化学进展 2019, Vol. 31 Issue (1): 121-134 DOI: 10.7536/PC180444 前一篇   后一篇

• 综述 •


李亚雯, 敖宛彤, 金慧琳, 曹利平**()   

  1. 西北大学化学与材料科学学院 合成与天然功能分子化学教育部重点实验室 西安 710127
  • 收稿日期:2018-04-26 修回日期:2018-06-30 出版日期:2019-01-15 发布日期:2018-12-07
  • 通讯作者: 曹利平
  • 基金资助:
    国家自然科学基金项目(21771145); 国家自然科学基金项目(21472149); 陕西省一流专业项目和西北大学校级创新创业训练计划项目资助(2018194)

Aggregation-Induced Emission of Tetraphenylethene Derivatives with Macrocycles via Host-Guest Interactions

Yawen Li, Wantong Ao, Huilin Jin, Liping Cao**()   

  1. Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi’an 710127, China
  • Received:2018-04-26 Revised:2018-06-30 Online:2019-01-15 Published:2018-12-07
  • Contact: Liping Cao
  • About author:
    ** Corresponding author e-mail:
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(21771145); The work was supported by the National Natural Science Foundation of China(21472149); The “Top-rated Discipline” Construction Scheme of Shaanxi Higher Education and the Innovation Training Program in Northwest University(2018194)


The compounds with aggregation-induced emission (AIE) property have been widely developed to solve aggregation-caused quenching (ACQ) problem of organic luminophores at high concentration, in the solid state, or in the form of thin film. Therefore, AIE compounds are useful for a number of applications, such as fluorescent probes and receptors, and cell imaging. Tetraphenylethene (TPE) and its derivatives, as typical compounds with AIE property, have been widely applied in materials chemistry, biochemistry, and other related fields. Inspired from AIE, TPE has been also introduced into the field of supramolecular chemistry by supramolecular chemists. Especially, given their ability to restrict the intramolecular rotation or motion of TPE molecules, macrocyclic hosts can form host-guest complexes or supramolecular polymers with TPE via host-guest interactions, which results in enhancement in the AIE effect of guests. Hence, AIE of TPE derivatives with macrocycles via host-guest interaction also provides a new approach to develop the applications in stimuli-responsive sensors and probes. This review mainly focuses on summarizing the research progress of host-guest complexes between macrocycles and TPE, and comments on the bright future of AIE behaviors of the supramolecular systems involving host-guest interactions.

Fig.1 The chemical structures of crown ether, calix[n]arene, cucurbit[n]uril and cyclodextrin
Fig.2 The chemical structures of new macrocycles
化合物1, 聚合物2
化合物3, 化合物4
19, 20
化合物24, 25
化合物32, 33
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