English
往期目录
新闻公告
More
化学进展 2007, Vol. 19 Issue (0708): 1177-1184 前一篇   后一篇

• 专题论坛 •

秸秆资源循环经济利用模式——纸浆与肥料联产的清洁生产技术体系

张小勇*;莫海涛;江启沛;李佐虎   

  1. 中国科学院过程工程研究所生化工程国家重点实验室 北京 100080
  • 收稿日期:2007-03-19 修回日期:1900-01-01 出版日期:2007-08-17 发布日期:2007-08-17
  • 通讯作者: 张小勇
下载PDF ( 2342 ) 引用
导出 被引次数 ( 30 | 5 )

The Mode of Cycle Economy Utilization of Stalk——the Technique System of Clean Production by the Co-Production of Pulp and Organic Fertilizer

Zhang Xiaoyong*;Mo Haitao;Jiang Qipei;Li Zuohu   

  1. State Key Laboratory of Biochemical Engineering,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100080,China
  • Received:2007-03-19 Revised:1900-01-01 Online:2007-08-17 Published:2007-08-17
本文对我国秸秆资源利用和肥料使用现状、清洁制浆技术的进展进行了较为详细的论述，介绍了纸浆与肥料联产的循环经济利用模式的内容和发展前景。该模式采用熔态水解法自制氢氧化钾并联产磷肥以降低原料成本，用氢氧化钾对秸秆进行蒸煮得到纸浆，通过用含钾黑液来制备液体肥料、固体有机肥料和灌溉水，使黑液全部得到资源化利用而实现系统内无污染物排放。秸秆资源来自于农业，所加工的肥料又服务于种植业，同时又生产了造纸工业急需的纸浆，因而采用这种肥料与纸浆联产的技术体系是实现秸秆资源得到清洁、高效、经济地利用的有效途径。
关键词： 秸秆, 有机肥料, 联产, 熔态水解, 钾碱制浆, 循环经济
Co-production of pulp and organic fertilizer is an effective method to realize clean utilization of stalk. In this paper, the evolution of stalk utilization and clean pulp technique are reviewed in detail, the content of this cycle economic mode and the prospect in future are introduced. The mode apply the melt hydrolyzation technology to prepare KOH and phosphorus fertilizer in order to reduce the material cost, and use KOH to cook the straw to produce pulp. The black liquor rich with Potassium can be used to produce the liquid fertilizer, solid organic fertilizer and irrigation water, and the liquor can be entirely achieved resource utilization, therefore no waste would be released out of the whole system. The straw come from the agriculture, and the fertilizer made from the straw return to serve the farming, at the same time the pulp which is urgent for paper industry is prepared. So the technique system of clean production by the co-production of pulp and fertilizer is the good way to realize the clean and effective utilization of straw resource.
Key words: stalks, organic fertilizer, co-production, melt hydrolyzation technology, potassium cooking, cycle economy

中图分类号: 

()

[ 1 ] Annstas P T , Warner J C. Green Chemistry : Theory and Practice.Oxford : Oxford University Press , 1998. 1 —10
[ 2 ] 徐惠忠(Xu H Z) , 王德义(Wang D Y) , 赵明(Zhao M) . 固体废弃物资源化技术(The Technology of Resources Utilization of Solid Wastes) . 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 2004. 1 —16
[ 3 ] 张懿(Zhang Y) . 过程工程学报(The Chinese Journal of Process Engineering) , 2001 , 1 —34
[ 4 ] 张懿(Zhang Y) . 源头污染控制与废弃物再生循环(Recycle of Wastes and Control of Source Pollution) . 北京: 中国纺织工业出版社(Beijing : China Textile Industry Press) , 2001 , 358 —368
[ 5 ] 卞有生(Bian Y S) . 生态农业中废弃物的处理与再生利用( Treatment and Re2utilization of Wastes in Ecological Agriculture) . 北京: 化学工业出版社(Beijing : Chemical Industry Press) , 20001 5
[ 6 ] Kuwatsuka S , Watanabe A. Soil Sci . Plant Nutr. , 1992 , 38(1) :23 —30
[ 7 ] 中国造纸协会(China Paper2making Association) . 浙江造纸(Zhejiang Paper2Making) , 2004 , 2 : 2 —6
[ 8 ] 赵丽英( Zhao L Y) . 濮阳教育学院学报(Journal of Puyang College of Education) , 2001 , 14(2) : 33 —34
[ 9 ] 国家环境保护总局科技标准司编著(ed. by Sci . Tech. Dept .State Enviro. Prot . Adminis. ) . 草浆造纸工业废水污染防治技术指南(The Guide of Prevention and Cure Technology of Waste Water in the Straw Paper Industry) . 北京: 中国环境科学出版社(Beijing : China Environment Science Press) , 2000
[10] 陈思亮(Chen S L) . 北方造纸(China Pulp & Paper Making) ,1997 , 4 : 13
[11] Kathy J P ( 王菊花译) . 纸浆造纸化学工艺学( Chemical Technology of Pulp and Paper Making) . 北京: 中国轻工业出版社(Beijing : China Light Industry Press) , 1998
[12] 林乔元(Lin Q Y) . 中国造纸(China Paper Making) , 2003 , 22(9) : 62
[13] 李忠正(Li Z Z) . 国际造纸( International Paper Making) ,2000 , 18(3) : 14 —16
[14] Loffe L O. Khim. , 1975 , (5) : 60 —65
[15] Loffe L O. Bum. Prom- st . , 1974 , (7) : 8 —10
[16] Deineko I P. Khim. Drev. , 1989 , (3) : 76 —83
[17] Huang G L , Chen Z S , Zhang C F. 林产化学与工业(Chemical and Industry of Wood Production) , 2002 , 22(4) : 31 —36
[18] Huang G L , Chen Z S , Zhang C F. 过程工程学报(Chinese Journal of Process Engineering) , 2002 , 2(6) : 547 —552
[19] 张进城( Zhang J C) . 南京林业大学硕士学位论文(Master Thesis of Nanjing Forestry University) , 2005
[20] 龙柱(Long Z) . 西北轻工学院硕士学位论文(Master Thesis of Northwest Light Industry University) , 1995
[21] 詹怀宇(Zhan H Y) . 中国造纸(China Paper Making) , 1993 ,1 : 13
[22] 詹怀宇(Zhan H Y) , 岳保珍(Yue B Z) , 陈港(Chen G) . 中国造纸(China Paper Making) , 1994 , 4 : 38 —43
[23] 盛利元(Sheng L Y) . CN1 167 853 , 1997
[24] 崔安平(Cui A P) . CN 1 206 761A , 1999
[25] 顾小平(Gu X P) , 吴晓丽(Wu XL) . CN 1 436 895 , 2003
[26] 顾小平(Gu X P) , 吴晓丽(Wu XL) . CN 1 537 830A , 2004
[27] 谢来苏(Xie L S) . 制浆造纸的生物技术(Biotechnology of Pulp and Paper Making) . 北京: 化学工业出版社(Beijing :Chem. Indu. Press) , 20031 6
[28] Yu H S , Chang H M. Biotechnology in Pulp and Paper Manufacture. London : Butterworth Heinemann , 1989. 59 —68
[29] 张爱萍(Zhang A P) , 秦梦华(Qin M H) , 徐清华(Xu Q H) .西南造纸(Southwest Paper Making) , 2005 , 34(2) : 20
[30] 尤纪雪(You J X) , 叶汉林(Ye HL) , 童国林(Tong GL) . 中国造纸(China Paper Making) , 2004 , 23
[31] Scott GM, Akhtar M, Lentz M, et al . Biotechnology in the Pulp and Paper Industry : Recent Advances in Applied and Fundamental Research. Vienna : Faculats2Universitasverlag , 1996. 217 —220
[32] 秦梦华(Qin M H) , 傅英娟(Fu YJ ) , 劭志勇(Shao Z Y) , 高培基( Gao P J ) . 中国造纸学报(The Chinese Journal of Paper Making) , 2005 , 15 : 33 —38
[33] 秦梦华(Qin M H) , 陈嘉翔(Chen J X) . 纸和造纸(Paper and Paper Making) , 1995 , (2) : 4 —6
[34] Jujop P. Pulp and Paper International , 1991 , 33(9) : 81 —83
[35] 陈军(Chen J ) , 韩波(Han B) , 杨俊杰( Yang J J ) . 云南科技管理( Yunnan Science and Technology Managment ) , 2004 , 17(1) : 33 —34
[36] 窦新田(Dou X T) . 生物固氮(Biological Nitrogen Fixation) . 北京: 农业出版社(Beijing : Agriculture Press) , 19891 8
[37] 李庆逵(Li Q K) , 朱兆良(Zhu ZL) , 于天仁(Yu T R) . 中国农业可持续发展中的肥料问题( Fertilizer Problem of the Agriculture Continuous Development in China) . 南昌: 江西科学技术出版社(Nanchang : Jiangxi Science and Technology Press) ,1998
[38] 章守陶(Zhang S T) , 谢天镳(Xie T L) . 新疆化工(Xinjiang Chemical Industry) , 1995 , 1 : 20 —24
[39] Palgrave D A. Fluid Fertilizer Science and Technology. New York : Marcel Dekker Inc. , 1991
[40] 张珂(Zhang K) , 周思毅(Zhou S Y) . 造纸工业蒸煮废液的综合利用与污染防治技术( Technology of Multipurpose Utilization and Pollution Prevention of Cooking Waste Water in Paper Industry) . 北京: 中国轻工业出版社(Beijing : China Light Industry Press) , 1992
[41] 张小勇(Zhang X Y) . 中国科学院过程工程研究所博士论文(Doctoral Thesis of Institute of Process Engineering , CAS) , 1999
[42] Garcia M C. Diez J A , Diez A. Industrial Engineering Chemical Resources (ACS) , 1996 , 35 : 245 —249
[43] 王德汉(Wang D H) , 彭俊杰(Peng J J) , 廖宗文(Liao Z W) .农业环境科学学报( Journal of Agriculture Environment Science) , 2003 , 22(2) : 185 —188
[44] 曹玲(Cao L) , 全金英(Quan J Y) , 李忠正(Li Z Z) . 中华纸业(Chinese Paper Industry) , 1998 , (2) : 68 —70
[45] Dietrich M, Virgilio Z P. Bioresource Technology , 1994 , 49 (2) :121 —128
[46] 王德汉(Wang D H) , 彭俊杰(Peng J J) , 廖宗文(Liao Z W) .上海环境科学(Shanghai Environment Science) , 2003 , 22 (2) :106 —109
[47] 朱兆华(Zhu Z H) , 王德汉(Wang D H) , 廖宗文(Liao Z W) .农业环境保护(Agriculture Environment Protection) , 2001 , 20(2) : 98 —100
[48] 王德汉(Wang D H) , 朱兆华(Zhu Z H) , 彭俊杰(Peng J J ) .农业环境科学学报( Journal of Agriculture Environment Science) , 2003 , 22(5) : 574 —577
[1] 李孔斋,王华,魏永刚,敖先权,刘明春. 晶格氧部分氧化甲烷制合成气*[J]. 化学进展, 2008, 20(09): 1306-1314.
[2] 赵岩,王洪涛,陆文静,李冬. 秸秆超（亚）临界水预处理与水解技术*[J]. 化学进展, 2007, 19(11): 1832-1838.
[3] 刘宏娟,杜伟,刘德华. 生物柴油及1,3-丙二醇联产工艺产业化进展[J]. 化学进展, 2007, 19(0708): 1185-1189.
[4] 宗志敏,赵炜,唐仕荣,周磊,夏纯杰,魏贤勇. 农作物秸秆解聚研究*[J]. 化学进展, 2007, 19(0708): 1134-1140.
[5] 孙君社,苏东海,刘莉. 秸秆生产乙醇预处理关键技术*[J]. 化学进展, 2007, 19(0708): 1122-1128.
[6] 陈洪章,邱卫华. 秸秆发酵燃料乙醇关键问题及其进展*[J]. 化学进展, 2007, 19(0708): 1116-1121.