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化学进展 2004, Vol. 16 Issue (02): 266- 前一篇   后一篇

• 综述与评论 •

不对称催化氢甲酰化中高效手性配体的进展*

任运来;赵文成;吕士杰**   

  1. (中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室 兰州 730000)
  • 收稿日期:2002-12-01 修回日期:2003-03-01 出版日期:2004-03-24 发布日期:2004-03-24
  • 通讯作者: 吕士杰
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Progress in Chiral Ligands for Asymmetric Catalytic Hydroformylation

Ren Yunlai;Zhao Wencheng;Lv Shijie**   

  1. (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China)
  • Received:2002-12-01 Revised:2003-03-01 Online:2004-03-24 Published:2004-03-24
  • Contact: Lu Shijie
比较系统地总结了应用于不对称催化氢甲酰化方面各类配体的合成、设计思路及性能,侧重于评述高效配体的最新进展.
关键词： 不对称催化, 氢甲酰化, 手性配体
Crucial to the success in asymmetric hydroformylation is the design and synthesis of ligunds. In the last decades, a number of excellent ligands have been found. But most of them are diphosphine or diphosphite ligands. Thus the features, development and applications of chiral ligands on asymmetric catalytic hydroformylation are the major focus of this review. Additionally, their mechanistic and conceptual background is included with 72 references.
Key words: asymmetric catalysis, hydroformylation, chiral ligands

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