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化学进展 2009, Vol. 21 Issue (09): 1763-1771 前一篇   后一篇

• 综述与评论 •

基于配位自组装的全共轭三联吡啶-过渡金属环状超分子的构筑及其光、电化学性能*

潘月秀1;佟斌1;支俊格2;赵玮1;申进波1;董宇平1**   

  1. (1. 北京理工大学材料科学与工程学院　北京100081 |2. 北京理工大学理学院　北京100081)
  • 收稿日期:2008-09-23 修回日期:2009-01-15 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 董宇平 E-mail:chdongyp@bit.edu.cn
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Self-Assembled Fabrication, Photochemical and Electrochemical Properties of Macrocyclic Metallosupramolecules Based on Conjugated Terpyridine and Transition Metal Ions

Pan Yuexiu1;Tong Bin1; |Zhi Junge2|Zhao Wei1|Shen Jinbo1|Dong Yuping1**   

  1. (1. College of Materials Science &|Engineering| Beijing Institute of Technology| Beijing 100081| China；2. College of Science| Beijing Institute of Technology| Beijing 100081| China)
  • Received:2008-09-23 Revised:2009-01-15 Online:2009-09-24 Published:2009-09-15
  • Contact: Dong Yuping E-mail:chdongyp@bit.edu.cn

2，2':6，2"-三联吡啶全共轭衍生物在与过渡金属离子配位络合后形成的全共轭配合物，因具有特殊的大π-π电子结构和金属-配体相互作用,成为构筑新型功能材料的重要基元，被广泛应用于光电转换、化学/生物检测、催化有机合成等领域。本文主要介绍近年来全共轭“三联吡啶-过渡金属离子（tpy-Mt）”环状超分子配合物的合成及其在光、电化学性能方面的研究进展,并探讨了该领域存在的问题及今后的发展方向。

关键词： 三联吡啶, 多边形环状超分子, 配位自组装, 光化学性能, 电化学性能

The polygonal cyclic metallosupramolecules based on 2,2':6',2"-terpyridine and transition metal ions are a new class of rigid oligomers which possess unique structural, electronic, and physical characteristics. Construction of highly ordered, regularly repeating molecular architectures through self-assembly techniques is of interest from a variety of supramolecular perspectives, which leads to utilitarian applications in molecular electronics, catalysis, luminescence, advanced drugs, nanoscale structures and devices, and crystal engineering. This review focuses on the synthesis, photochemical and electrochemical properties of the special class of the full-conjugated polygonal macrocyclic metallosupramolecules. The problems existed in this research field and possible prospects are also discussed.

Contents
1 Introduction
2 Conjugated Coordinate self-assembly supramolecular metallomacrocycles of terpyridine and transition metal ions
2.1 Triangle
2.2 Quadrangle
2.3 Pentagon
2.4 Hexagon
3 Perspects

Key words: conjugated terpyridine, polygonal macrocyclic metallosupramolecules, coordinate self-assembly, photochemical properties, electrochemical properties

中图分类号: 

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