PDF(377 KB)
PDF(377 KB)
PDF(377 KB)
超级电容器用炭/导电聚合物复合材料*
- 安红芳|王先友**|李娜|郑丽萍|陈权启
作者信息
+
Carbon and Conducting Polymer Composites for Supercapacitors
- An Hongfang ; |Wang Xianyou** ; |Li Na ; |Zheng Liping ; |Chen Quanqi
Author information
+
文章历史
+
摘要
炭/导电聚合物复合材料是近年来发展起来应用于超级电容器的一种新型电极材料。炭材料与氧化物的复合材料，或者炭材料与导电聚合物的复合材料，能够将双电层电容与法拉第电容结合，既可提高超级电容器的比电容，改变其充放电电压，又可提高其循环性能。本文综述了近年来国内外各种炭材料，如活性炭，碳纳米管等与导电聚合物复合材料的研究进展，认为炭与导电聚合物的复合材料，尤其是性能优良的炭气凝胶，模板法制备的中孔炭，以及由金属或非金属碳化物与氯气等刻蚀剂反应制备的骨架炭与导电聚合物的复合材料是超级电容器电极材料研究的一个重要发展方向。
Abstract
Carbon/conducting polymer composite is a novel electrode material which is recently used for the application of supercapacitors. The composites of carbon and metal oxide, or carbon and conducting polymers can fully combine advantages of double-layer capacitance of carbon materials and pseudo-capacitance of metal oxide or conducting polymer, thus the materials can provide not only high specific capacitance and working voltage, but also excellent cycle stability. In this paper, we illustrate the recent research progress of the composites of carbon at home and abroad, such as active carbon, carbon nanotubes and conducting polymers, and believe that the composites of carbon and conducting polymers will be a promising electrode material for supercapacitors, especially carbon aerogels, mesoporous carbon prepared by template synthesis, and carbide derived carbon which is prepared by selective thermo-chemical etching from carbide in chlorine gas flow.
Contents
1 Introduction
2 Energy storage mechanism of supercapacitors using carbon conducting polymer
3 Recent Progress in Carbon and Conducting polymer composites
3.1 Carbon
3.2 Conducting polymer
3.3 Carbon/conducting polymer composites
4 Conclusion
关键词
炭 / 导电聚合物 / 复合 / 超级电容器 {{custom_keyword}} /
Key words
carbon / conducting polymers / composites / supercapacitors {{custom_keyword}} /
中图分类号：
O646
TB332
{{custom_clc.code}}
({{custom_clc.text}})
{{custom_sec.title}}
{{custom_sec.title}}
参考文献
[ 1 ] Peng C , Zhang S W, Daniel J , et al . Prog. Nat . Sci . , 2008 , 18(7) : 777 —788
[ 2 ] 苗小丽(Miao X L) , 邓正华(Deng Z H) . 合成化学(Chinese Journal of Synthetic Chemistry) , 2002 , 10 (2) : 106 —109
[ 3 ] Conway B E. Electrochemical Supercapacitors : Scientific Fundamentals and Technological Applications. New York: Kluwer Academic , 1999. 183 —220
[ 4 ] Sugimoto W, Yokoshima K, Murakami Y, et al . Electrochim. Acta ,2006 , 52 (4) : 1742 —1748
[ 5 ] 张庆武(Zhang Q W) , 周啸(Zhou X) , 汤孝平(Tang X P) 等. 电子元件与材料( Electronic Components & Materials) , 2002 , 20(5) : 21 —26
[ 6 ] Marina M R , Catia A. Solid State Ionics , 2002 , 148 (3P4) : 493 —498
[ 7 ] 王晓峰(Wang X F) , 孔祥华(Kong X H) , 解晶莹(Xie J Y) 等.电子元件与材料( Electronic Components &Materials) , 2001 , 21(5) : 24 —29
[ 8 ] 卢斐(Lu F) , 吴志明(Wu Z M) , 徐建华(Xu J H) 等. 电子元件与材料(Electronic Components &Materials) , 2005 , 24 (2) : 51 —53
[ 9 ] 蔡志江(Cai Z J ) . 电源技术(Chinese Journal of Power Sources) ,2006 , (1) : 71 —88
[10 ] Gupta V , Miura N. Mater. Lett . , 2006 , 60 (12) : 1466 —1469
[11 ] Fan L Z, Maier J . Electrochem. Commun. , 2006 , 8 (6) : 937 —940
[12 ] Xu Y, Wang J , Sun W, et al . J . Power Sources , 2006 , 159 (1) :370 —373
[13 ] 汪形艳(Wang X Y) , 王先友(Wang X Y) , 黄伟国(Huang W G) . 电池(Battery Bimonthly) , 2004 , 34 (3) : 192 —193
[14 ] Becker H I. US 2800616 , 1957
[15 ] Subramanian V , Luo C , Stephan A M, et al . J . Phys. Chem. C ,2007 , 111 (20) : 7527 —7531
[16 ] Babel K, Jurewicz K. J . Phys. Chem. Solids , 2004 , 65 ( 2/3) :275 —280
[17 ] 张治安(Zhang Z A) , 邓梅根(Deng M G) , 王斌华(Wang B H)等. 功能材料(Journal of Functional Materials) , 2005 , 36 (2) :275 —280
[18 ] Frank M, Mark L , Gerrard I M, et al . Electrochem. Commun. ,2001 , 3 (8) : 177 —180
[19 ] Che G L , Lakshmi B B , Fisher E R , et al . Nature , 1998 , 393(6683) : 346 —348
[20 ] Pekala R W, Farmer J C , Alviso C T, et al . J . Non-Cryst . Solids ,1998 , 225 (1) : 74 —80
[21 ] Sullivan M, Kê tz R , Haas O. Electrochemical Capacitors ,Pennington : The Electrochemical Society , Inc. , 1996. 198 —209
[22 ] Nikitin A , Gogotsi Y. Nanostructured Carbide-Derived Carbon(CDC) . American Scientific Pubilishers , 2003
[23 ] Denisa H , Junya Y, Yasushi S , et al . Chem. Mater. , 2005 , 17(5) : 1241 —1247
[24 ] 李娜(Li N) , 王先友(Wang X Y) , 易四勇(Yi S Y) 等. 化学进展(Progress in Chemistry) , 2008 , 20 (7P8) : 1202 —1207
[25 ] Pekala R W, Farmer J C , Alviso C T, et al . J . Non-Cryst . Solids ,1998 , 225 (1) : 74 —80
[26 ] Li J , Wang X Y, Huang Q H , et al . J . Power Sources , 2006 , 158(2) : 784 —788
[27 ] Iijima S. Nature , 1991 , 354 : 56 —58
[28 ] Shirakawa H , Louis E L , MacDiarmid A G, et al . J . Chem. Soc.Chem. Commun. , 1977 , 578 —580
[29 ] Zhou C , Han J , Song G, Guo R. Macromolecules , 2007 , 40 (20) :7075 —7078
[30 ] Mi H Y, Zhang X G, Yang S D , et al . Mater. Chem. Phys. ,2008 , 112 (1) : 127 —131
[31 ] Zhou M, Pagels M, Geschke B , et al . J . Phys. Chem. B , 2002 ,106 : 10065 —10073
[32 ] Sharma R K, Rastogi A C , Desu S B. Electrochem. Commun. ,2008 , 10 (2) : 268 —272
[33 ] 袁国辉(Yuan G H ) . 电化学电容器( Electrochemical Supercapacitors) . 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 1999. 150 —153
[34 ] Laforgue A , Simon P , Sarrazin C , et al . J . Power Sources , 1999 ,80 (1/2) : 142 —148
[35 ] 毛定文(Mao D W) , 田艳红( Tian Y H) . 电源技术( Chinese Journal of Power Sources) , 2007 , 131 (8) : 614 —616
[36 ] 黄震雷(Huang ZL) , 丛文博(Cong WB) , 张宝宏(Zhang B H) .电源技术(Chinese Journal of Power Sources) , 2007 , 131 ( 8) :605 —608
[37 ] 丛文博(Cong WB) , 张宝宏(Zhang B H) , 俞应霞(Yu YX) . 哈尔滨工程大学学报(Journal of Harbin Engineering University) ,2004 , 25 (6) : 809 —813
[38 ] Muthulakshmi B , Kalpana D , Pitchumani S , et al . J . Power Sources , 2006 , 158 (2) : 1533 —1537
[39 ] KimJ H , Lee Y S , Sharma A K, et al . Electrochim. Acta , 2006 ,52 (4) : 1727 —1732
[40 ] Selvakumar M, Bhat D K. J . Appl . Polym. Sci . , 2008 , 107 (4) :2165 —2170
[41 ] Wang Y G, Li H Q , Xia Y Y. Adv. Mater. , 2006 , 18 ( 19) :2619 —2623
[42 ] Xing W, Zhuo S P , Cui H Y, et al . Mater. Lett . , 2007 , 61 (23/24) : 4627 —4630
[43 ] Chen W C , Wen T C , Teng H. Electrochim. Acta , 2003 , 48 (6) :641 —649
[44 ] Deng M G, Yang B C , Hu Y D. J . Mater. Sci . , 2005 , 40 (18) :5021 —5023
[45 ] Zhou Y K, He B L , Zhou WJ , et al . Electrochim. Acta , 2004 , 49(2) : 257 —262
[46 ] Gupta V , Miura N. J . Power Sources , 2006 , 157 (1) : 616 —620
[47 ] Wang J , Xu YL , Chen X, Sun X F. Comp. Sci . Technol . , 2007 ,67 (14) : 2981 —2985
[48 ] Kima J Y, Kima K H , Kim KB. J . Power Sources , 2008 , 176 (1) :396 —402
[49 ] Lota K, Khomenko V , Frackowiak E. J . Phys. Chem. Solids ,2004 , 65 (2/3) : 295 —301
[50 ] Wang J , Xu Y L , Sun X F , et al . J . Solid State Electrochem. ,2008 , 12 (7P8) : 947 —952
[51 ] Frackowiak E , Beguin F. Carbon , 2002 , 40 (10) : 1775 —1787
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}
基金
国家自然科学基金
{{custom_fund}}
/
| 〈 |
|
〉 |