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化学进展 2016, Vol. 28 Issue (12): 1788-1797 DOI: 10.7536/PC160619 前一篇   后一篇

• 综述与评论 •

Li-Mg-N-H体系储氢材料的热力学和动力学调控

李超1,2*, 范美强1, 陈海潮1, 陈达1, 田光磊1, 舒康颖1*   

  1. 1. 中国计量大学材料科学与工程学院 杭州 310018;
    2. 浙江大学硅材料国家重点实验室 杭州 310027
  • 收稿日期:2016-06-01 修回日期:2016-10-01 出版日期:2016-12-25 发布日期:2016-12-23
  • 通讯作者: 李超,e-mail:lichao@cjlu.edu.cn;舒康颖,e-mail:shukangying@cjlu.edu.cn E-mail:lichao@cjlu.edu.cn;shukangying@cjlu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.51501175）和浙江省自然科学基金项目（No.LQ16E010001）资助
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Thermodynamics and Kinetics Modifications on the Li-Mg-N-H Hydrogen Storage System

Li Chao1,2*, Fan Meiqiang1, Chen Haichao1, Chen Da1, Tian Guanglei1, Shu Kangying1*   

  1. 1. College of Materials Science and Engineering, China Jiliang University, Hangzhou 310018, China;
    2. State Key Lab of Silicon Materials, Zhejiang University, Hangzhou 310027, China
  • Received:2016-06-01 Revised:2016-10-01 Online:2016-12-25 Published:2016-12-23
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 51501175)
Mg（NH2）2-2LiH体系储氢材料具有较高的储氢容量和较适宜的热力学性能，并且其吸放氢过程完全可逆，是目前最有望实现大规模应用的固态储氢材料之一。然而，由于该体系在吸放氢过程中具有较高的动力学壁垒，导致其在200℃以上才能实现快速地吸放氢。因此，国际上对该体系储氢材料的研究主要集中在热力学和动力学的调控方面。本文从成分调变、纳米化和掺杂改性等方面，详细综述了Mg（NH2）2-2LiH体系储氢材料热力学和动力学调控的研究现状，并提出了其中存在的问题和相应对策，同时指出了将来的研究方向。
关键词： 储氢材料, 热力学, 动力学, 氨基物, 氢化物, 性能调控
Mg(NH2)2-2LiH system possesses a higher reversible hydrogen storage capacity and favorable thermodynamics, consequently being regarded as one of the most promising hydrogen storage materials. However, a temperature above 200℃ is needed to obtain quick de-/hydrogenation because of a rather high kinetic barrier. As a result, numerous investigations have been attempted to adjust the hydrogen storage thermodynamics and kinetics properties. Starting from the three aspects of material composites, nanocrystallization and modification by doping, the progress in the hydrogen storage thermodynamics and kinetics is systematically summarized in this review. The challenges and countermeasures are illustrated, and the direction to further enhancing the hydrogen storage properties of the Mg(NH2)2-2LiH system is also pointed out.

Contents
1 Introduction
2 Compositional manipulation of the Li-Mg-N-H system
3 Nanosized Li-Mg-N-H system
4 Modification by doping
4.1 The effect of transition metals and their compounds
4.2 The effect of carbon-based materials
4.3 The effect of metal borohydrides
4.4 The effect of alkali metal-based compounds
4.5 The effect of other dopants
5 Conclusion

Key words: hydrogen storage materials, thermodynamics, kinetics, amides, hydrides, performance adjustment

中图分类号: 

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