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化学进展 2014, Vol. 26 Issue (11): 1821-1831 DOI: 10.7536/PC140636 前一篇   后一篇

• 综述与评论 •

纳米纤维制备工艺进展及其对壳聚糖的适用性分析

王奕寒1,2, 脇坂港*2   

  1. 1. 扬州大学食品科学与工程学院 扬州 225127;
    2. 九州工業大学大学院生命体工学研究科 北九州 8080196
  • 收稿日期:2014-06-23 修回日期:2014-07-28 出版日期:2014-11-15 发布日期:2014-09-12
  • 通讯作者: 脇坂港 E-mail:wakisaka@life.kyutech.ac.jp
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Nanofiber Fabrication Techniques and Its Applicability to Chitosan

Wang Yihan1,2, Wakisaka Minato*2   

  1. 1. School of Food Science and Engineering, Yangzhou University, Yangzhou 225127, China;
    2. Graduate School of Life Science and Systems Engineering, Kyushu Institute of Technology, Kitakyushu 8080196, Japan
  • Received:2014-06-23 Revised:2014-07-28 Online:2014-11-15 Published:2014-09-12

壳聚糖是一种性质独特、可生物降解及生物相容的海洋多糖,以其为原料制备的纳米纤维目前已经得到了广泛应用.传统的壳聚糖纳米纤维/纳米复合纤维制备方法主要采用湿法纺丝与静电纺丝,但是这些方法通常需要复杂的过程和挥发性有机溶剂的参与,安全性较低.为了探寻更简单、更安全的壳聚糖纳米纤维制备方法,本文综述了6种最新颖的纳米纤维制备过程,这些过程被分为"由小到大捆绑"与"从大到小粉碎"两大类."由小到大捆绑"包含各种纺丝(例如离心甩丝法、手纺法、溶液吹喷法)和两种冷冻铸造(直接冷冻干燥法和射流急速冷冻法),而"从大到小粉碎"则以星爆系统法为例.我们从纤维直径、纤维取向与对壳聚糖的适用性的角度对比讨论了它们各自的优缺点并融合了每种方法给予的灵感,提出了一种全新的"超声喷雾结合冷冻铸造"的壳聚糖纳米纤维制备理念.超声喷雾与冷冻铸造相结合的方法彻底摆脱了挥发溶剂的使用.以这种安全性较高的新方法制备出的壳聚糖纳米纤维在生物医学工程与食品科学工程领域具有广阔的应用潜能.

关键词： 壳聚糖纳米纤维, 纺丝, 冷冻铸造, 乳浊液碰撞, 制备工艺

Chitosan is a biodegradable and biocompatible polymer with unique properties derived from marine resources, it is expected as important raw material for nanofibers with wide range of applications. Chitosan and its composite nanofibers have been fabricated by traditional spinning processes such like wet spinning or electrospinning, but these processes are complex, using harmful solvent or high voltage with lower safety. In search of more simple and safe nanofiber fabrication method applicable to chitosan, six kinds of novel nanofiber fabrication methods are reviewed, these methods are divided into two major categories of "small~large" approach and "large~small" approach. "Small~large" approach includes variety of spinning processes (such as rotary jet-spinning, handspinning and solution blowing) and two freeze casting processes (simple freeze-drying and jet-rapid freezing), while star burst system as an example of "large~small" approach. Both advantages and disadvantages of each method are compared from the viewpoint of fiber diameter, fiber orientation and the applicability to chitosan. A new innovative idea of combining ultrasonic atomization and freeze casting process for chitosan nanofibers is also provided in this review. Ultrasonic atomization combined with freeze casting method is simple and avoids usage of volatile solvents. Chitosan nanofibers obtained by this innovative method could be applicable to biomedical engineering and food engineering due to both chitosan's characteristics and the safety of fabrication process.

Contents
1 Introduction
2 Spinning nanofiber fabrication methods
2.1 Rotary jet-spinning
2.2 Handspinning
2.3 Solution blowing
3 Freeze casting nanofiber fabrication methods
3.1 Simple freeze-drying
3.2 Jet-rapid freezing
4 Star burst nanofiber fabrication method
5 Conclusion and outlook

中图分类号: 

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