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化学进展 2008, Vol. 20 Issue (0203): 280-287 前一篇   后一篇

• 综述与评论 •

金属-氮-氢体系储氢材料*

刘淑生1,2 孙立贤1** 徐芬1   

  1. (1. 中国科学院大连化学物理研究所 大连 116023； 2. 中国科学院研究生院 北京 100049）
  • 收稿日期:2007-04-23 修回日期:2007-06-11 出版日期:2008-03-24 发布日期:2008-03-24
  • 通讯作者: 孙立贤
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Metal-N-H Systems as Hydrogen Storage Materials

Liu Shusheng1,2; Sun Lixian1**; Xu Fen1   

  1. (1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China; 2. Graduate School of the Chinese Academy of Sciences, Beijing 100049, China)
  • Received:2007-04-23 Revised:2007-06-11 Online:2008-03-24 Published:2008-03-24
  • Contact: Sun Lixian
氢能作为未来理想的清洁能源之一，已经成为全球研究的重要领域，而在氢能的应用中最关键的问题是氢气的存储。近年来，人们的研究集中在固态储氢材料上，许多新型储氢材料不断出现，其中由轻元素组成的金属-氮-氢体系拥有储氢容量高、可逆性好等优点，被认为是最有前景的储氢材料之一。截至目前，金属-氮-氢体系已经发展出许多体系，而研究最多的是Li-N-H和Li-Mg-N-H两种体系。本文重点综述了两者作为可逆储氢材料的研究现状，主要从制备方法、储氢性能、反应机理、理论计算和存在的问题等方面进行了讨论，同时指出了金属-氮-氢储氢体系的发展趋势。
关键词： 轻元素, 储氢, 金属-氮-氢, Li-N-H, Li-Mg-N-H
Hydrogen is one of the ideal clean energies in the future and has become an important research field all over the world. The storage of hydrogen is the most critical issue for the application of hydrogen energy. In recent years, attention has been mainly focused on solid hydrogen storage materials. As a result, many new hydrogen storage materials have been developed. Among them, metal-nitrogen-hydrogen (Metal-N-H) systems composed of light elements possess quite high hydrogen storage capacity and good reversibility so that they are viewed as ones of the most promising hydrogen storage materials. So far, many systems have occurred in the realm of Metal-N-H systems. Two most attractive reversible hydrogen storage materials are Li-N-H system and Li-Mg-N-H system，and the recent studies are reviewed in this paper. We mainly put the emphasis on the preparation methods, hydrogen storage properties, reaction mechanisms, theory calculations and remaining problems of Li-N-H system and Li-Mg-N-H system. At the same time, the development trend of Metal-N-H systems is also introduced.
Key words: light elements, hydrogen storage, Metal-N-H, Li-N-H, Li-Mg-N-H

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摘要

金属-氮-氢体系储氢材料*