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化学进展 2007, Vol. 19 Issue (11): 1710-1717 前一篇   后一篇

• 综述与评论 •

稳定的ZrO2基SOFC中CeO2夹层的制备方法和作用机制*

朱晓东 孙克宁** 周德瑞   

  1. (哈尔滨工业大学应用化学系 哈尔滨 150001）
  • 收稿日期:2006-12-28 修回日期:2007-01-27 出版日期:2007-11-14 发布日期:2007-11-25
  • 通讯作者: 孙克宁
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Preparation and Mechanism of CeO2 Interlayer in Stabilized ZrO2-Based SOFC

Zhu Xiaodong; Sun Kening** ;Zhou Derui   

  1. (Department of Applied Chemistry, Harbin Institute of technology, Harbin 150001, China)
  • Received:2006-12-28 Revised:2007-01-27 Online:2007-11-14 Published:2007-11-25
  • Contact: Sun Kening
Sm、Gd和Y掺杂的CeO2夹层是解决固体氧化物燃料电池的电极和电解质间物理化学性质不相容问题的最佳材料，已经展示出广泛的应用前景。本文介绍了CeO2粉体的各种合成方法以及对粉体性能的影响。综述了制备CeO2夹层薄膜的各种方法，其中包括直流反应磁控溅射（Reactively direct current magnetron sputtering）物理方法；火焰辅助气相沉积（Flame assisted vapor deposition，FAVD）和溶胶凝胶法（Sol-gel）等化学方法；电泳沉积法（Electrophoretic deposition, EPD）、丝网印刷法（Screen printing）和浸渍涂布法（dipping deposition）等陶瓷成型方法，评述了这些方法的优缺点，详细介绍了近年来采用上述方法制备的CeO2夹层薄膜的性能以及对电池性能的改进，论述了CeO2夹层提高电池性能的作用机制。综合分析了这些制备方法的异同和特点，指明了该领域的发展前景。阐述了开展CeO2夹层研究对我国SOFC发展的重大意义。
关键词： 固体氧化物燃料电池, 掺杂的CeO2夹层, 稳定的ZrO2
Sm, Gd and Y-doped CeO2 interlayers have shown great promise for resolving the chemical incompatibility and physical mismatch between the electrode and the electrolyte. In this paper, CeO2 powders synthesized by different methods and their corresponding performance were reported. Moreover, the preparing methods of CeO2 interlayer film and their properties were reviewed. These methods include physical ones like reactively direct current magnetron sputtering, chemical ones such as flame assisted vapor deposition and Sol-gel deposition, and ceramic processes containing electrophoretic deposition, Screen printing and dipping deposition. The improvements in the cell performance by introduction of these CeO2 interlayers and the related mechanism were discussed in detail, respectively. The sameness and differentness as well as advantage and disadvantage of these preparing methods of CeO2 interlayer film were elucidated synthetically. Also indicated in this paper was the significance of the study on CeO2 interlayers for the development of Chinese SOFCs.
Key words: solid oxide fuel cell(SOFC), doped CeO2 interlayer, stabilized ZrO2

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