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化学进展 2009, Vol. 21 Issue (09): 1705-1721   后一篇

• 综述与评论 •

碳纳米材料及其在多相催化中的应用

王春雷|马丁|包信和   

  1. （中国科学院大连化学物理研究所催化基础国家重点实验室   |大连　116023）
  • 收稿日期:2008-10-08 修回日期:2008-12-09 出版日期:2009-09-24 发布日期:2009-09-15
  • 通讯作者: 包信和 E-mail:xhbao@dicp.ac.cn
  • 基金资助:

    国家自然科学基金

下载PDF ( 4429 ) 引用
导出 被引次数 ( 26 | 5 )

Carbon Nanomaterials and Their Heterogeneous Catalytic Application

Wang Chunlei ; |Ma Ding ; |Bao Xinhe   

  1. (State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China)
  • Received:2008-10-08 Revised:2008-12-09 Online:2009-09-24 Published:2009-09-15
  • Contact: Bao Xinhe E-mail:xhbao@dicp.ac.cn
  • Supported by:

    National Natural Science Foundation of China

碳纳米材料（包括零维、一维、二维碳纳米材料以及碳纳米孔材料）是一类新型的催化剂或催化剂载体材料，在氧化脱氢、选择加氢、合成氨、氨分解制氢以及燃料电池等多相催化领域具有广阔的应用前景。本文综述了近年来新型碳纳米材料在多相催化领域中的应用研究进展，介绍了这类催化材料的制备方法，重点阐述了碳载体的微/介观结构、掺杂、电子性质、表面性质、限域效应等对所担载的催化活性组分的分散，对反应物的扩散以及对催化反应的活性和选择性等方面的影响。

关键词： 碳纳米材料, 多相催化, 催化剂, 催化剂载体

As a new type of catalyst and/or catalyst supports, carbon nanomaterials (including zero-dimensional, one-dimensional, two-dimensional carbon nanomaterials and nanoporous carbon materials) have potential applications in fields of heterogeneous catalysis, such as oxidative dehydrogenation, selective hydrogenation, ammonia synthesis and decomposition, and electrocatalysis in fuel cell. This paper presents an overview of the development of carbon nanomaterials and their applications in the field of heterogeneous catalysis in recent years. The preparation methods of these carbon nanomaterials are introduced; the relationships of their micro/mesostructures, dopping, electronic properties, surface properties, confinement effects and thus-resulted catalytic performance variations are emphatically reviewed.

Contents
1 Zero-dimensional carbon nanomaterials
1.1 Fullerene discover, structure and application in heterogeneous catalysis
1.2 Onion-like carbon, carbon-encapsulated metal nanoparticles and applications in heterogeneous catalysis
1.3 Nano-diamond and its application in heterogeneous catalysis
2 One-dimensional carbon nanomaterials
2.1 Carbon nanofibers preparation and application in heterogeneous catalysis
2.2 Carbon nanotubes discover, structure and application in heterogeneous catalysis
2.3 Heterogeneous catalyst confined in carbon nanotubes
3 Two-dimensional carbon nanomaterials
3.1 Graphene and its application in heterogeneous catalysis
3.2 Carbon nanowall and its application in heterogeneous catalysis
4 Carbon nanoporous materials
4.1 Mesoporous carbon materials and its application in heterogeneous catalysis
4.2 Functionalized mesoporous carbon and its application in heterogeneous catalysis
4.3 Other carbon nanoporous materials and their applications in heterogeneous catalysis
5 Conclusion and perspective

Key words: carbon nanomaterials, heterogeneous catalysis, catalysts, catalyst supports

中图分类号: 

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