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张赛晖, 王悦, 柳开鹏, 王捷. 聚电解质型正渗透汲取液[J]. 化学进展, 2019, 31(7): 969-979.
Saihui Zhan, Yue Wang, Kaipeng Liu, Jie Wang. Polyelectrolyte-Based Draw Solution in Forward Osmosis[J]. Progress in Chemistry, 2019, 31(7): 969-979.
聚电解质作为正渗透汲取液具有渗透压高、溶质反向渗透、易于回收等特点,符合理想正渗透汲取液的要求。此外,多种分离方法诸如纳滤、超滤和热处理可用于其回收,使得聚电解质型汲取液成为诸如氯化钠等的传统无机汲取液的理想代替物。近年来关于聚电解质型汲取液的研究日益增加,而聚电解质型汲取液较无机型汲取液有许多独特的性质,应对相关研究进展予以总结。本文以聚电解质的化学结构分类对其研究进展进行了概述。重点总结了不同种类聚电解质的分子量、渗透压、黏度等性质,以及正渗透过程的水通量及溶质反向渗透情况,同时还介绍了相应的正渗透机理。最后,探讨和总结了各类汲取液的特点,并展望了未来的研究方向。
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Category of the polyelectrolytes | Polyelectrolyte(Mw-Da) | Concentration(g/mL) | Osmotic pressure or Osmolality (bar or mOsmol/kg) | Viscosity(cP) | Waterflux(LMH) | Reverse solute flux(gMH) | Advantages | Drawbacks | ref |
---|---|---|---|---|---|---|---|---|---|
Carboxylate type | PAA-Na(1800) | 0.72 | ~54 bar | 127 | ~19 | ~1.2 | Commercial available | High viscosity | 34 |
PAspNa(1313) | 0.30 | 2150 mOsmol/kg | 4.4 | 31.8 | - | Non-toxic; | - | 44 | |
PESA(400~1500) | 0.20 | 1250 mOsmol/kg | ~2.2 | 15.4 | 3.19 | Degradable | - | 48 | |
PIAM-Na(5919) | 0.375 | ~2000 mOsmol/kg | ~32 | 34 | - | Low leakage | High viscosity | 49 | |
PMAS(559) | ~0.28 | 143 bar | ~10 | 30.6 | ~0.9 | High osmotic pressure | High viscosity | 50 | |
P(IA-co-AA) (533) | ~0.267 | ~57 bar | ~30 | 27 | 0.68 | Low leakage | - | 50 | |
PAMAM-COONa(~2806) | 0.333 | 3603 mOsmol/kg | 9.16 | 29.7 | 7.5 | Low leakage | High reverse solute flux | 51 | |
Sulfonate type | PSS(70 000) | 0.24 | - | ~19 | 18.2 | ~5.5 | High water flux | High reverse solute flux | 52 |
PSSP(4700) | 0.20 | ~15 bar | 12.62 | 14.50 | 0.14 | Thermo-sensitive | - | 54 | |
PBET(18 000) | 0.20 | 898 mOsmol/kg | 17.69 | 3.22 | 0.36 | Thermo-sensitive | Low water flux | 58 | |
PSS-co-MA-Na-1(20 000) | 0.25 | 32.8±0.89 bar | 5.89 | 15 | 0.04 | Low leakage | 59 | ||
PSS-co-AA (96 308) | 0.18 | ~23 bar | 5.4 | 11.77 | 0.1 | Low leakage | 60 | ||
Amine type | PEI(800) | 0.05 | 125.7 mOsmol/kg | 0.62 | ~1.2 | 0.01 | Low leakage | Low osmotic presure at high pH value | 66 |
PEI(1200) | 0.05 | 88.3 mOsmol/kg | 0.75 | ~0.75 | 0.05 | 66 | |||
PEI(25 000) | 0.10 | ~7 bar | 1.93 | 24 | 0.7~1.0 | 67 | |||
TTHP-4Na (666.21) | 0.50 | ~165 bar | ~7 | 23.07 | 0.75 | High osmotic pressure | - | 68 | |
TPHMP-Na | 0.05 | ~105 bar | ~17 | 54 | 0.83 | High water flux | High viscosity | 71 | |
ETAC-starch | 0.3 | 11.91 bar | 118.0 | 4.1 | 1.62 | Low reverse flux | Low water flux | 72 | |
Amide type | PAM(3 000 000) | 0.30 | 544 mOsmol/kg | 244.7 | ~5 | 1.5 | Stable water flux | High viscosity | 73 |
4%PNIPAM-SA | 0.40 | ~2 bar | - | 0.347 | - | Thermo-sensitive | Low water flux | 83 | |
PNSA-10(3530) | 0.38 | 7.2 bar | 59.8 | 2.95 | - | Thermo-sensitive | High viscosity | 85 | |
PSSS-PNIPAM (3500) | 0.333 | 2137 mOsmol/kg | 68 | 4.0 | 2 | Thermo-sensitive | High viscosity | 86 |
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