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化学进展 2007, Vol. 19 Issue (11): 1703-1709 前一篇   后一篇

• 综述与评论 •

液相法制备（亚）铁磁性纳米材料*

赵涛1,2 孙蓉2 冷静2,3 杜如虚2,3 张治军1**   

  1. （1. 河南大学 特种功能材料重点实验室 开封 475001；2. 中国科学院香港中文大学深圳先进集成技术研究所 中国科学院深圳先进技术研究院 深圳 518067；3. 香港中文大学精密工程研究所 香港 999077）
  • 收稿日期:2006-12-15 修回日期:2007-04-29 出版日期:2007-11-14 发布日期:2007-11-25
  • 通讯作者: 张治军
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Liquid-Phase Synthesis of Ferrimagnetic/Ferromagnetic NanoMaterials

Zhao Tao1,2 Sun Rong2 Leng Jing2,3 Du Ruxu2,3 Zhang Zhijun1**   

  1. (1. Key Lab for Special Functional Materials, Henan University, Kaifeng 475001，Chian；2. Shenzhen Institute of Advanced Integration Technology，Chinese Academy of Sciences, Chinese University of Hong Kong, Shenzhen 518067，Chian；3. Institute of Precision Engineering , The Chinese University of Hong Kong, Hong Kong 999077，Chian)
  • Received:2006-12-15 Revised:2007-04-29 Online:2007-11-14 Published:2007-11-25
  • Contact: Zhang Zhijun
（亚）铁磁性纳米材料因其特殊的磁学性能，在生物、医药、电子器件、军工等领域具有广泛的应用前景。本文综述了（亚）铁磁性纳米金属铁、钴、镍以其合金和铁氧体的液相制备方法，包括沉淀法、水热/溶剂热法、微乳液法、多元醇工艺、热分解法、溶胶-凝胶法和超声化学法等；详细介绍了这些方法的反应机制和发展现状以及应用上述方法制备相关纳米材料的过程；分析了有关（亚）铁磁性纳米材料能够实现产业化的制备方法的发展趋势。
关键词： 液相法, （亚）铁磁性纳米材料, 反应机制, 产业化
Ferrimagnetic/ferromagnetic nanomaterials are widely used in biology, medicine, Electronic devices and military industry Etc,because of their unusual magnetic properties.This paper reviews the synthesis of ferrimagnetic/ferromagnetic nano-materials, such as Fe, Co, Ni, alloys and ferrites, by using the liquid-phase methods such as precipitation、hydrothermal/solvothermal processing、micelle routes、polyol processing、thermolysis、sol-gel methods and sonochemical. The reaction mechanisms and the status quo of the liquid-phase methods as well as the preparation processes of related nano-materials using these methods are given. The future of the liquid-phase methods to realize industrialization of nanomaterilas is analyzed as well.
Key words: Liquid-phase Syntheses, ferromagnetic/ferrimagnetic nano-materials, reaction mechanism, industrialization

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