化学进展

图/表详细信息

锌-碘电池正极用碳材料

关银燕, 郝小蕊, 徐锐, 李洪飞, 吴禹翰, 梁吉艳

化学进展, 2025, 37(5): 775-787. DOI: 10.7536/PC240610

type	cathode materials	anode materials	electrolyte	cyclic stability	retention	Ref
Carbon nanotube-based cathodes	HCNS	Zn flake	0.5 M ZnSO₄ + 0.5 M H₂SO₄	94 mAh·g^-1@1 A·g^-1/1500 cycles	87%	24
	HCNT-O	Zn foil	hydrogel electrolyte（CPAM-Zn-I-0.5）	352.5 μAh·cm^-2@10 mA·cm^-2/2600 cycles	89.20%	48
	CNT@MPC12	Zn foil	1 M ZnSO₄	0.38 mAh·cm^-2@10 mA·cm^-2/12000 cycles	91%	25
Graphene-based cathodes	I₂/3DGC	Zn foil	1 M ZnSO₄	205 mAh·g^-1@3.2 C/400 cycles	99%	54
	rGO-I₂	Zn foil	20 M ZnCl + 5 M KI	2 mAh·cm^-2@50 mA·cm^-2/2000 cycles	100%	26
	PNC-1000-I₂	Zn foil	1 M ZnSO₄	200mAh·g^-1@1 A·g^-1/1000 cycles	89%	56
	N-rGO	Zn@rGO	2 M KI + 0.5 M NaSO₄	150 mAh·g^-1@5 A·g^-1/2000 cycles	96.70%	57
	G/PVP@ZnI₂	CuNC@Cu/Zn	2 M ZnSO₄	125.7mAh·g^-1@1 A·g^-1/200 cycles	63.80%	58
	HOPG	Zn foil	ZnI₂ + ZnSO₄/H₂O + EG	144.1 mAh·cm^-3@5 A·g^-1/15000 cycles	97.60%	59
Activated carbon-based cathodes	I₂@C-50	Zn foil	2 M Zn（CF₃SO₃）₂	151 mAh·g^-1@5 A·g^-1/10000 cycles	75%	60
	I₂-AC-6	Zn foil	1 M ZnSO₄	104 mAh·g^-1@5 A·g^-1/6000 cycles	90%	62
	I₂@APCC	Zn foil	5.9 M ZnCl₂ + 0.2 M KI	523.69 mAh·g^-1@500 mA·g^-1/600 cycles	92.20%	61
Biomass-derived carbon-based cathodes	I-BC_HP	Zn foil	1 M ZnSO₄	70 mAh·g^-1@300 mA·g^-1/800 cycles	/	62
	N-LPC/I₂	Zn foil	1 M ZnSO₄	114 mAh·g^-1@300 mA·g^-1/400 cycles	99%	64
	I₂@APCC	Zn foil	5.9 M ZnCl₂ + 0.2 M KI	523.69 mAh·g^-1@500 mA·g^-1/600 cycles	92.20%	65
Other porous carbon material-based cathodes	I₂@C	Zn/C	2 M ZnSO₄	122.3 mAh·g^-1@12 C/3000 cycles	88.10%	67
	NCCs/I₂	Zn foil	2 M ZnSO₄	131 mAh·g^-1@5 A·g^-1/3500 cycles	/	68
	HMMC-I₂ NSs	Zn foil	1 M ZnSO₄	137.5mAh·g^-1@8 A·g^-1/9200 cycles	92.10%	69
	CMK-3@I₂	Zn foil	2 M ZnSO₄	10 A·g^-1/39000 cycles	80.60%	70
	NGA/I₂	Zn foil	1 M ZnSO₄	178.8 mAh·g^-1@5 C/10000 cycles	/	71