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化学进展 2022, Vol. 34 Issue (5): 1011-1012 DOI: 10.7536/PC220435   后一篇

所属专题： 中国化学印记

• 中国化学印记 •

富勒烯“电子缓冲”机制与催化

王春儒1, 李亚栋2,*()   

  1. 1.中国科学院化学研究所 北京100190
    2.清华大学化学系 北京 100084
  • 出版日期:2022-05-24 发布日期:2022-06-24
  • 通讯作者: 李亚栋
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“Electron Buffering” Effect of Fullerene in Catalysis

Chunru Wang1, Yadong Li2()   

  1. 1. Institute of Chemistry Chinese Academy of Science, Beijing 100190, China
    2. College of Chemistry, Tsinghua University, Beijing 100084, China
  • Online:2022-05-24 Published:2022-06-24
  • Contact: Yadong Li

Ethylene glycol was synthesized from dimethyl oxalate hydrogenation at ambient pressure over fullerene modified copper catalyst. Fullerenes show electron buffering effect to stabilize cuprous species and boost the copper catalysis. This finding provides a novel strategy for the design of stable catalysts using fullerenes as a molecular promoter.

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摘要

富勒烯“电子缓冲”机制与催化