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化学进展 2009, Vol. 21 Issue (01): 235-243 前一篇   后一篇

• 综述与评论 •

非对称混合电池/混合电容器*

徐睿1 ;唐子龙1** ;李俊荣2 ;张中太1   

  1. (1. 清华大学材料科学与工程系 新型陶瓷与精细工艺国家重点实验室 北京 100084； 2. 中国航天员中心 北京 100094)
  • 收稿日期:2008-03-12 修回日期:2008-05-03 出版日期:2009-01-24 发布日期:2009-01-25
  • 通讯作者: 唐子龙 E-mail:tzl@tsinghua.edu.cn
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Asymmetric Hybrid Electrochemical Cell/Capacitor

Xu Rui1 ;Tang Zilong1** ;Li Junrong2 ;Zhang Zhongtai1   

  1. (1. State Key Laboratory of New Ceramics and Fine Processing, Department of Materials Science and Engineering, Tsinghua University, Beijing 100084, China|2. China Astronaut Center, Beijing 100094, China)
  • Received:2008-03-12 Revised:2008-05-03 Online:2009-01-24 Published:2009-01-25
  • Contact: Tang Zilong E-mail:tzl@tsinghua.edu.cn

非对称混合电池/混合电容器（asymmetric hybrid electrochemical cell/capacitor, AHEC）的发展源于电动汽车、电子存储设备、家用电气、航天航空设备等对高能量密度和高功率密度储能装置的需求。AHEC具有较长的循环寿命、较低的自放电性能和高于电池的功率密度、高于电容器的能量密度。本文对非对称电池/电容器的发展历史做了简短的介绍，重点讨论了研究现状和存在的问题，并对今后的发展方向进行了评述。

关键词： 非对称混合电池/混合电容器, 电池, 电容器

The development of asymmetric hybrid electrochemical cell/capacitor (AHEC) has been driven by an ever-increasing demand on high energy and power density energy storage devices for electric vehicles (EV), potable electronic devices, as well as space and military applications. AHEC combine the merits of Li-ion batteries and supercapacitors, offering higher power density than lithium ion cells, and higher energy density than supercapacitors, as well as long charge-discharge cycling life, and low self-discharge rate. Here we present a brief historical review of the development of asymmetric hybrid electrochemical cell/capacitor, discuss the present situation and challenges that remain regarding the energy/power density and lifetime of the systems, and highlight ongoing research strategies on AHEC.

Contents
1 Introduction
2 Historical developments in asymmetric hybrid electrochemical cell/capacitor research
3 Present status and remaining challenges
4 Materials for asymmetric hybrid electrochemical cell/capacitor electrodes
4.1 Carbon materials
4.2 Metal materials
4.3 Metal oxides
4.4 Li-intercalation materials
4.5 Polymers
5 Conclusion

Key words: asymmetric hybrid electrochemical cell/capacitor, cells, capacitors

中图分类号: 

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非对称混合电池/混合电容器*