PDF(197 KB)
PDF(197 KB)
PDF(197 KB)
非均相催化烯烃交叉复分解反应
- 徐泽辉*; 顾超然; 王佩琳
作者信息
+
Cross-Metathesis Reaction of Olefins over Heterogeneous Catalysts
- Xu Zehui*; Gu Chaoran; Wang Peilin
Author information
+
文章历史
+
摘要
烯烃交叉复分解反应作为石油化工领域一种重要过程，为各种单烯烃间的互相转化提供了一条有效的途径。特别是在利用正丁烯生产丙烯和其它重要单烯烃方面，复分解反应受到越来越多的重视。本文对烯烃交叉复分解反应(CM)的进展进行了综述，讨论了CM各种工艺的技术特点及反应机理，重点介绍了WO3/SiO2、Re2O7/Al2O3、MoO3/Al2O33类催化剂的最新改进及相应的理论分析，试图理清催化剂今后发展的思路，为进一步改进催化剂的性能提供相关的依据。
Abstract
Olefin metathesis opens up new industrial processes for the production of important olefins in the field of petrochemicals. In particular, the production of propylene and other important olefins via olefins metathesis reaction from n-butenes feedstock has received considerable attention. The most recent progress of olefin cross-metathesis reaction process, reactive mechanism, catalytic theory and catalysts for metathesis is reviewed in this paper and we try to explain the improved aspect of catalyst performance and provide reference for the study of metathesis catalyst afterwards.
Contents
1 Introduction
2 Cross metathesis process
2.1 Olefin conversion technology
2.2 Meta-4 technology
2.3 BASF technology
2.4 Sasol technology
2.5 SHOP technology
3 Cross-metathesis catalysts
3.1 WO3/SiO2 catalyst
3.2 Re2O7/Al2O3 catalyst
3.3 MoO3/Al2O3 catalyst
3.4 Catalytic performance comparison among three kinds of catalysts
4 Mechanisms of metathesis reaction
4.1 Mechanisms of metathesis reaction over WO3/SiO2 catalyst
4.2 Mechanisms of metathesis reaction over Re2O7/Al2O3 catalyst
4.3 Mechanisms of metathesis reaction over MoO3/Al2O3 catalyst
5 Conclusion
关键词
交叉复分解 / 烯烃 / 非均相催化 {{custom_keyword}} /
Key words
cross-metathesis / olefins / heterogeneous catalysts {{custom_keyword}} /
中图分类号：
TQ649.4+2
TQ032
{{custom_clc.code}}
({{custom_clc.text}})
{{custom_sec.title}}
{{custom_sec.title}}
参考文献
[ 1 ] Banks R L , Bailey G C. Ind. Eng. Chem. Prod. Res. Develo. ,1964 , 3 : 170 —173
[ 2 ] Schrock R R , Hoveyda A H. Angew. Chem. Int . Ed. Engl . ,2003 , 42 (38) : 4592 —633
[ 3 ] Chatterjee A K, Choi T L , Sanders D P , Grubbs R H. J . Am.Chem. Soc. , 2003 , 125 (37) : 11360 —11370
[ 4 ] Funk T W, Efskind J , Grubbs R H. Org. Lett . , 2005 , 7 (2) :187 —190
[ 5 ] Hsu M C , Junia A J , Haight A R , Zhang W. J . Org. Chem. ,2004 , 69 (11) : 3907 —3911
[ 6 ] La D S , Sattely E S , Ford J G, Schrock R R , Hoveyda A H. J .Am. Chem. Soc. , 2001 , 15 ;123 (32) : 7767 —7778
[ 7 ] Chatterjee A K, Grubbs R H. Org. Lett . , 1999 , 1 (11) : 1751 —1753
[ 8 ] Connon S J , Blechert S. Angew. Chem. Int . Ed. Engl . , 2003 , 42(17) : 1900 —1923
[ 9 ] Tsang W C , Jernelius J A , Cortez GA , Weatherhead G S , Schrock R R , Hoveyda A H. J . Am. Chem. Soc. , 2003 , 5 ; 125 ( 9) :2591 —2596
[10 ] Sanford M S , Love J A , Grubbs R H. J . Am. Chem. Soc. , 2001 ,123 (27) : 6543 —6554
[11 ] Banks R L. Journal of Molecular Catalysis , 1980 , 8 : 269 —276
[12 ] Mol J C. Journal of Molecular Catalysis A: Chemical , 2004 , 213 :39 —45
[13 ] Hu J C , Wang YD , Chen L F , et al . Microporous and Mesoporous Materials , 2006 , 93 (1P3) : 158 —163
[14 ] Huang S J , Liu S L , Xia WJ , et al . Journal of Molecular Catalysis A: Chemical , 2005 , 226 (1) : 61 —68
[15 ] Moodley D J , van Schalkwyk C , Spamer A , et al . Applied Catalysis A: General , 2007 , 318 : 155 —159
[16 ] Spamer A , Dube T I , Moodley D J , et al . Applied Catalysis A:General , 2003 , 255 (2) : 133 —142
[17 ] Van Schalkwyk C , Spamer A , Moodley DJ , et al . Applied Catalysis A: General , 2003 , 255 (2) : 121 —131
[18 ] Van Schalkwyk C , Spamer A , Moodley DJ , et al . Applied Catalysis A: General , 2003 , 255 (2) : 143 —152
[19 ] Gartside RJ , Greene M I , Khonsari A M, et al . US 6683019 , 2004
[20 ] Botha J M, Justice MMJ , Nkosi B S , et al . US 6586649 , 2003
[21 ] Spamer A , Botha J M, ˇZilkovàN , et al . US 0293548 , 2006
[22 ] Balcar H , Hamtil R , ˇZilkovàN , et al . Applied Catalysis A:General , 2007 , 320 : 56 —63
[23 ] Hamtil R , ˇZilkováN , Balcar H , et al . Applied Catalysis A:General , 2006 , 302 (2) : 193 —200
[24 ] Aguado J , Escola J M, Castro M C , et al . Applied Catalysis A:General , 2005 , 284 (1P2) : 47 —57
[25 ] Oikawa A , Ookoshi T, Tanaka T, et al . Microporous and Mesoporous Materials , 2004 , 74 (1P3) : 93 —103
[26 ] Mathew TM, Du Plessis J A K, Prinsloo J J . Journal of Molecular Catalysis A: Chemical , 1999 , 148 (1P2) : 157 —164
[27 ] Cristiane B , Rodella , Buffon R. Applied Catalysis A: General ,2004 , 263 (2) : 203 —211
[28 ] Doledec G, Commereuc D. Journal of Molecular Catalysis A: Chemical , 2000 , 161 (1P2) : 125 —140
[29 ] Sibeijn M, Vanveen J A R , Bliek A , et al . Journal of Catalysis ,1994 , 145 (2) : 416 —428
[30 ] Spronk R , Andreini A , Mol J C. Journal of Molecular Catalysis ,1991 , 65 (1P2) : 219 —235
[31 ] Amigues P , Chauvin Y. Journal of Molecular Catalysis , 1991 , 65 (1/2) : 39 —50
[32 ] Commereuc D , Hugues F , Saussine L. US 6277781 , 2001
[33 ] Commereuc D , Hugues F , Saussine L. US 6235958 , 2001
[34 ] Commereuc P , Mikitenkop. US 6437209 , 2002
[35 ] Commereuc D , Hugues F , Saussine L. US 6624338 , 2003
[36 ] Euzen P , Guibert S , Kruger-Tissot V , et al . US 6908878 , 2005
[37 ] Brown D S , Ginestra J M R. US 2006P0116542 , 2006
[38 ] Handzlik J , Ogonowski J , Stoch J , et al . Applied Catalysis A: General , 2006 , 312 : 213 —219
[39 ] Handzlik J , Ogonowski J , Stoch J , et al . Applied Catalysis A: General , 2004 , 273 (1P2) : 99 —104
[40 ] Pantoja A , Sarrin J , Gonzalez L , et al . Journal of Catalysis , 1993 ,142 (1) : 110 —120
[41 ] Liu SL , Huang SJ , Xin WJ , et al . Catalysis Today , 2004 , 93P95 :471 —476
[42 ] Kwini M N , Botha J M. Applied Catalysis A: General , 2005 , 280(2) : 199 —208
[43 ] Lombardo E A , Jacono ML , Hall W K. Journal of Catalysis , 1980 ,64 (1) : 150 —162
[44 ] Grupp T. , Kohl V , Sch?fer H , et al . Applied Catalysis , 1991 , 76(1) : 61 —77
[45 ] Basrur A G, Patwardhan S R , Was S N. Journal of Catalysis , 1991 ,127 (1) : 86 —95
[46 ] Verpoort F , Fiermans L , Bossuyt A R , et al . Journal of Molecular Catalysis , 1994 , 90 (1P2) : 43 —52
[47 ] Verpoort F , Bossuyt A R , Verdonck L. Journal of Electron Spectroscopy and Related Phenomena , 1996 , 82 (3) : 151 —163
[48 ] Wang Y D , Chen Q L , Yang W M, et al . Applied Catalysis A:General , 2003 , 250 (1) : 25 —37
[49 ] Mahmood C S , Yarmo M A , Hamid S B D. Journal of Molecular Catalysis A: Chemical , 2000 , 161 (1P2) : 11 —16
[50 ] Schekler-Nahama F , Clause O , Commereuc C , et al . Applied Catalysis A: General , 1998 , 167 (2) : 247 —256
[51 ] Rumeana M, Edreva-Kardjieva M, Vuurman A , et al . Journal of Molecular Catalysis , 1992 , 76 (1P3) : 297 —305
[52 ] McCoy J R , Farona M F. Journal of Molecular Catalysis , 1991 , 66(1) : 51 —58
[53 ] Vikulov K A , Shelimov B N , Kazansky V B. Journal of Molecular Catalysis , 1991 , 65 (3) : 393 —402
[54 ] Lombardo E A , Jacono ML , Hall W K. Journal of Catalysis , 1978 ,51 (2) : 243 —255
[55 ] Vikulov K A , Shelimov B N , Kazansky V B. Journal of Molecular Catalysis , 1992 , 72 (1) : 1 —11
[56 ] Vikulov K A , Shelhnov B N , Kazansky V B. Journal of Molecular Catalysis , 1992 , 72 (1) : 117 —125
[57 ] Oliveros I , Zurita MJ P , Scott C , et al . Journal of Catalysis , 1997 ,171 (2) : 485 —489
{{custom_fnGroup.title_cn}}
脚注
{{custom_fn.content}}
/
| 〈 |
|
〉 |