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化学进展 2018, Vol. 30 Issue (12): 1887-1898 DOI: 10.7536/PC180345 前一篇   后一篇

• 综述 •

低表面能化合物在超浸润材料中的应用

侯琳刚, 马利利, 周亦晨, 赵彧, 张毅, 何金梅*   

  1. 西安科技大学化学与化工学院 西安 710054
  • 收稿日期:2018-03-18 修回日期:2018-06-15 出版日期:2018-12-15 发布日期:2018-09-26
  • 通讯作者: 何金梅 E-mail:jinmhe@gmail.com
  • 基金资助:
    国家自然科学基金项目（No.21473132）资助
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Application of Low Surface Energy Compounds to the Superwetting Materials

Lingang Hou, Lili Ma, Yichen Zhou, Yu Zhao, Yi Zhang, Jinmei He*   

  1. College of Chemistry and Chemical Engineering, Xi'an University of Science and Technology, Xi'an 710054, China
  • Received:2018-03-18 Revised:2018-06-15 Online:2018-12-15 Published:2018-09-26
  • Supported by:
    The work was supported by the National Natural Science Foundation of China(No. 21473132).
近年来，由于超浸润材料在自清洁、微流体传输和生物相容性等方面的潜在应用，具有极端润湿性的超浸润材料成为了材料领域的一个研究热点。研究表明，除材料表面微纳米结构的构筑外，材料表面能的控制也是制备超浸润材料的另一关键因素。随着对超浸润材料润湿性机理研究的深入，许多不同结构不同类型的低表面能化合物也越来越多地被应用于超浸润材料的制备中。本文从分子结构、化合物类型等角度出发，综述了超浸润材料制备中所大量应用的低表面能化合物，并归纳了pH值、温度、浓度及溶剂等因素对材料低表面能化的影响，总结了低表面能化合物在提高机械强度、制备润湿性转换材料和不同浸润性修饰中的选择和应用情况，最后提出了低表面能化合物应用的一些不足之处并对其发展方向进行了展望。
关键词： 超浸润, 表面自由能, 低表面能化合物, 超疏水, 超双疏
Recently, the superwetting materials have become a new research hotspot due to their potential application in self-cleaning, microfluidics transmission, biocompatibility etc. In addition to the creating of rough micro-nanoscale structure, the control of surface energy of the materials is also a vital factor for fabricating the superwetting materials. With the deepening of research on the mechanism of the wettability of superwetting surface, more and more kinds of low surface energy compounds with different structures have been used to decrease the surface energy. Based on the molecular structures and compound types, this paper reviews the low surface energy compounds in fabricating the superwetting materials, concludes the effects of pH value, temperature, concentration and solvent on the low surface energy materials, and summarizes the selection and application of low surface energy compounds for improving the mechanical strength, and preparing materials of wettability transformation and different wettability modification. Finally, some existing problems are discussed and the future research directions in this field are proposed.
Contents
1 Introduction
2 Types of the low surface energy compounds
2.1 Silane coupling agent
2.2 Aluminate coupling agent
2.3 Saturated fatty compounds
2.4 Low surface energy polymers with 3D structure
2.5 Composite compounds with low surface energy
3 Factors affecting the low surface energy of materials
3.1 pH
3.2 Temperature
3.3 Concentration
3.4 Solvent
3.5 Other factors
4 Selection and application of low surface energy compounds
4.1 Mechanical strength
4.2 Wettability transformation
4.3 Different wettability
5 Existing problems
6 Conclusion and outlook
Key words: superwetting, surface free energy, low surface energy compounds, superhydrophobic, superamphiphobic

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