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化学进展 2018, Vol. 30 Issue (5): 547-563 DOI: 10.7536/PC171251 前一篇   后一篇

• 综述 •

CO2:羧基化反应的C1合成子

张宇, 岑竞鹤, 熊文芳, 戚朝荣, 江焕峰*   

  1. 华南理工大学 化学与化工学院 广东省功能分子工程重点实验室 广州 510640
  • 收稿日期:2018-01-02 修回日期:2018-02-27 出版日期:2018-05-15 发布日期:2018-04-25
  • 通讯作者: 江焕峰e-mail:jianghf@scut.edu.cn E-mail:jianghf@scut.edu.cn
  • 基金资助:
    国家自然科学基金项目（No.2016YFA0602900）资助
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CO2: C1 Synthon in Carboxylation Reactions

Yu Zhang, Jinghe Cen, Wenfang Xiong, Chaorong Qi, Huanfeng Jiang*   

  1. Key Lab of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China
  • Received:2018-01-02 Revised:2018-02-27 Online:2018-05-15 Published:2018-04-25
  • Supported by:
    The work was supported by the National Program on Key Research Project (No.2016YFA0602900) for financial support.
基于资源与环境的考虑，以二氧化碳为原料的有机合成研究近年来日益受到科学家们的关注，其中以二氧化碳为C1合成子参与的过渡金属催化羧基化反应由于可有效构建各种羧酸类化合物及其衍生物，是二氧化碳利用和实现碳循环的理想途径之一。本文综述了催化活化二氧化碳与亲电试剂、烃类C—H键化合物、亲核试剂等通过构建新碳-碳键实现羧基化反应的最新研究进展。
关键词： 二氧化碳, C1合成子, 羧基化, 碳-碳成键, 过渡金属催化
Recently organic synthesis using carbon dioxide as the raw material has attracted considerable attention from scientists because of the resourceful and environmental factors. Especially, transition metal-catalyzed carboxylation reaction is an efficient method to construct carboxylic acids and their derivatives, which is regarded as one of ideal strategies for carbon dioxide utilization and carbon recycle. The recent advances of carboxylation reaction of CO2 with various substrates (electrophiles, hydrocarbons, nucleophiles) are reviewed herein.
Contents
1 Introduction
2 Carboxylation of CO2 with various electrophiles
2.1 Carboxylation of CO2 with halogenated hydrocarbon
2.2 Carboxylation of CO2 with esters or alcohols
2.3 Carboxylation of CO2 with other electrophiles
3 Carboxylation of CO2 with diverse hydrocarbon compounds containing C—H bond
3.1 Carboxylation of CO2 with hydrocarbon containing C(sp)—H bond
3.2 Carboxylation of CO2 with hydrocarbon containing C(sp2)—H bond
3.3 Carboxylation of CO2 with hydrocarbon containing C(sp3)—H bond
4 Carboxylation of CO2 with different nucleophiles
4.1 Carboxylation of CO2 with organoboranes
4.2 Carboxylation of CO2 with organosilanes
5 Conclusion and outlook
Key words: carbon dioxide, C1 synthon, carboxylation, C—C bond formation, transition metal-catalyzed

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摘要

CO2:羧基化反应的C1合成子