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化学进展 1998, Vol. 10 Issue (02): 146- 前一篇   后一篇

• 综述与评论 •

水溶性均相络合催化研究进展*

陈华;黎耀忠; 李东文;程溥明;李贤均**   

  1. 四川大学化学系 成都 610064
  • 收稿日期:1900-01-01 修回日期:1900-01-01 出版日期:1998-06-24 发布日期:1998-06-24
  • 通讯作者: 李贤均
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Advances of Aqueous Biphasic Catalysis by Wa ter-Soluble Phosphine Transition-Metal Complexes

Chen Hua;Li Yaozhong;Li Dongwen;Cheng Puming;Li Xianjun   

  1. Department of Chemistry, Sichuan University, Chengdu 610064, China
  • Received:1900-01-01 Revised:1900-01-01 Online:1998-06-24 Published:1998-06-24
  • Contact: Li Xianjun

本文评述了水溶性膦配体的合成及以水溶性过渡金属膦络合物为催化剂的两相催化体系的研究和开发概况, 着重介绍了两相体系在烯烃氢甲酰化、不饱和化合物的加氢及催化不对称合成中的应用, 并对两相催化体系研究中存在的问题进行了探讨。

关键词： 两相催化, 水溶性膦配体, 氢甲酰化, 加氢, 不对称合成

This paper describes the advances in the syntheses of water soluble phosphines and aqueous biphasic catalysis by water soluble phosphine transition metal complexes, especially in the hydroformylation of olefins and the hydrogenation of A, B2unsaturated carbonyl compounds, and also in the asymmetric catalytic synthesis. The problems to be overcome in the applications of aqueous biphasic catalysis are discussed.

Key words: biphasic catalysis, water soluble phosphines, hydroformylation, hydrogenation, asymmetric synthesis

中图分类号: 

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摘要

水溶性均相络合催化研究进展*