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化学进展 2019, Vol. 31 Issue (12): 1637-1652 DOI: 10.7536/PC1904105 前一篇   后一篇

• •

质子交换膜燃料电池膜电极耐久性的提升

叶跃坤, 池滨, 江世杰, 廖世军**()   

  1. 华南理工大学化学与化工学院 广州 510641
  • 收稿日期:2019-01-07 出版日期:2019-12-15 发布日期:2019-10-15
  • 通讯作者: 廖世军
  • 基金资助:
    国家重点研发计划项目(2017YFB0102900); 国家重点研发计划项目(2016YFB0101201); 国家自然科学基金项目(21476088); 国家自然科学基金项目(21776105); 广东省自然科学基金项目(2015B010106012); 广州市科技创新委员会(201504281614372); 广州市科技创新委员会(2016GJ006)
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Enhancing the Durability of Membrane Electrode Assembly of Proton Exchange Membrane Fuel Cells

Yuekun Ye, Bin Chi, Shijie Jiang, Shijun Liao**()   

  1. School of Chemistry and Engineering, South China University of Technology, Guangzhou 510641, China
  • Received:2019-01-07 Online:2019-12-15 Published:2019-10-15
  • Contact: Shijun Liao
  • About author:
    ** E-mail:
  • Supported by:
    National Key Research and Development Program of China(2017YFB0102900); National Key Research and Development Program of China(2016YFB0101201); National Natural Science Foundation of China(21476088); National Natural Science Foundation of China(21776105); Guangdong Provincial Department of Science and Technology(2015B010106012); Guangzhou Science Technology and Innovation Committee(201504281614372); Guangzhou Science Technology and Innovation Committee(2016GJ006)

质子交换膜燃料电池由于具有能量转换效率高、操作温度低、环境友好等优点而备受人们关注。随着2014年丰田发布燃料电池电动汽车Mirai,带来了新一轮燃料电池及燃料电池汽车的产业化热潮。然而,提升质子交换膜燃料电池的寿命,开发新一代长寿命燃料电池膜电极及燃料电池仍然是本领域的挑战性课题。膜电极(MEA)是质子交换膜燃料电池最核心的部件,其耐久性直接决定着燃料电池的寿命。MEA主要由质子交换膜、催化剂层、气体扩散层三部分组成。本文从质子交换膜、催化剂及载体、气体扩散层三个方面介绍了近年来国内外在提升燃料电池膜电极的寿命(耐久性)方面所做的工作,并对未来的相关研究和发展做了述评及展望。

关键词： 质子交换膜燃料电池, 膜电极, 耐久性, 老化机理, 缓解策略

Proton exchange membrane fuel cell(PEMFC) has attracted huge attention recently due to its high energy conversion efficiency, low operating temperature and environmental benign. With the launch of the Mirai fuel cell electric vehicle by Toyota in 2014, a new wave of industrialization of fuel cells and fuel cell vehicles has been brought about. However, enhancing the durability of PEMFC and developing a new generation of membrane electrode assembly(MEA) and fuel cells are still challenging topics in the field. The MEA is the core component of PEMFC, and its durability directly determines the life of the fuel cell. The MEA is mainly composed of a proton exchange membrane, anode and cathode catalyst layers and gas diffusion layers on both sides. In last decade, great efforts have been paid to improving the durability of MEAs/PEMFCs from three aspects, membrane, catalyst layer and gas diffusion layer. In this paper, we introduce these research works systematically, and a review and prospect for the research and development of this topic in the future is also made.

Key words: proton exchange membrane fuel cell, membrane electrode assembly, durability, degradation mechanism, mitigation strategy
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图1 自由基攻击Nafion离聚物结构机理汇总[7]
Fig. 1 Summary of the mechanisms of radical attack on the Nafion polymer structure[7]
图2 负载在碳载体上的铂颗粒老化机制[57]
Fig. 2 Degradation mechanisms for platinum particles on a carbon support in fuel cells[57]
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