化学进展

图/表详细信息

非富勒烯受体DA'D型稠环单元的结构修饰及电池性能研究

薛朝鲁门, 刘宛茹, 白图雅, 韩明梅, 莎仁, 詹传郎

化学进展, 2022, 34(2): 447-459. DOI: 10.7536/PC201143

Compounds	Acceptor	$E g o p t$ [eV]	HOMO/LUMO [eV]	μ_h[10^-4 cm² V^-1s^-1]	μ_e[10^-4 cm² V^-1s^-1]	Donor	J_SC (mA/cm²)	V_OC (V)	FF (%)	PCE (%)	ref
A1	Y6	1.31	-5.65/-4.10	2.77	2.54	PM6	25.20	0.82	76.10	15.70	23
A2	AQX-1	1.35	-5.59/-3.85	0.58	3.72	PM6	22.18	0.89	67.14	13.31	46
A3	AQX-2	1.35	-5.62/-3.88	1.34	2.89	PM6	25.38	0.86	76.25	16.64	46
A4 A5 A6	TPQx-4F TPQx-6F QIP-4F	1.41 1.43 1.54	-5.54/-3.56 -5.66/-3.62 -5.75/-3.86	4.53 6.47 0.74	2.65 4.57 4.71	PM6 PM6 P2F-EHp	15.42 22.37 18.27	0.94 0.92 0.94	54.52 72.16 70.53	7.75 14.62 12.12	47 47 48
A7	BZIC	1.45	-5.42/-3.88	1.15	1.11	HFQ_X-T	12.67	0.84	59.00	6.30	33
A8	Y1	1.44	-5.45/-3.95	1.56	3.04	PBDB-T	22.44	0.87	69.10	13.42	49
A9	BTPT-4F	1.45	-5.73/-4.00	-	-	P2F-EHP	3.20	0.78	43.78	1.09	50
A10	X94FIC	1.25	-5.58/-4.17	1.49	6.10	PBDB-T	14.67	0.73	66.10	7.08	51
A11	N3	-	-	5.9	4.8	PM6	25.81	0.84	73.90	15.98	52
A12	N4	-	-	3.2	1.4	PM6	25.01	0.82	69.90	14.31	52
A13	N-C11	-	-	3.1	1.1	PM6	21.47	0.85	70.60	12.91	52
A14	BTP-4F-12	1.33	-5.68/-4.06	-	7.4	PM6	25.30	0.86	76.0	16.40	53
A15	DTY6	-	-5.67/-4.04	-	4.73	PM6	25.25	0.858	75.4	16.3	54
A16	Y6-PhC6	-	-5.74/-4.05	9.12	2.29	PM6	21.80	0.803	67.3	11.77	55
A17	Y6-PhOC6	-	-5.75/-4.08	0.46	0.42	PM6	21.31	0.844	61.6	11.07	55
A18	Y6-nC8	-	-5.71/-4.02	2.35	3.84	PM6	19.07	0.863	63.1	10.38	55
A19	C4	1.39	-5.60/-4.05	-	-	PM6	15.74	0.689	67.01	7.28	56
A20	BTPT-4Cl	1.40	-5.68/-4.12	2.12	1.58	PM6	25.4	0.867	75	16.5	57
A21	BTIC-BO-4Cl	1.34	-5.54/-4.14	3.1	1.1	PM6	25.6	0.858	77.6	17.0	58
A22	BTIC-HD-4Cl	1.34	-5.58/-4.14	5.9	4.8	PM6	24.2	0.862	74.8	15.6	58
A23	N3-4Cl	1.35	-5.63/-3.98	7.65	4.45	PM6	25.90	0.85	74.9	16.53	59
A24	BTIC-4Br	1.46	-5.57/-4.11	4.8	1.1	PM6	20.67	0.85	69.58	12.2	60
A25	BTIC-BO-4Br	1.44	-5.53/-4.09	1.4	4.5	PM6	24.06	0.86	67.84	14.03	60
A26	BTIC-2Br-m	1.49	-5.56/-4.07	1.9	1.1	PM6	25.03	0.88	73.13	16.11	60
A27	BTP-PhC6	1.36	-5.58/-3.85	6.25	7.19	PM6	25.00	0.86	77.00	16.70	61
A28	BTP-C6Ph	1.35	-5.60/-3.94	4.53	6.12	PM6	24.30	0.84	76.20	15.50	61
A29	BTPS-4F	1.38	-5.73/-3.91	1.2	2.1	PM6	24.8	0.82	76	16.2	62
A30	BTP-eC9	1.4	-5.64/-4.05	-	2.7	PM6	26.20	0.84	81.10	17.80	15
A31	BTP-eC7	1.4	-5.62/-4.03	-	1.28	PM6	24.10	0.843	73.50	14.90	15
A32	Y1-4F	1.31	-5.56/-4.11	5.25	3.01	PM6	25.2	0.83	68.50	14.80	63
A33	Y11	1.31	-5.69/-3.87	-	-	PM6	26.74	0.83	73.33	16.54	64
A34	Y18	1.31	-5.58/-3.91	5.74	5.27	PM6	25.33	0.84	76.50	16.52	65