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化学进展 2003, Vol. 15 Issue (02): 151- 前一篇   

• 综述与评论 •

多元多金属含氧簇合物在催化化学中的应用*

单永奎**;戴立益;余淑媛;叶生荣;何鸣元**   

  1. （华东师范大学离子液体化学研究中心 上海 200062）
  • 收稿日期:2001-11-01 修回日期:2002-10-01 出版日期:2003-03-24 发布日期:2003-03-24
  • 通讯作者: 单永奎;何鸣元
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Catalysis of Multicomponent Polyoxometalate Clusters*

Shan Yongkui**;Dai Liyi;Yu Shuyuan;Ye Shengrong;He Mingyuan**   

  1. (Center for the Chemistry of Ionic Liquids,East China Normal University, Shanghai 200062, China)
  • Received:2001-11-01 Revised:2002-10-01 Online:2003-03-24 Published:2003-03-24
  • Contact: Shan Yong kuI;He Mingyuan
多金属含氧簇合物在催化化学中的重要性与日俱增，在原子经济反应和环境友好催化方面有着诱人的实用前景。这类物种的催化活性、理化性质、分子结构和固态体相结构以及制备方法均能在分子水平上给出详细信息，因而被视为混合金属氧化物催化剂的分子设计材料。本文拟对能够直观反映出这种信息的多元多金属含氧簇合物催化的研究作一评述。
关键词： 催化作用, 多金属含氧簇合物
Catalysis by polyoxometalate clusters is a field of increasing importance. Polyoxometalate clusters have several advantages as catalysts which make them economically and environmentally attractive, and provide a good basis for the molecular design of mixed oxide catalysts. The relationship among the following four levels of information can be established on the molecular basis: catalysis performance; chemical and physical properties; molecular and bulk composition and structure; and method of synthesis of catalysts. The review focuses on catalysts of the multicomponent polyoxometalate clusters to represent information mentioned above.
Key words: atalysis, polyoxometalate clusters

中图分类号: 

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[ 1 ] Muller A , Peters F, Pope M T, Gatteschi D. Chem.Rev. , 1998, 98: 239—271
[ 2 ] Pope M T, Muller A. Angew. Chem. Int. Ed. Engl. ,1991, 30: 34—38
[ 3 ] Rhule J T, Hill C L , Judd D A. Chem. Rev. , 1998, 98:327—357
[ 4 ] Katsoulis D E. Chem. Rev. , 1998, 98: 359—387
[ 5 ] Kozhevnikov IV. Chem. Rev. , 1998, 98: 171—198
[ 6 ] Mizuno N , Misono M. Chem. Rev. , 1998, 98: 199—217
[ 7 ] Misono M. Applied Catalysis, 1990, 64: 1—30
[ 8 ] Noiiri M , Misono M. Applied Catalysis A: General,1993, 93: 103—122
[ 9 ] 闵恩泽(Min E Z). 石油与天然气化工(Chem. Eng. Oil Nat. Gas) , 2000, 29 (5) : 215—220
[ 10 ] Mizuno N , Misono M. J. Molecular Catalysis, 1994, 86:319—342
[ 11 ] 单永奎(Shan Y K) , 戴立益(Dai L Y) , 余淑媛(Yu S Y) , 叶生荣(Ye S R ) , 何鸣元(He M Y). 化学通报(Chem. Bull. ) , 2002, (1) : 1—12
[ 12 ] Centi G, Lopez J , Nieto, et al. App l. Catal. , 1989, 46:197—212
[ 13 ] Showa D K K. J P 59 19 545, 10
[ 14 ] Davis M E, Dillon C J , Holles J H, Labinger J. Angew.Chem. Int. Ed. , 2002, 41: 858—860
[ 15 ] Cavani F, Mezzogori R, Pigamo A , Trifiro F, Etienne E.Catal. Today, 2001, 71: 97—110
[ 16 ] Jiang H S, Mao X, Xie S J , Zhong B K. J. Mol. Catal.A: Chem. , 2001, 3433: 1—7
[ 17 ] Min J S, Mizuno N. Catal. Today, 2001, 71: 89—96
[ 18 ] Okuhara T, Mizuno N , Misono M. Appl. Catal. A: General, 2001, 222: 63—77
[ 19 ] Seki Y, Mizuno N , Misono M. Appl. Catal. A: Gen. ,1997, 158: 147—151
[ 20 ] Seki Y, Mizuno N , Misono M. Appl. Catal. A: Gen. ,2000, 194: 13—20
[ 21 ] Seki Y, Min J S, Misono M , Mizuno N. J. Phys. Chem.B, 2000, 104: 5940—5946
[ 22 ] Nizova G V , Suss-Fink G, Shul′pin G B. J. Mol. Catal.A. Chem. , 1998, 130: 163—170
[ 23 ] Nizova G V , Suss-Fink G, Shul′pin G B. Tatrahedron,1997, 53: 3603—3614
[ 24 ] Nizova G V , Suss-Fink G, Shul′pin G B. Chem. Commun. , 1997, 397—398
[ 25 ] Kao L C, Huston A C, Sen A. J. Am. Chem. Soc. ,1991, 113: 700—701
[ 26 ] Khenkin A M , Rosenberger A , Neumann R. J. Catal. ,1999, 182: 82—91
[ 27 ] Muller-Erluein E M , Hofmann H. Chem. Eng. Sci. ,1988, 43 (8) : 2245—2250
[ 28 ] Neumann R, LisselM. J. Org. Chem. , 1989, 54: 4607—4610
[ 29 ] Neumann R, deMauricio L. J. Molecular Catalysis, 1993,84: 93—96
[ 30 ] Nomiya K, Hashino K, Nemoto Y, Watanabe M. J. Mol.Catal. A: Chem. , 2001, 176: 79—86
[ 31 ] Khenkin A M , Weiner L , Wang Y, Neumann R. J. Am.Chem. Soc. , 2001, 123 (35) : 8531—8542
[ 32 ] Odyakov V F, Zhizhina E G, Matveev K I. J. Mol. Catal.A: Chem. , 2000, 158: 453—456
[ 33 ] Masatoshi H, Kouichi N , Yutaka N , et al. J. Org.Chem. , 1993, 58: 6421—6425
[ 34 ] Matsuda F, Inoe K, Kato K. JP 06 72 920, 1994
[ 35 ] William B S, Anthony H, Marie K A , et al. WO 92 14 691, 1992
[ 36 ] Nomiya K, Yanagibayashi H, Nozaki C, et al. J. Mol.Catal. A , 1996, 114: 181—186
[ 37 ] Kuznetsova L I, Detusheva L G, Fedotox M A , et al. J.Mol. Catal. A , 1996, 111: 81—85
[ 38 ] Nomiya K, Nemoto Y, Hasegawa T, Matsuoka S. J.Mol. Catal. A: Chem. , 2000, 152, 55—68
[ 39 ] Neumann R, Khenkin A M , Vigdergauz I. Chem. Eur.J. , 2000, 6: 875—882
[ 40 ] Kholdeeva O A , Golovin A V , Kozhevnikov I V. React.Kinet. Catal. Lett. , 1992, 46 (1) : 107—112
[ 41 ] Kholdeeva O A , Golovin A V , Maksimovskaya R I, et al.J. Mol. Catal. , 1992, 75: 235—239
[ 42 ] Manfred L , Helmut J. Tetrahedron Letters, 1992, 33(13) : 1795—1798
[ 43 ] Kouichi N , Masatoshi H, Yutaka N , et al. Chem. Letters, 1993, 1699—1702
[ 44 ] Langerbeins K. DE 3 626 256, 1988
[ 45 ] Kusnetsova L I, Chernyshova Yu V , Maksimovskaya R I.Inorg. Chim. Acta, 1990, 167: 223—231
[ 46 ] Gerhard E, Krueger B, Frank K, et al. EP 606 056, 1994
[ 47 ] Titova T F, Matvecv K I, Zhizhina E G, et al. Zh. Org.Khim. , 1991, 27 (6) : 1321—1331
[ 48 ] Ziumi Y. JP 04 89 465, 1992
[ 49 ] 吴通好(Wu T H) , 杨洪茂(Yang H M ) , 王国甲(Wang G J ). 高等学校化学学报(Chemical Journal of Chinese Universities) , 1985, 6 (11) : 1025—1027
[ 50 ] Masagutov R M , Churkin Y V , Maksinov S M , et al.U SSR 722 895, 1980
[ 51 ] Romy N , Igal A. J. Chem. Soc. , Chem. Commun. ,1988, 19: 1285—1287
[ 52 ] Delling U H. U S 4 237 315, 1980
[ 53 ] Kummer J T, Oei D G. U S 4 396 647, 1993
[ 54 ] Xu L , Boring E, Hill C L. J. Catal. , 2000, 195: 394—405
[ 55 ] Evtuguin D V , Neto C P. ACS Symp. Ser. , 785 (Oxidative Delignification Chemistry) 2001, 327—341
[ 56 ] Orzta H, Takashi H, Masao S, et al. Appl. Catal. , 1991,77: 133—140
[ 57 ] Hiroshi F, TeijiN , Hiroyuki I, et al. Chemistry Letters,1988, 877—880
[ 58 ] Kwan-Young L , Koshi I, Masato H, et al. Stud. Surf.Sci. Catal. (New Developments in Selective Oxidationê ) ,1994, 583—590
[ 59 ] Akio F, Yu F, Masanobu Z, et al. JP 04 35 716, 1992
[ 60 ] Kuniakij M , Toshiro S, Kenicli S. JP 05 301 842, 1993
[ 61 ] Griffith W P. Transition Met. Chem. , 1991, 16: 548—552
[ 62 ] Kozhevnikov L V. Kinet Katal. , 1980, 21 (4) : 947—953
[ 63 ] Hill G L , Brown R B. J. Am. Chem. Soc. , 1986, 108:536—538
[ 64 ] Traylor P S, Dolphin D H, Traylor T G. J. Chem. Soc. ,Chem. Commun. , 1984, 279— 280
[ 65 ] Neumann R, Avu-Gnim C. J. Chem. Soc. , Chem. Commun. , 1989, 18: 1324—1325
[ 66 ] Faraj M , Hill C L. J. Chem. Soc. , Chem. Commun. ,1987, 1487—1489
[ 67 ] Bressan M. J. Molecular Catalysis, 1992, 77: 283—288
[ 68 ] Mizuno N , Nozaki C, Hirose T, Tateishi M. J. Mol.Catal. A , 1997, 117: 159—164
[ 69 ] Kuznetsova L I, Kuznetsova N I, Detusheva M A , et al.J. Mol. Catal. A: Chem. , 2000, 158: 429—433
[ 70 ] Mizuno N , Misono M , Nishiyama Y, Siki Y, Kiyoto I,Nozaki C. Res. Chem. Intermed. , 2000, 26: 193—199
[ 71 ] Ellis S, Kozhevnikov I V. J. Mol. Catal. A: Chem. ,2002, 187: 227—235
[ 72 ] Neumann R. J. Am. Chem. Soc. , 1990, 112: 6025—6031
[ 73 ] Mizuno N , Hirose T, Iwamoto M. Stud. Surf. Sci. Catal.( New Developments in Selective Oxidation ê ) , 1994,593—600
[ 74 ] Kuznetsova N I, Detusheva L G, Kuznetsova L I, et al.Kinet. Katal. , 1992, 33 (3) : 516—523
[ 75 ] Johnson B J S, Stein A. Inorg. Chem. , 2001, 40: 801—808
[ 76 ] Katsoulis D E, Pope M T. J. Chem. Soc. , Dalton.T rans. , 1989, 8: 1483—1489
[ 77 ] Gheorghe M , Trina P, Traian B, et al. Rom 100 477, 1990
[ 78 ] Khenkin A M , Shimon L J W , Neumann R. European J.Inorg. Chem. , 2001, 789—794
[ 79 ] Adam W , Herod M , Hill C L , Saha-Moller C R. European J. Org. Chem. , 2002, 941—946
[ 80 ] Kuznetsova L I, Yurchenko E N. React. Kinet. Catal.Lett. , 1989, 39 (2) : 399—404
[ 81 ] Kuznetsova L I, Fedotov M A , Yurchenko E N. React.Kinet. Catal. Lett. , 1990, 41 (2) : 333—336
[ 82 ] Bart C J. Electrochem. Soc. Interface, 1994, 3 (3) : 15—22
[ 83 ] 吴志芸(Wu Z Y) , 赵仲清(Zhao Z Q ) , 李凯(Li K ) , 张强(Zhang Q ). 高等学校化学学报(Chemical Journal of Chinese Universities) , 1985, 6 (5) : 459—464
[ 84 ] Harrup M K, Hill C L. Inorg. Chem. , 1994, 33: 5448—5445
[ 85 ] Harrup M K, Hill C L. J. Mol. Catal. A , 1996, 106:57—62
[ 86 ] Neumann R, Dahan M. J. Am. Chem. Soc. , 1998, 120:11969—11976
[ 87 ] 刘建允(Liu J Y) , 刘佰峰(Liu B F) , 董绍俊(Dong S J ).分析化学(Chinese Journal of Analytical Chemistry ) ,2002, 30: 129—133
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