English
往期目录
新闻公告
More
化学进展 2009, Vol. 21 Issue (09): 1954-1962 前一篇   后一篇

所属专题： 金属有机框架材料

• 综述与评论 •

金属有机骨架化合物（MOFs）作为储氢材料的研究进展*

贾超|原鲜霞**|马紫峰   

  1. （上海交通大学化学工程系 |上海 |200240）
  • 收稿日期:2008-09-25 修回日期:2009-01-13 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 原鲜霞 E-mail:yuanxx519@yahoo.com.cn
  • 基金资助:

    973项目;国家自然科学基金

下载PDF ( 5952 ) 引用
导出

Metal-Organic Frameworks (MOFs) as Hydrogen Storage Materials

Jia Chao;  |Yuan Xianxia** ; |Ma Zifeng   

  1. （Department of Chemical Engineering, Shanghai Jiao Tong University, Shanghai |200240, China）
  • Received:2008-09-25 Revised:2009-01-13 Online:2009-09-24 Published:2009-09-15
  • Contact: Yuan Xianxia E-mail:yuanxx519@yahoo.com.cn

氢的储存对于21世纪氢经济时代的发展至关重要。金属有机骨架化合物（MOFs）因具有纯度高、结晶度高、成本低、能够大批量生产和结构可控等优点，在气体存储尤其是氢的存储方面展示出广阔的应用前景。本文详细综述了近年来MOFs类化合物（MOF-5、IRMOFs和MMOMs）作为储氢材料的研究进展，介绍了各种用于改善MOFs材料储氢性能的结构改性方法，总结了MOFs储氢材料在理论模拟计算方面的研究进展，并指出了MOFs储氢材料目前存在的不足和发展方向。

关键词： 金属有机骨架化合物, 储氢材料, 中心金属离子, 有机联结体

Hydrogen storage technology is of great importance for hydrogen economy in the 21st century. With the merits of high purity, high crystallization, low cost, large scale productive capability and structure controllable characteristics, metal-organic frameworks (MOFs) have been proved to be very promising in the field of gas storage especially hydrogen storage. In this paper, the research progress of MOFs, including MOF-5, IRMOFs and MMOMs, as hydrogen storage materials in recent years is detailedly reviewed, the structure-modifying technologies for improving hydrogen storage capability of MOFs are systematically introduced, the research progress of theoretical simulation of MOFs as hydrogen storage materials is summarized, and the problems and controversial opinions on hindering the enhancement of hydrogen storage ability of MOFs are pointed out.

Contents
1 Introduction
2 Metal-organic frameworks (MOFs) as hydrogen storage materials
2.1 MOF-5 as hydrogen storage materials
2.2 IRMOFs as hydrogen storage materials
2.3 MMOMs as hydrogen storage materials
2.4 Other modification methods of MOFs as hydrogen storage materials
2.5 Theoretical modeling and prediction of hydrogen storage property of MOFs
3 Conclusion

Key words: metal-organic frameworks (MOFs), hydrogen storage material, central metal ion, organic linker

中图分类号: 

()

[ 1 ] 　毛宗强(Mao Z Q) , 刘志华(Liu Z H) . 电池(Battery) , 2002 ,32 (3) : 150 —152
[ 2 ] 　Rowsell J L C , Yaghi O M. Microporous Mesoporous Material ,2004 , 73 : 3 —14
[ 3 ] 　Fang S S , Dong YD. Nature , 2001 , 23 (5) : 259 —262
[ 4 ] 　Chae H K, Siberio-PUrez D Y, Yaghi O M, et al . Nature , 2004 ,427 : 523 —527
[ 5 ] 　许炜(Xu W) , 陶占良(Tao Z L) , 陈军(Chen J ) . 化学进展(Progress in Chemistry) , 2006 , 18 : 200 —210
[ 6 ] 　Tomic E A. Journal of Applied Polymer Science , 1965 , 9 : 3745 —3752
[ 7 ] 　Kitagawa S , Kitaura R , Noro S. Angewandte Chemie International Edition , 2004 , 43 : 2334 —2375
[ 8 ] 　Mueller U , Puetter H , Hesse M, et al . WO 20050498922A1 , 2005
[ 9 ] 　王素娜(Wang S N) , 江国庆(Jiang G Q) , 白俊峰(Bai J F)等. 无机化学学报( Chinese Journal of Inorganic Chemistry) ,2005 , 21 (1) : 1 —11
[10 ] 　洪茂椿(Hong M C) , 吴新涛(Wu X T) , 苏伟平(Su W P) 等.化学进展(Progress in Chemistry) , 2003 , 15 (4) : 249 —255
[11 ] 　Bai J F , Virovets A V , Scheer M. Angewandte Chemie International Edition , 2002 , 41 (10) : 1737 —1740
[12 ] 　Bai J F , Leiner E , Scheer M. Angewandte Chemie International Edition , 2002 , 41 (5) : 783 —786
[13 ] 　Yaghi O M, Li H L , Davic C , et al . Accounts of Chemistry Research , 1998 , 31 : 474 —484
[14 ] 　Li HL , Eddaoudi M, Yaghi O M, et al . Nature , 1999 ,402 : 276 —279
[15 ] 　Rosi N L , Eckert J , Eddaoudi M, et al . Science , 2003 , 300 :1127 —1129
[16 ] 　Eddaoudi M, KimJ , Rosi N L , et al . Science , 2002 , 295 : 469 —472
[17 ] 　Pan L , Sander M B , Huang X Y, et al . Journal of American Chemistry Society , 2004 , 126 : 1308 —1309
[18 ] 　Rowsell J L C , Millward A R , Yaghi O M, et al . Journal of American Chemistry Society , 2004 , 126 : 5666 —5667
[19 ] 　Rowsell J L C , Yaghi O M. Journal of American Chemistry Society ,2006 , 128 : 1304 —1315
[20 ] 　Kaye S S , Dailly A , Yaghi O M, et al . Journal of the American Chemistry Society , 2007 , 129 : 14176 —14177
[21 ] 　Furukawa H , Michael M A , Yaghi O M. Journal of Material Chemistry , 2007 , 17 : 3197 —3204
[22 ] 　Rosi N L , Kim J , Yaghi O M. Journal of American Chemistry Society , 2005 , 127 : 1504 —1518
[23 ] 　Panella B , Hirscher M, Müller U , et al . Advanced Functional Materials , 2006 , 16 : 520 —524
[24 ] 　Vishnyakov A , Ravikovitch P I , Neimark A V , et al . Nano Letter ,2003 , 3 : 713 —718
[25 ] 　Wang Q , Johnson J K. Journal of Chemical Physics , 1999 , 110 :577 —586
[26 ] 　Yaghi O M, Keeffe M O , Ockwig N W, et al . Nature , 2003 , 423 :705 —714
[27 ] 　Chen B L , Ockwig N W, Yaghi O M, et al . Angewandte Chemie International Edition , 2005 , 44 : 4745 —4749
[28 ] 　Lee J Y, Pan L , Kelly S P , et al . Advanced Materials , 2005 , 17 :2703 —2706
[29 ] 　Forster P M, Eckert J , Chang J S , et al . Journal of American Chemistry Society , 2003 , 125 : 1309 —1312
[30 ] 　Férey G, Latroche M, Serre C , et al . Chemistry Communication ,2003 , 2976 —2977
[31 ] 　Latroche M, Surble S , Serre C , et al . Angewandte Chemie International Edition , 2006 , 45 : 8227 —8231
[32 ] 　Zhou W, Wu H , Yildirim T. Journal of American Chemistry Society ,2008 , 130 : 15268 —15269
[33 ] 　Wang X S , Ma S Q , Zhou H C. Chemistry of Materials , 2008 , 20 :3145 —3152
[34 ] 　Fang Q R , Zhu GS , Jin Z, et al . Angewandte Chemie International Edition , 2007 , 46 : 6638 —6642
[35 ] 　Xue M, Zhu G S , Li Y Y, et al . Crystal Growth &Design , 2008 ,8 : 2478 —2483
[36 ] 　Li Y Q , Xie L , Li X G, et al . Inorganic Chemistry , 2008 , 47 :10372 —10377
[37 ] 　Wang Y, Cheng P , Yan S P. Inorganic Chemistry , 2007 , 46 :4530 —4534
[38 ] 　Dinca M, Dailly A , Liu Y, et al . Journal of the American Chemistry Society , 2006 , 128 : 16876 —16883
[39 ] 　Dinca M, Long J R. Journal of the American Chemistry Society ,2007 , 129 : 11172 —11176
[40 ] 　Dinca M, Yu A F , Long J R. Journal of the American Chemistry Society ,2006 ,128 : 8904 —8913
[41 ] 　Choi HJ , Dinca M, Long J R. Journal of the American Chemistry Society , 2008 , 130 : 7848 —7850
[42 ] 　Dybtsev D N , Kim D , Kim K, et al . Journal of American Chemistry Society , 2004 , 126 : 32 —33
[43 ] 　Li Y W, Yang R T. AIChE Journal , 2008 , 54 : 269 —279
[44 ] 　Li Y W, Yang R T. Journal of American Chemistry Society , 2006 ,128 : 726 —727
[45 ] 　Li Y W, Yang R T. Journal of American Chemistry Society , 2006 ,128 : 8136 —8137
[46 ] 　Liu Y Y, Zeng J L , Sun L X, et al . International Journal of Hydrogen Energy , 2007 , 32 : 4005 —4010
[47 ] 　Mulfort K L , Hupp J T. Inorganic Chemistry , 2008 , 47 : 7936 —7938
[48 ] 　Han S S , Deng W Q , Goddard W A. Angewandte Chemie International Edition , 2007 , 46 : 6289 —6292
[49 ] 　Han S S , Goddard W A. Journal of Physical Chemistry C , 2008 ,112 : 13431 —13436
[50 ] 　Yang Q Y, Zhong CL. Journal of Physical Chemistry B , 2005 , 109 :11862 —11864
[51 ] 　Chen B L , Ockwig N W, Millward A R , et al . Angewandte Chemie International Edition , 2005 , 44 : 4745 —44749
[52 ] 　Yang Q Y, Zhong CL. Journal of Physical Chemistry B , 2006 , 110 :655 —658
[53 ] 　Zhang L , Wang Q , Liu Y C. Journal of Physical Chemistry B , 2007 ,111 : 4291 —4295
[54 ] 　Li Y W, Yang F H , Yang R T. Journal of Physical Chemistry C ,2007 , 111 : 3405 —3411
[55 ] 　Klontzas E , Mavrandonakis A , Klopper W, et al . Journal of Physical Chemistry C , 2007 , 111 : 13635 —13640
[56 ] 　Buda C , Dunietz B D. Journal of Physical Chemistry B , 2006 , 110 :10479 —10484
[57 ] 　Dalach P , Frost H , Ellis D E , et al . Journal of Physical Chemistry C , 2008 , 112 : 9278 —9284
[1] 丁朝, 杨维结, 霍开富, Leon Shaw. LiBH4储氢热力学和动力学调控[J]. 化学进展, 2021, 33(9): 1586-1597.
[2] 顾婷婷, 顾坚, 张喻, 任华. 金属硼氢化物基固态储氢体系[J]. 化学进展, 2020, 32(5): 665-686.
[3] 姚淇露, 杜红霞, 卢章辉. 氨硼烷催化水解制氢[J]. 化学进展, 2020, 32(12): 1930-1951.
[4] 张世亮, 姚淇露, 卢章辉*. 肼硼烷的合成及产氢[J]. 化学进展, 2017, 29(4): 426-434.
[5] 李超, 范美强, 陈海潮, 陈达, 田光磊, 舒康颖. Li-Mg-N-H体系储氢材料的热力学和动力学调控[J]. 化学进展, 2016, 28(12): 1788-1797.
[6] 李雪, 张伊放, 齐卫宏, 曹晓武, 王渊, 李浩华. 纳米储氢合金[J]. 化学进展, 2013, 25(07): 1122-1130.
[7] 徐叔军, 梁丽芸, 李步怡, 罗亚莉, 刘承美, 谭必恩. 有机微孔聚合物研究进展[J]. 化学进展, 2011, 23(10): 2085-2094.
[8] 段东红 孙彦平. 直接硼氢化物燃料电池（DBFC）阳极材料及反应机理*[J]. 化学进展, 2010, 22(09): 1720-1728.
[9] 陈兆旭 黄玉成 李哲 康国俊. 理论化学与新能源*[J]. 化学进展, 2009, 21(11): 2271-2284.
[10] 方占召 康向东 王平. 硼氢化锂储氢材料研究* [J]. 化学进展, 2009, 21(10): 2212-2218.
[11] 陶占良,陈军. MAlH4(M=Li, Na)储氢材料*[J]. 化学进展, 2009, 21(09): 1945-1953.