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化学进展 2008, Vol. 20 Issue (05): 650-656 前一篇   后一篇

• 综述与评论 •

ZSM-5分子筛在低碳烷烃脱氢中的催化应用*

胥月兵 陆江银** 钟梅 王吉德   

  1. （新疆大学 石油天然气精细化工教育部重点实验室 乌鲁木齐 830046）
  • 收稿日期:2007-06-11 修回日期:2007-06-25 出版日期:2008-05-24 发布日期:2008-05-24
  • 通讯作者: 陆江银
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Catalytic Application of ZSM-5 Molecular Sieve for Light Alkanes Dehydrogenatoin

Xu Yuebing; Lu Jiangyin**; Zhong Mei; Wang Jide   

  1. (Key Laboratory of Oil & Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China)
  • Received:2007-06-11 Revised:2007-06-25 Online:2008-05-24 Published:2008-05-24
  • Contact: Lu Jiangyin
ZSM-5分子筛是应用广泛的催化体系，常用于烷烃的芳构化、催化裂化及异构化。近年来因其独特的孔道结构及表面酸碱特性，开始应用于低碳烷烃脱氢。本文综述了Zn/ZSM-5及Ga/ZSM-5催化剂对低碳烷烃的脱氢理论研究，概述了Fe/ZSM-5、Cr/ZSM-5、Pt/ZSM-5以及一些其他过渡金属催化剂对低碳烷烃的催化应用；探讨了ZSM-5基催化剂的影响因素如硅铝比、焙烧温度及制备方法等，以利于对低碳烷烃脱氢可作进一步了解；最后对ZSM-5催化体系进行了评述及展望。
关键词： ZSM-5, 脱氢, 低碳烷烃, 金属元素
ZSM-5 molecular sieve was widely used as catalysts for aromatization, catalytic cracking and isomerization. Recently The ZSM-5 was applied to light alkanes dehydrogenation due to its unique bore configuration and the character of surface acidity. The paper summarized the progress of ZSM-5 in application and theoretical research for light alkanes dehydrogenation, including Zn/ZSM-5, Ga/ZSM-5 for theory of dehydrogenation used computer simulation, and the ZSM-5 catalysts modified with Fe, Cr, Pt and some transition metal else prepared by liquid-ion exchange and impregnation methods. The influencing factors of ZSM-5-based catalysts such as Si/Al, calcination temperature and the preparation methods are discussed. Further prospects of the ZSM-5-based catalysts are provided.
Key words: ZSM-5 molecular sieve, dehydrogenation, light alkanes, metal elements

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