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化学进展 2006, Vol. 18 Issue (06): 768-779 前一篇   后一篇

• 综述与评论 •

pH/温度响应的两亲性嵌段共聚物的研究*

赵群;倪沛红**   

  1. 苏州大学化学化工学院 江苏省有机合成重点实验室(苏州大学)   苏州 215123
  • 收稿日期:2005-06-01 修回日期:2005-11-01 出版日期:2006-06-24 发布日期:2006-06-24
  • 通讯作者: 倪沛红
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Recent Progress in pH/Temperature-Responsive Amphiphilic Block Copolymers

Qun Zhao;Peihong Ni**   

  1. School of Chemistry and Chemical Engineering, Soochow University, The Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou 215123, China
  • Received:2005-06-01 Revised:2005-11-01 Online:2006-06-24 Published:2006-06-24
  • Contact: Peihong Ni
刺激响应性两亲性嵌段共聚物由于具有多种潜在的用途而引起广泛关注。其中，pH和温度响应的嵌段共聚物被认为是较易获得并对外界环境刺激响应较敏感的一类聚合物。本文综述了利用各种可控/活性聚合方法制备不同结构刺激响应性的两亲性嵌段共聚物研究的最新进展，重点介绍聚（甲基）丙烯酸及其酯类与聚环氧乙烷(PEO)和聚环氧丙烷(PPO)类结构的两亲性嵌段共聚物的合成以及它们在水溶液中对pH值和温度变化的响应性。
关键词： pH/温度响应性, 两亲性嵌段共聚物, 活性聚合, 聚甲基丙烯酸酯类, 聚环氧乙烷, 聚环氧丙烷
The stimuli-responsive amphiphilic block copolymers have drawn much attention due to their various promising potential applications. The pH and temperature responsive block copolymers are considerably important because they are relatively convenient to be synthesized and sensitive to outer stimuli. This review focuses on recent progress in stimuli-responsive and amphiphilic block copolymers containing polymethacrylates, poly(ethylene oxide) (PEO), and poly(propylene oxide) (PPO)，which are prepared by various controlled/living polymerizations. The pH/temperatureresponsive properties of these copolymers in aqueous solution are also summarized.
Key words: pH/temperature-response, amphiphilic block copolymers, controlled /living polymerization, polymethacrylates, PEO, PPO

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