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化学进展 1995, Vol. 7 Issue (04): 253-   后一篇

• 综述与评论 •

二十面体壳层结构——纪念C60发现10周年

郭可信   

  1. (中国科学院北京电子显微镜实验室 北京 100080)
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1995-12-01 发布日期:1995-12-01
  • 通讯作者: 郭可信

Icosahedral Shell Structures--Geodesic Domes, Virus, C60 and Fullerenes

Guo Kexin   

  1. (Beijing Laboratory of Electron Microscopy, Chinese Academy of Sciences, Beijing 100080)
  • Received:1900-01-01 Revised:1900-01-01 Online:1995-12-01 Published:1995-12-01
  • Contact: Kexin Guo

圆顶建筑、病毒衣壳和C60分子·笼的生成机制和尺寸差别很大,但都属二十面体壳层,遵循同一几何规律。圆顶建筑和病毒衣壳由近似全等的三角面构成,有12个五键连35顶,10(T-1)个六键连36顶,其中三角面数T=h2+hkk2是二十面体的一个三角中的小三角面数,h,k是六角坐标系中35顶的坐标。另一方面,全碳分子笼Cn(包括其原型C60)由12个五角面与10(T-1)个六角面围成,全是三键连顶(h,k是一个五角面中心的坐标)。显然,这两类二十面体壳层是对偶的,也就是它们的面、顶有互换关系。本文讨论这些二十面体壳层的几何特征及富勒烯的多样性,强调不同学科间的联系和科学研究的继承与发展的关系。

Though the dimensions and formation mechanisms of geodesic domes, the protein capsids of virus,and the C60 molecular cage vary significantly, they all belong to the same category of the icosahedral shells and consequently follow the same geometrical rules. Geodesic domes and virus capsids consist of triangular faces of almost the same size (quasi-equivalence)forming 12 penta-connected 35 and 10(T-1)hexa-connected 36 ver- tices, where T=h2+hkk2is the triangular number or the number of small triangles in an icosahedral face, and h, k are the hexagonal coordinates between two 35 vertices. On the other hand,the fullerene Cn,including the archetype C60,consists of 12 pentagonal faces and 10(T-1)hexagonal faces forming only tri-connected vertices,now hk become thehexagonal coordinates between the centers of two pentagonal faces. Obviously,these two kinds of icosahedral shells are duals with each other,or,in other words,their faces and vertices are interchanged. The geometrical characteristics of these icosahedral shells are discussed and the great variety of fullerenes is emphasized.

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