249 (1/4) : 71 —75
[65 ] 　Guo M, Diao P , Cai S M, et al . J . Solid State Chem. , 2005 , 178(9) : 3210 —3215
[66 ] 　Martinson A B F , McGarrah J E , Hupp J T, et al . Phys. Chem.Chem. Phys. , 2005 , 7 (24) : 4157 —4163
[67 ] 　Ravirajan P , PeiróAM, Nelson J , et al . J . Phys. Chem. B , 2006 ,110 (15) : 7635 —7639
[68 ] 　Galoppini E , Rochford J , Boschloo G, et al . J . Phys. Chem. B ,2006 , 110 (33) : 16159 —16161
[69 ] 　Baxter J B , Aydil E S. Appl . Phys. Lett . , 2005 , 86 (05) : art .no. 053114
[70 ] 　Baxter J B , Aydil E S. Sol . Energy Mater. Sol . Cells , 2005 , 90(5) : 607 —622
[71 ] 　Baxter J B , Walker A M, Aydil E S. Nanotechnology , 2006 , 17(11) : S304 —S312
[72 ] 　Ku C H , Wu J J . Appl . Phys. Lett . , 2007 , 91 ( 9) : art . no.093117
[73 ] 　Ku C H , Yang H H , Wu J J , et al . Cryst . Growth Des. , 2008 , 8(1) : 283 —290
[74 ] 　Law M, Greene L E , Yang P D , et al . Nat . Mater. , 2005 , 4 (6) :455 —459
[75 ] 　Law M, Greene L E , Yang P D , et al . J . Phys. Chem. B , 2006 ,110 (45) : 22652 —22663
[76 ] 　Nagai M, Gao Y F. Langmuir , 2006 , 22 (8) : 2936 —3940
[77 ] 　Suh D I , Lee S Y, Lee S K, et al . Chem. Phys. Lett . , 2007 , 442(4/6) : 348 —353
[78 ] 　Pradhan B , Batabyal S K, Pal A J . Sol . Energy Mater. Sol . Cells ,2007 , 91 (5) : 769 —773
[79 ] 　Joanni E , Savu R , Góes M S , et al . Scripta Mater. , 2007 , 57 (3) :277 —280
[80 ] 　Tornow J , Ellmer K, Schwarzburg K, et al . Thin Solid films , 2008 ,516 (20) : 7139 —7143
[81 ] 　Sheng XL , Zhao Y, Zhai J , et al . Appl . Phys. A , 2007 , 87 (4) :715 —719
[82 ] 　Sheng XL , Zhao Y, Zhai J , et al . Chem. Eng. Comm. , 2008 , 195(4) : 375 —385
[83 ] 　盛显良(Sheng X L) , 赵勇(Zhao S Y) , 翟锦(Zhai J ) 等. 化学进展(Progress in Chemistry) , 2007 , 19 (1) : 59 —65
[84 ] 　Macák J M, Tsuchiya H , Schmuki P , et al . Electrochem.Commun. , 2005 , 7 (11) : 1133 —1137
[85 ] 　Mor G K, Shankar K, Grimes A , et al . Nano Lett . , 2006 , 6 (2) :215 —218
[86 ] 　Paulose M, Shankar K, Grimes A , et al . J . Phys. D: Appl .Phys. , 2006 , 39 (16) : 2498 —2503
[87 ] 　Shankar K, Mor G K, Grimes A , et al . Nanotechnology , 2007 , 18(6) : 065707
[88 ] 　Shankar K, Bandara J , Grimes A , et al . Nano Lett . , 2008 , 8 (6) :1654 —1659
[89 ] 　Park H , Yang D J , Choi W Y, et al . J . Electroceram , 2007 , doi10. 1007Ps108322007293412x
[90 ] 　Yip C T, Mak S C K, Djuris ’ ic’ A B , et al . Appl . Phys. A , 2008 ,92 (3) : 589 —593
[91 ] 　Kuang D B , Zakeeruddin S M, Grøtzel M, et al . ACS NANO ,2008 , 2 (6) : 1113 —1116
[92 ] 　Zhu K, Neale N R , Frank A J , et al . Nano Lett . , 2007 , 7 (1) :69 —74
[93 ] 　Zhu K, Vinzant T B , Frank A J , et al . Nano Lett . , 2007 , 7 (12) :3739 —3346
[94 ] 　Keis K, Lindgren J , Hagfeldt A , et al . Langmuir , 2000 , 16 (10) :4688 —4694
[95 ] 　Bedja I , Kamat P V , Hotchandani S , et al . Langmuir , 1997 , 13(8) : 2398 —2403
[96 ] 　Asbury J B , Wang YQ , Lian T Q. J . Phys. Chem. B , 1999 , 103(32) : 6643 —6647
[97 ] 　Bauer C , Boschloo G, Hagfeldt A , et al . J . Phys. Chem. B , 2001 ,105 (24) : 5585 —5588
[98 ] 　Quitana M, Edvinsson T, Boschloo G, et al . J . Phys. Chem. C ,2007 , 111 (2) : 1035 —1041
[99 ] 　Cheung K Y, Yip C T, Djuris ’ ic’ A B , et al . Adv. Func. Mater. ,2007 , 17 (4) : 555 —562
[100 ] Ong K G, Varghese O K, Grimes A , et al . Sol . EnergyMater. Sol .Cells , 2007 , 91 (5) : 250 —257
[101 ] Yang D J , Park H , Choi W Y, et al . J . Phys. Chem. Solids ,2008 , 69 (5/6) : 1272 —1275
[102 ] Fabregat-Santiago F , Barea E M, Bisquert J , et al . J . Am. Chem.Soc. , 2008 , 130 (34) : 11312 —11316
[103 ] Jennings J R , Ghicov A , Peter L M, et al . J . Am. Chem. Soc. ,2008 , 130 (34) : 13364 —13375
[104 ] Martinson A B F , Elam J W, Hupp J T, et al . Nano Lett . , 2008 ,(89) : 2862 —2866
[105 ] Park J H , Lee T W, Kang M G. Chem. Comm. , 2008 , 2867 —2869
[106 ] Charoensirithavorn P , Ogomi Y, Yoshikawa S , et al . J . Cryst .Growth , 2009 , 311 (3) : 757 —759
[107 ] Usui H , Matsui H , Yanagida S , et al . J . Photochem. Photobio. A:Chem. , 2004 , 164 (1P3) : 163 —169
[108 ] Zhang X H , Wang S M, Xu Z X, et al . J . Photochem. Photobio.A: Chem. , 2008 , 198 (2P3) : 288 —292
[109 ] Akhtar M S , Chun J M, Yang O B. Electrochem. Commun. , 2007 ,9 (12) : 2833 —2837
[110 ] Murakami T N , Grøtzel M. Inorganica Chimica Acta , 2008 , 361(3) : 572 —580
[111 ] Suzuki K, Yamanoto M, Yanagida S , et al . Chem. Lett . , 2003 , 32(1) : 28 —29
[112 ] Ramasamy E , Lee W J , Song J S , et al . Electrochem. Commun. ,2008 , 10 (7) : 1087 —1089
[113 ] Anandan S , Wen X G, Yang S H. Mater. Chem. Phys. , 2005 , 93(1): 35 —40
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