English
往期目录
新闻公告
More
化学进展 1999, Vol. 11 Issue (01): 11- 前一篇   后一篇

• 综述与评论 •

介孔硅基分子筛研究新进展

张兆荣;索继栓;张小明;李树本*   

  1. 中国科学院兰州化学物理研究所汤剂合成与选择氧化国家重点实验室 兰州 730000
  • 收稿日期:1998-02-01 修回日期:1998-04-01 出版日期:1999-02-24 发布日期:1999-02-24
  • 通讯作者: 李树本
下载PDF ( 1949 ) 引用
导出 被引次数 ( 147 | 13 )

New Vistas for Silica-Based Mesoporous Molecular Sieves

Zhang Zhaorong;Suo Jishuan;Zhang Xiaoming;Li Shuben*   

  1. State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
  • Received:1998-02-01 Revised:1998-04-01 Online:1999-02-24 Published:1999-02-24
  • Contact: Li Shuben

M41S、HMS、MSU 和SBA 等具有规则孔道结构的介孔硅基分子筛及其杂原子衍生物在多相催化、吸附分离及材料科学领域有重要的学术研究与工程应用价值。此类物质可以通过长链季铵盐、伯胺、双子胺或聚氧乙烯类表面活性剂胶束的模板作用, 在多种不同的条件下合成, 并可通过SEM、TEM、XRD、N2 (A r) 等温吸附-脱附技术和FT-IR、激光Ram an、固体MA S NMR、UV-V is 漫反射、XPS、EXA FS、XAN ES 等谱学手段加以表征。本文对介孔硅基分子筛近年来所取得的进展进行了综述。

The M41S, HMS, MSU , and SBA silica2based crystalline mesoporous molecular sieves are of great academic and practical importance in catalysis, absorptive separation technology, and materials science. Such materials may be prepared by involving the micellae of longchain quaternary ammoniumion, primary amine, geminal amine, or polyethylene oxide surfactants as templating species, and characterized by SEM , TEM ,XRD, N2 (Ar) adsorption desorption techniques, FT-IR,laser Raman, solid state MASNMR, UV-V is diffuse reflectance, XPS, EXA FS, and XAN ES spectroscopy. In this review , progress made in these aspects are summarized.

Key words: silica-based mesoporous molecular sieve, synthesis, characterization,catalytic performance

中图分类号: 

()

[1 ] IUPAC Manual of Symbols and Terminology, Pure Appl. Chem. , 1972, 31, 578.
[2 ] Kresge C T , Leonowicz M E, Roth W J et al. , Nature, 1992, 359, 710.
[3 ] Beck J S, Vartuli J C, Roth W J et al. , J. Am. Chem. Soc. , 1992, 114, 10834.
[4 ] Beck J S, Vartuli J C, Current Opinionin Solid State and Mater. Sci. , 1996, 1, 76.
[5 ] Casci J L , Stud. Surf . Sci. Catal. , 1994, 85, 329.
[6 ] Sayari A , Chem. Mater. , 1996, 8, 1840.
[7 ] Coma A , Chem. Rev. , 1997, 97, 2373.
[8 ] Yang H, Kuperman A , Coombs N et al. , Nature, 1996, 379, 703.
[9 ] Feng X, Fryxell F, Wang L Q et al. , Science, 1997, 276, 923.
[10 ] Tanev P T , Pinnavaia T J , Science, 1995, 267, 865.
[11 ] Tanev P T , Chibwe M , Pinnavaia T J , Nature, 1994, 368, 321.
[12 ] Bagshaw S A , Pinnavaia T J , Science, 1995, 268, 1242.
[13 ] Attard G S, Glyde J C, Goltner C G, Nature, 1995, 378, 366.
[14 ] Huo Q S, Margolese D I, Ciesla U et al. , Nature, 1994, 378, 317.
[15 ] Huo Q S, Margolese D I, Ciesla U et al. , Chem. Mater. , 1994, 6, 1176.
[16 ] Huo Q S, Leon R, Petroff P M et al. , Science, 1995, 268, 1324.
[17 ] Monnier A , Schuth F, Huo Q S et al. , Science, 1993, 261, 1299.
[18 ] Whittingham M S, Current Opinionin Solid State &Mater. Sci. , 1996, 1, 227.
[19 ] Ulagapan N , Neeraj, Raju B V N et al. , Chem. Commun. , 1996, 2243.
[20 ] Doi T , Miyake T , Chem. Commun. , 1996, 1635.
[21 ] SayariA , Moudrakovski I, Reddy J S et al. , Chem. Mater. , 1996, 8, 2080.
[22 ] SayariA , Karra V R, Reddy J S et al. , Chem. Commun. , 1996, 411.
[23 ] Yanagisawa T , Shimizu T , Kiroda K et al. , Bull. Chem. Soc. Jpn. , 1990, 63, 988.
[24 ] Inagaki S, Fukushima Y, Kiroda K, Chem. Commun. , 1993, 680.
[25 ] Vartuli J C, Schmitt K D, Kresge C T et al. , Chem. Mater. , 1994, 6, 2317.
[26 ] Cheng C F, Luan Z H, Klinowski J , Langmuir, 1995, 11, 2815.
[27 ] Firouzi A , Kumar D, Bull L M et al. , Science, 1995, 267, 1138.
[28 ] Huo Q S, Margolese D I, Stucky G D, Chem. Mater. , 1996, 8, 1147.
[29 ] 张兆荣(Zhang Z R) , 索继栓(Suo J S) , 张小明(Zhang X M ) 等, 物理化学学报(Acta Physico-Chimica Sinica) , 1998, 14, 243.
[30 ] Chen C Y, Burkett S L , Li H X et al. , Microporous Mater. , 1993, 2, 27.
[31 ] Sayari A , Danumah C, Moudrakovski I L , Chem. Mater. , 1995, 7, 813.
[32 ] SayariA , Moudrakovski I L , Danumah C et al. , J. Phy. Chem. , 1995, 99, 16373.
[33 ] On D T , Joshi P N , Kaliaguine S, J. Phy. Chem. , 1996, 100, 6743.
[34 ] Luan Z H, Cheng C F, Zhou W Z et al. , J. Phy. Chem. , 1995, 99, 108.
[35 ] Fyfe C A , Fu G Y, J. Am. Chem. Soc. , 1995, 117, 9709.
[36 ] Cheng C F, He H Y, Zhou W Z et al. , J. Phy. Chem. , 1996, 100, 390.
[37 ] Abeld-Fattah T T , Pinnavaia T J , Chem. Commun. , 1996, 665.
[38 ] Das T K, Chaudari K, Chandwadkar A J et al. , Chem. Commun. , 1995, 2495.
[39 ] Corma T , Navarro M T , Perez-Pariente J , Chem. Commun. , 1994, 147.
[40 ] Koyano K A , Tatsumi T , Chem. Commun. , 1996, 145.
[41 ] Zhang W Z, Wang J L , Tanev P T et al. , Chem. Commun. , 1996, 979.
[42 ] Blasco T , Corma A , Navarro M T et al. , J. Catal. , 1995, 156, 65.
[43 ] TuelA , Gontier S, Teissier R, Chem. Commun. , 1996, 651.
[44 ] Gontier S, TuelA , Appl. Catal. , 1996, 143, 125.
[45 ] Chenite A , Le Page Y, Sayari A , Chem. Mater. , 1995, 7, 1015.
[46 ] Reddy K M , Moudrakovski I L , SayariA , Chem. Commun. , 1994, 1059.
[47 ] Zhang Z R, Suo J S, Zhang X M et al. , Chem. Commun. , 1998, 241.
[48 ] Zhao D Y, Goldfarb D, Stud. Surf . Sci. Catal. , 1995, 97, 181.
[49 ] Zhao D Y, Goldfarb D, Chem. Commun. , 1995, 875.
[50 ] Tian Z R, Tong W , Wang J Y et al. , Science, 1997, 276, 926.
[51 ] Yuan Z Y, Liu S Q , Chen T H et al. , Chem. Commun. , 1995, 973.
[52 ] Echchahed B, Moen A , Nicholson D et al. , Chem. Mater. , 1997, 9, 976.
[53 ] Hartmann M , Poppl A , Kevan L , J. Phy. Chem. , 1996, 100, 9906.
[54 ] Poppl A , Hartmann M , Kevan L , J. Phy. Chem. , 1995, 99, 17251.
[55 ] Maschmeyer T , Rey F, Sanker G et al. , Nature, 1995, 378, 159.
[56 ] Kozhevonikov I V , Sinnema A , Jansen R J J et al. , Catal. Lett. , 1995, 30, 241.
[57 ] O ’Brien S, Francis R J , Price S J et al. , Chem. Commun. , 1995, 2423.
[58 ] Matijasic A , Voegtlin A C, Patarin J et al. , Chem. Commun. , 1996, 1123.
[59 ] Horvath G, Kawazoe K J , J. Chem. Eng. Jpn. , 1983, 16, 470.
[60 ] Schmidt R, Hansen E W , Stocker M et al. , J. Am. Chem. Soc. , 1995, 117, 4049.
[61 ] Perego G, Bellussi G, Corno C et al. , Stud. Surf . Sci. Catal. , 1986, 28, 129.
[62 ] Bellussi G, Rigutto M S, Stud. Surf . Sci. Catal. 1994, 85, 177.
[63 ] Reddy J S, Sayari A , Chem. Commun. , 1995, 23.
[64 ] Corma A , Camblor M A , Esteve P et al. , J. Catal. , 1994, 145, 151.
[65 ] Reddy K M , Kaliaguine S, Sayari A et al. , Catal. Lett. , 1994, 23, 169.
[66 ] Reddy K M , Kaliaguine S, Sayari A et al. , Catal. Lett. , 1994, 23, 175.
[67 ] Sayari A , Karra V R, Reddy J S et al. , Mater. Res. Soc. S ymp. Proc. , 1995, 371, 53.
[68 ] Sanker G, Rey F, Thomas J M et al. , Chem. Commun. , 1994, 2279.
[69 ] Graselli J G Bulkin B J , Analytical Raman Spectroscopy , Wiley, New York, 1991, 352.
[70 ] Corma A , Martinez A , Martinez-Soria V et al. , J. Catal. , 1995, 153, 25.
[71 ] Roos K, Liepold A , Roschetilowski W et al. , Stud. Surf . Sci. Catal. , 1994, 84, 389.
[72 ] Aufdembrink, B A , Chester A W , Hersbst J A et al. , US Patent 5 258 114, 1993.
[73 ] Appelian M R , Degnan T F Jr et al. , US Patent 5 264 116, 1993.
[74 ] Kresge C T , Leonowicz M E, Roth. W J , US Patent 5 183 561, 1993.
[75 ] Le Q N , Thomson R T , Yokomizo G H, US Patent 5 134 241, 1992; 5 134 242, 1992.
[76 ] Bhore N A , Le Q N Yokomizo G H, US Patent 5 134 243, 1993.
[77 ] Kresge C T , Leonowicz M E , Roth W J et al. , US Patent 5 174 888, 1992; 5 196 633, 1993.
[78 ] Le Q N , U S Patent 5 191 134, 1993; 5 118 894, 1992.
[79 ] Armengol A , Cano M L , Corma A et al. , Chem. Commun. , 1995, 519.
[80 ] Kloestra K R, Van Bekkum H J , J. Chem. Res. (S ) , 1995, 26.
[81 ] Kloestra K R, Van Bekkum H J , Chem. Commun. , 1995, 1005.
[82 ] Kresge C T , Marler D O , Rav J Setal, US Patent, 5 366 945, 1994.
[83 ] Martens J A , Buskens P, Jacobs P A , Appl. Catal. , 1993, 99, 71.
[84 ] Reddy J S, Sayari A , Chem. Commun. , 1995, 2231.
No related articles found!
阅读次数
全文


摘要

介孔硅基分子筛研究新进展