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化学进展 2014, Vol. 26 Issue (11): 1832-1839 DOI: 10.7536/PC140723 前一篇   后一篇

• 综述与评论 •

冷冻干燥法制备聚合物基新型材料及其应用

张晓敏, 张力, 贺雪英, 吴俊涛*   

  1. 北京航空航天大学化学与环境学院 仿生智能界面科学与技术教育部重点实验室 北京 100191
  • 收稿日期:2014-07-01 修回日期:2014-07-01 出版日期:2014-11-15 发布日期:2014-09-12
  • 通讯作者: 吴俊涛 E-mail:wjt@buaa.edu.cn
  • 基金资助:

    国家自然科学基金项目(No.51373007, 51003004)、北京市自然科学基金项目(No.2142019)、国家重点基础研究发展计划(973)项目(No. 2010CB934700, 2012CB933200)、中央高校基本科研业务费专项资金和教育部留学回国人员科研启动基金资助

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Fabrication and Application of New Polymer-Based Materials by Freeze-Drying

Zhang Xiaomin, Zhang Li, He Xueying, Wu Juntao*   

  1. Key Laboratory of Bio-Inspired Smart Interfacial Science and Technology of Ministry of Education, College of Chemistry and Environment, Beihang University, Beijing 100191, China
  • Received:2014-07-01 Revised:2014-07-01 Online:2014-11-15 Published:2014-09-12
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No.51373007, 51003004), the Beijing Natural Science Foundation (No.2142019), the National Basic Research Program of China (No.2010CB934700, 2012CB933200), the Fundamental Research Funds for the Central Universities, and the Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

冷冻干燥法是一种环境友好、经济高效的制备通孔先进材料的成型方法,采用冷冻干燥技术高效可控地构筑多孔结构材料备受关注.近年来采用冷冻干燥法制备出的聚合物基新型材料,在不同功能材料领域展现出广阔的应用前景.本文综述了国内外通过冷冻干燥法制备聚合物新型材料的研究进展,对其在生物医学、环境保护、导电以及气体检测方面的应用进行了总结,并展望了其发展趋势.

关键词： 冷冻干燥, 聚合物多孔结构, 功能材料

The freeze-drying technique is an attractive method because it is an environmental friendly and cost-effective shaping process for preparing advanced materials with interconnecting pore channels or pore gradients in bodies. Freeze-drying technology is a kind of methods to build porous structural material efficiently and controllably. In recent years many new polymer-based materials prepared by freeze-drying have exhibited broad applications as functional materials. This article reviews the progress of advanced polymer materials prepared by freeze-drying, and summerizes the applications in the field of materials engineering, environment, biomedicine and other prospects. The research prospects and directions of this rapidly developing field are also briefly addressed.

Contents
1 Introduction
2 The fabrication of polymer-based materials by direct freeze-drying
2.1 Solution freeze-drying
2.2 Emulsion freeze-drying
3 The fabrication of polymer-based materials by indirect freeze-drying
4 Applications of polymer-based materials prepared by freeze-drying
4.1 The application in tissue engineering and medicine
4.2 The application in the fields of adsorption and separation
4.3 The application in conduct electricity and gas detection
5 Conclusion

Key words: freeze-drying, polymeric porous materials, functional materials

中图分类号: 

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