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化学进展 2008, Vol. 20 Issue (05): 629-636 前一篇   后一篇

• 综述与评论 •

胶体半导体纳米晶的能带宽调控新方法*

顾震宇 朱为宏 钟新华**

  

  1. （华东理工大学化学与分子工程学院 结构可控先进功能材料及其制备教育部重点实验室 上海 200237）
  • 收稿日期:2007-06-01 修回日期:2007-07-13 出版日期:2008-05-24 发布日期:2008-05-24
  • 通讯作者: 钟新华
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New Methods for Tuning Band Gap of Colloidal Semiconductor Nanocrystals

Gu Zhenyu; Zhu Weihong; Zhong Xinhua**   

  1. (Laboratory for Advanced Materials, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China)
  • Received:2007-06-01 Revised:2007-07-13 Online:2008-05-24 Published:2008-05-24
  • Contact: Zhong Xinhua
由于量子限域效应，半导体纳米晶的能带宽随粒子大小而改变。单纯依靠改变纳米晶大小来调控能带宽将引起许多技术和应用上的不便。本文对胶体半导体纳米晶的能带宽调控新概念和新的合成途径，包括近年来发展起来的通过采用合金纳米晶、反转Type－I及Type－II核/壳结构等进行了综述，并对各种途径的优缺点进行了描述。
关键词： 胶体, 半导体纳米晶, 能带宽调控, 合金纳米晶, 核/壳结构
Due to quantum confinement effect, band gap of semiconductor nanocrystals (NCs) is dependent on the particle size. However, tuning band gap of NCs simply by changing particle size may cause problems technically. Herein, we review new concepts and new routes to tune band gap of NCs including alloyed NCs, inverted Type- I and Type- II core/shell structur and their corresponding advantages.
Key words: colloid, semiconductor nanocrystals, band gap engineering, alloyed nanocrystals, core/shell structure

中图分类号: 

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