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化学进展 2018, Vol. 30 Issue (11): 1601-1614 DOI: 10.7536/PC180316 前一篇   后一篇

• 综述 •

Janus粒子的制备及功能化应用

周婉蓉, 孙巍*, 杨平辉   

  1. 1. 宁波大学材料化学与工程学院 材料科学与工程系;
    2. 宁波特种高分子材料制备与应用技术重点实验室 宁波 315211
  • 收稿日期:2018-03-13 修回日期:2018-06-04 出版日期:2018-11-15 发布日期:2018-09-10
  • 通讯作者: 孙巍,e-mail:sunwei@nbu.edu.cn E-mail:sunwei@nbu.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.21104036）、宁波市自然科学基金项目（No.2018A610113）、浙江省重点科技创新团队自设项目（No.211R50001-04）和宁波大学王宽诚幸福基金资助
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Preparation and Functional Application of Janus Particles

Wanrong Zhou, Wei Sun*, Pinghui Yang   

  1. 1. Department of Materials Science and Engineering, School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China;
    2. Key Laboratory of Specialty Polymer, School of Material Science and Chemical Engineering, Ningbo University, Ningbo 315211, China
  • Received:2018-03-13 Revised:2018-06-04 Online:2018-11-15 Published:2018-09-10
  • Supported by:
    The work was supported by the National Natural Science Foundation of China (No. 21104036), the Ningbo Natural Science Foundation(No.2018A610113), the Zhejiang Key Technology Innovation Team Sets Up Program (No.211R50001-04),and the Ningbo University Wang Kuancheng Happiness Fund.
Janus粒子是指表面具有两种或两种以上不同化学组成或性质的不对称粒子，目前Janus粒子的制备方法仍在发展中，同时也逐渐形成了Janus粒子在生物医药、催化、材料以及防污等领域功能化应用的研究重点。本文从Janus粒子制备和应用两个方面方法来介绍Janus粒子的研究进展。制备方法主要包括表面选择性修饰法、晶种生长法、微流控法、嵌段共聚物自组装法和电化学沉积法等。应用方面则着重介绍了Janus粒子在生物医药、界面催化、表面活性剂、复合材料、微米马达和防污等方面的功能化应用，并对Janus粒子未来的发展趋势做了展望。
关键词： Janus粒子, 各向异性粒子合成, 不对称性, 功能性粒子
Janus particle refers to particle that possesses two or more sides with different surface chemical compositions or polarities, or is composed of two parts with different geometrical morphologies. With rapid development of the preparation methods of Janus particles, the research attention has been shifted from particles synthesis to applications of the Janus particles in the fields of biomedicine, catalysis, advanced materials and anti-fouling. In this review, research progress of Janus particles is extensively introduced with special focus on functional application of Janus particles. The first part of the review illustrates the progress of synthesizing methods including the selective surface modification, seeded crystallization, microfluidics, self-assembly of block copolymer and electrochemical deposition. The second part gives detailed discussions regarding the applications of Janus particles in biomedicine, interfacial catalyst, surfactants, composite materials, micromotors and anti-fouling. An outlook of Janus particle and its applications in future perspective is also made.
Contents
1 Introduction
2 Synthesis of Janus particles
2.1 Selective surface modification
2.2 Seeded crystallization
2.3 Microfluidic synthesis
2.4 Self-assembly of block copolymer
2.5 Electrochemical deposition
2.6 Other preparation strategies
3 Functional application of Janus particles
3.1 Biomedicine
3.2 Interfacial catalyst
3.3 Surfactant
3.4 Composite material
3.5 Micromotors
3.6 Anti-fouling
4 Conclusion
Key words: Janus particles, synthesis of anisotropic particles, asymmetry, functional particles

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Janus粒子的制备及功能化应用