English
往期目录
新闻公告
More
化学进展 2009, Vol. 21 Issue (09): 1792-1799 前一篇   后一篇

• 综述与评论 •

离子液体应用于电合成导电聚合物*

董彬1,2|徐景坤1**|郑利强2**   

  1. (1.江西科技师范学院江西省有机功能分子重点实验室 南昌 330013；2.山东大学胶体与界面教育部重点实验室 济南 250100)
  • 收稿日期:2008-09-15 修回日期:2008-10-28 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 徐景坤;郑利强 E-mail:xujingkun@tsinghua.org.cn;lqzheng@sdu.edu.cn
  • 基金资助:

    省级资助

下载PDF ( 2617 ) 引用
导出

Ionic Liquids for the Electrosyntheses of Conducting Polymers

Dong Bin1,2; |Xu Jingkun1**; |Zheng Liqiang2**   

  1. (1.Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science and Technology Normal University, 330013, Nanchang, China|2.Key Laboratory of Colloid and Interface Chemistry of Education Ministry, Shandong University, Jinan 250100, China)
  • Received:2008-09-15 Revised:2008-10-28 Online:2009-09-24 Published:2009-09-15
  • Contact: Xu Jingkun;Zheng Liqiang E-mail:xujingkun@tsinghua.org.cn;lqzheng@sdu.edu.cn

自20世纪70年代导电聚合物发现以来，聚吡咯、聚苯胺、聚噻吩、聚（3,4-乙撑二氧噻吩）、聚对苯及其衍生物等，以其特殊的电子、电化学、光学性质以及巨大应用潜力受到广泛关注。离子液体是一类在室温或接近室温时呈液态的离子化合物，作为一类环境友好的新型绿色溶剂，具有很多独特的物理化学性质。本文综述了离子液体作为反应介质、支持电解质、测试介质以及离子液体参与形成的聚集体，在导电聚合物的电化学合成以及电化学性质测试中的研究进展，并展望了发展趋势。

关键词： 离子液体, 导电聚合物, 电化学合成

Since the discovery of conducting polymers in 1970s, they have attracted much attention due to their novel electronic, electrochemical and optical properties, as well as their promising applications. Typical examples are polypyrrole (PPy), polyaniline (PANI), polythiophene (PTh), poly(3,4-ethylenedioxythiophene) (PEDOT), and poly(p-phenylene) (PPP). Ionic liquids (ILs), a class of organic molten electrolytes at or near ambient temperature, are novel environmentally benign “green solvents” and have remarkable physicochemical properties. This paper reviews the research progress of ionic liquids for the electrosyntheses of conducting polymers, including the use of ionic liquids as growth media or supporting electrolytes to electrosynthesize and test the electrochemical behaviors of conducting polymers, and the use of the aggregations composed of ionic liquids (e.g. ionic liquid microemulsions) as novel electrolytes. The trend for future research is also prospected.

Contents
1 Introduction
2 Ionic liquids as growth media
2.1 Polypyrrole and its derivatives
2.2 Polyaniline and its derivatives
2.3 Polythiophene and its derivatives
2.4 Poly(3,4-ethylenedioxythiophene) and its derivatives
2.5 Poly(p-phenylene)
2.6 Co-polymerization of conducting polymers
3 Ionic liquids as supporting electrolytes
4 Ionic liquids as testing media
5 Aggregations composed of ionic liquids as growth media
6 Conclusion

Key words: ionic liquids, conducting polymers, electrosyntheses

中图分类号: 

()

[ 1 ] 　李汝雄(Li R X) . 绿色溶剂———离子液体的合成与应用(Synthesis and Application of Green Solvent Ionic Liquids) . 北京:化学工业出版社(Beijing: Chemical Industry Press) , 2004
[ 2 ] 　Walden P. Bull . Acad. Imper. Sci . ( St . Petersburg) , 1914 ,1800 : 405 —422
[ 3 ] 　Hurley F H , Wier T P. J . Electrochem. Soc. , 1951 , 98 : 203 —208
[ 4 ] 　Wilkes J S , Zaworotko M J . J . Chem. Soc. Chem. Commun. ,1992 , 13 : 965 —967
[ 5 ] 　Lei Z G, Chen B H , Li C Y, et al . Chem. Rev. , 2008 , 108 :1419 —1455
[ 6 ] 　Martins M A P , Frizzo C P , Moreira D N , et al . Chem. Rev. ,2008 , 108 : 2015 —2050
[ 7 ] 　Dahl J A , Maddux B L S , Hutchison J E. Chem. Rev. , 2007 ,107 : 2228 —2269
[ 8 ] 　Endres F , Abedin S Z E. Phys. Chem. Chem. Phys. , 2006 , 8 :2101 —2116
[ 9 ] 　Qiu ZM, Texter J . Curr. Opin. Colloid Interface Sci . , 2008 , 13 :252 —262
[10 ] 　Buzzeo M C , Evans R G, Compton R G. ChemPhysChem , 2004 , 5 :1106 —1120
[11 ] 　Hapiot P , Lagrost C. Chem. Rev. , 2008 , 108 : 2238 —2264
[12 ] 　Vasudeva Rao P R , Venkatesan KA , Srinivasan T G. Prog. Nucl .Energ. , 2008 , 50 : 449 —455
[13 ] 　顾彦龙(Gu YL) , 石峰(Shi F) , 邓友全(Deng YQ) . 科学通报(Chinese Science Bulletin) , 2004 , 49 (6) : 5l5 —52l
[14 ] 　寇元(Kou Y) , 何玲(He L) . 化学进展( Progress in Chemistry) ,2008 , 20 (1) : 5 —10
[15 ] 　王仲妮(Wang Z N) , 王洁莹(Wang J Y) , 司友华(Si Y H) 等.化学进展(Progress in Chemistry) , 2008 , 20 (7P8) : 1057 —1063
[16 ] 　石家华(Shi J H) , 孙逊(Sun X) , 杨春和(Yang C H) 等. 化学通报(Chemistry) , 2002 , (4) : 243 —250
[17 ] 　顾彦龙(Gu Y L) , 彭家建(Peng J J ) , 乔琨(Qiao K) 等. 化学进展(Progress in Chemistry) , 2003 , 15 (3) : 222 —241
[18 ] 　王媛媛(Wang Y Y) , 孙辉(Sun H) , 戴立益(Dai L Y) . 高分子通报(Polymer Bulletin) , 2006 , (5) : 20 —26
[19 ] 　曹洁明(Cao J M) , 房宝青(Fang B Q) , 王军(Wang J ) 等. 化学进展(Progress in Chemistry) , 2005 , 17 (6) : 1028 —1033
[20 ] 　赵崇军(Zhao C J ) , 蒋咏文(Jiang YW) , 赵启涛(Zhao Q T) 等.高分子通报(Polymer Bulletin) , 2006 , (12) : 8 —12
[21 ] 　Robinson J , Osteryoung R A. J . Am. Chem. Soc. , 1979 , 101 :323 —327
[22 ] 　Pickup P G, Osteryoung R A. J . Am. Chem. Soc. , 1984 , 106 :2294 —2299
[23 ] 　Pickup P G, Osteryoung R A. J . Electroanal . Chem. , 1985 , 195 :271 —288
[24 ] 　Oudard J F , Allendoerfer R D , Osteryoung R A. J . Electroanal .Chem. , 1988 , 241 : 231 —246
[25 ] 　Janiszewska L , Osteryoung R A. J . Electrochem. Soc. , 1987 , 134 :2787 —2794
[26 ] 　Janiszewska L , Osteryoung R A. J . Electrochem. Soc. , 1988 , 135 :116 —122
[27 ] 　Oudard J F , Allendoerfer R D , Osteryoung R A. Synth. Met . ,1988 , 22 : 407 —414
[28 ] 　Zawodzinski T A , Janiszewska L , Osteryoung R A. J . Electroanal .Chem. , 1988 , 255 : 111 —117
[29 ] 　Geetha S , Trivedi D C. Mater. Chem. Phys. , 2004 , 88 : 388 —397
[30 ] 　Trivedi D C. J . Chem. Soc. Chem. Commun. , 1989 , 9 : 544 —545
[31 ] 　Goldenberg L M, Pelekh A E , Krinichnyi V I , et al . Synth. Met . ,1990 , 36 : 217 —228
[32 ] 　Goldenberg L M, Osteryoung R A. Synth. Met . , 1994 , 64 : 63 —68
[33 ] 　Arnautov S A. Synth. Met . , 1997 , 84 : 295 —296
[34 ] 　Fenelon A M, Breslin C B. J . Electrochem. Soc. , 2005 , 152 :D6 —D11
[35 ] 　Sekiguchi K, Atobe M, Fuchigami T. Electrochem. Commun. ,2002 , 4 : 881 —885
[36 ] 　Sekiguchi K, Atobe M, Fuchigami T. J . Electroanal . Chem. ,2003 , 557 : 1 —7
[37 ] 　Pringle J M, Efthimiadis J , Howlett P C , et al . Polymer , 2004 , 45 :1447 —1453
[38 ] 　Pringle J M, MacFarlane D R , Forsyth M. Synth. Met . , 2005 ,155 : 684 —689
[39 ] 　Boxall D L , Osteryoung R A. J . Electrochem. Soc. , 2004 , 151 :E41 —E45
[40 ] 　Pringle J M, Forsyth M, Wallace G G, et al . Macromolecules ,2006 , 39 : 7193 —7195
[41 ] 　刘宝友(Liu B Y) , 许丹倩(Xu D Q) , 徐振元(Xu Z Y) . 中国化学(Chinese Journal of Chemistry) , 2005 , 23 (7) : 803 —805
[42 ] 　Li M C , Ma C A , Liu B Y, et al . Electrochem. Commun. , 2005 ,7 : 209 —212
[43 ] 　Wei D , Kvarnstrêm C , Lindfors T, et al . Electrochem. Commun. ,2006 , 8 : 1563 —1566
[44 ] 　Wei D , Kvarnstrêm C , Lindfors T, et al . Electrochem. Commun. ,2007 , 9 : 206 —210
[45 ] 　Du Y F , Qi XM, Zhao P , et al . Chinese Chemical Letters , 2004 ,15 (9) : 1098 —1100
[46 ] 　Zane D , Raffaele A , Curulli A , et al . Electrochem. Commun. ,2007 , 9 : 2037 —2040
[47 ] 　Pringle J M, Forsyth M, MacFarlane D R , et al . Polymer , 2005 ,46 : 2047 —2058
[48 ] 　Murray P S , Ralph S F , Too C O , et al . Electrochim. Acta , 2006 ,51 : 2471 —2476
[49 ] 　Pang Y H , Li X Y, Ding HL , et al . Electrochim. Acta , 2007 , 52 :6172 —6177
[50 ] 　Zhang A J , Qi X M, Du Y F , et al . Chinese Journal of Chemistry ,2006 , 24 (5) : 609 —612
[51 ] 　Arbizzani C , Soavi F , Mastragostino M. J . Power Sources , 2006 ,162 : 735 —737
[52 ] 　许贺(Xu H) , 庞月红(Pang Y H) , 黎小宇(Li X Y) 等. 化学学报(Acta Chimica Sinica) , 2006 , 64 (24) : 2254 —2258
[53 ] 　Pang Y H , Xu H , Li X Y, et al . Electrochem. Commun. , 2006 ,8 : 1757 —1763
[54 ] 　Pang Y H , Li X Y, Shi G Y, et al . Thin Solid Films , 2008 , 516 :6512 —6516
[55 ] 　Naudin E , Ho H A , Breau L , et al . J . Phys. Chem. B , 2002 ,106 : 10585 —10593
[56 ] 　Shi J H , Yang C H , Sun X, et al . Chinese Chemical Letters , 2002 ,13 (4) : 302 —307
[57 ] 　石家华(Shi J H) , 杨春和(Yang C H) , 高青雨(Gao Q Y) 等. 化学物理学报(Chinese Journal of Chemical Physics) , 2004 , 17 (4) :503 —507
[58 ] 　Dong B , Xing Y H , Xu J K, et al . Electrochim. Acta , 2008 , 53 :5745 —5751
[59 ] 　Lu W, Fadeev A G, Mattes B R , et al . Synth. Met . , 2003 , 135/136 : 139 —140
[60 ] 　Damlin P , Kvarnstrêm C , Ivaska A. J . Electroanal . Chem. , 2004 ,570 : 113 —122
[61 ] 　Liu K K, Hu ZL , Zhang J R , et al . J . Power Sources , 2008 , 179 :858 —862
[62 ] 　Danielsson P , Bobacka J , Ivaska A. J . Solid State Electrochem. ,2004 , 8 : 809 —817
[63 ] 　Wagner K, Pringle J M, Hall S B , et al . Synth. Met . , 2005 , 153 :257 —260
[64 ] 　Ahmad S , Deepa M, Singh S. Langmuir , 2007 , 23 : 11430 —11433
[65 ] 　Dong B , Zheng L Q , Xu J K, et al . Polymer , 2007 , 48 : 5548 —5555
[66 ] 　Zein El Abedin S , Borissenko N , Endres F. Electrochem.Commun. , 2004 , 6 : 422 —426
[67 ] 　Schneider O , Bund A , Endres F , et al . J . Phys. Chem. B , 2005 ,109 : 7159 —7168
[68 ] 　Zhang A J , Zhang G R , Yang G D , et al . Chinese Journal of Chemistry , 2007 , 25 (3) : 268 —271
[69 ] 　李美超(Li M C) , 沈振陆(Shen Z L) , 高云芳(Gao Y F) 等. 化学物理学报(Chinese Journal of Chemical Physics) , 2005 , 18 (4) :471 —473
[70 ] 　李美超(Li M C) , 沈振陆(Shen Z L) , 马淳安(Ma C A) 等. 催化学报(Chinese Journal of Catalysis) , 2006 , 27 (7) : 541 —543
[71 ] 　Koo Y K, Kim B H , Park D H , et al . Mol . Cryst . Liq. Cryst . ,2004 , 425 : 55 —60
[72 ] 　Kim H S , Park D H , Lee Y B , et al . Synth. Met . , 2007 , 157 :910 —913
[73 ] 　Deepa M, Ahmad S , Sood K N , et al . Electrochim. Acta , 2007 ,52 : 7453 —7463
[74 ] 　Mu S L. Electrochim. Acta , 2007 , 52 : 7827 —7834
[75 ] 　Tang J , Allendoerfer R D , Osteryoung R A. J . Phys. Chem. ,1992 , 96 : 3531 —3536
[76 ] 　Yang C H , He G F , Zhang J R , et al . Chinese Chemical Letters ,2000 , 11 (10) : 919 —920
[77 ] 　Lu W, Fadeev A G, Mattes B R , et al . Science , 2002 , 297 : 983 —987
[78 ] 　Mazurkiewicz J H , Innis P C , Wallace G G, et al . Synth. Met . ,2003 , 135/136 : 31 —32
[79 ] 　Innis P C , Mazurkiewicz J , Nguyen T, et al . Curr. Appl . Phys. ,2004 , 4 : 389 —393
[80 ] 　Zhang J L , Zhang X G, Xiao F , et al . J . Colloid Interf . Sci . ,2005 , 287 : 67 —71
[81 ] 　Randriamahazaka H , Plesse C , TeyssiéD , et al . Electrochem.Commun. , 2003 , 5 : 613 —617
[82 ] 　Randriamahazaka H , Plesse C , TeyssiéD , et al . Electrochem.Commun. , 2004 , 6 : 299 —305
[83 ] 　Randriamahazaka H , Plesse C , TeyssiéD , et al . Electrochim. Acta ,2005 , 50 : 1515 —1522
[84 ] 　Randriamahazaka H , Plesse C , TeyssiéD , et al . Electrochim. Acta ,2005 , 50 : 4222 —4229
[85 ] 　Gao Y A , Li N , ZhengL Q , et al . Green Chem. , 2006 , 8 : 43 —49
[86 ] 　Li N , Zhang S H , Zheng L Q , et al . Langmuir , 2008 , 24 : 2973 —2976
[87 ] 　Dong B , Zhang S H , Zheng L Q , et al . J . Electroanal . Chem. ,2008 , 619P620 : 193 —196
[1] 刘亚伟, 张晓春, 董坤, 张锁江. 离子液体的凝聚态化学研究[J]. 化学进展, 2022, 34(7): 1509-1523.
[2] 吴磊, 刘利会, 陈淑芬. 基于碳基透明电极的柔性有机电致发光二极管[J]. 化学进展, 2021, 33(5): 802-817.
[3] 康美荣, 金福祥, 李臻, 宋河远, 陈静. 离子液体固载化及应用研究[J]. 化学进展, 2020, 32(9): 1274-1293.
[4] 刘风国, 王博, 章莲玉, 刘爱民, 王兆文, 石忠宁. 离子液体在电沉积铝及铝合金中的应用[J]. 化学进展, 2020, 32(12): 2004-2012.
[5] 郭芬岈, 李宏伟, 周孟哲, 徐正其, 郑岳青, 黎挺挺. 基于非贵金属催化剂常温常压电化学合成氨[J]. 化学进展, 2020, 32(1): 33-45.
[6] 佟国宾, 鄂雷, 徐州, 马春慧, 李伟, 刘守新. 基于离子液体的炭材料制备、改性及应用[J]. 化学进展, 2019, 31(8): 1136-1147.
[7] 李志勇, 冯莹, 王慧勇, 袁晓晴, 赵玉灵, 王键吉. 光响应离子液体的结构与性能调控[J]. 化学进展, 2019, 31(11): 1550-1559.
[8] 刘文巧, 李臻, 夏春谷. 酸功能化离子液体固相催化材料的制备及应用[J]. 化学进展, 2018, 30(8): 1143-1160.
[9] 程海东, 陈双俊*. 功能化离子液体在聚酯PET降解与合成中的应用[J]. 化学进展, 2017, 29(4): 443-449.
[10] 宋河远, 康美荣, 靳荣华, 金福祥, 陈静. 离子液体在羰基化反应中的应用[J]. 化学进展, 2016, 28(9): 1313-1327.
[11] 胡传波, 厉英, 孔亚州, 丁玉石. 改性聚苯胺及其衍生物涂层的防腐性能[J]. 化学进展, 2016, 28(8): 1238-1250.
[12] 杨许召, 王军, 方云. 双阳离子液体的合成、性能及应用[J]. 化学进展, 2016, 28(2/3): 269-283.
[13] 孟艳山, 陈玉焕, 邓雨晨, 张姝明, 王桂香. 离子液体及离子液体膜在天然气净化方面的应用[J]. 化学进展, 2015, 27(9): 1324-1332.
[14] 舒昕, 李兆祥, 夏江滨. 聚噻吩的合成方法[J]. 化学进展, 2015, 27(4): 385-394.
[15] 杨雷, 程涛, 曾文进, 赖文勇, 黄维. 导电聚合物薄膜的喷墨打印制备及其光电器件[J]. 化学进展, 2015, 27(11): 1615-1627.