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化学进展 2015, Vol. 27 Issue (2/3): 251-266 DOI: 10.7536/PC140914 前一篇   后一篇

• 综述与评论 •

不同种类敏感膜修饰的QCM气体传感器研究现状

王振强1,2, 杨明庆2, 贺军辉*2, 杨巧文1   

  1. 1. 中国矿业大学(北京) 化学与环境工程学院 北京 100083;
    2. 中国科学院理化技术研究所 微纳材料与技术研究中心 功能纳米材料实验室 北京 100190
  • 收稿日期:2014-09-01 修回日期:2014-10-01 出版日期:2015-03-15 发布日期:2014-12-22
  • 通讯作者: 贺军辉 E-mail:jhhe@mail.ipc.ac.cn
  • 基金资助:

    国家自然科学基金项目(No.21271177),国家重点基础研究发展计划(973)项目(No.2010CB934103)和中国科学院理化技术研究所所长基金资助

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Progress of Different Sensing Materials Modified QCM Gas Sensors

Wang Zhenqiang1,2, Yang Mingqing2, He Junhui*2, Yang Qiaowen1   

  1. 1. School of Chemical and Environmental Engineering, China University of Mining and Technology (Beijing), Beijing 100083, China;
    2. Functional Nanomaterials Laboratory, Center for Micro/Nanomaterials and Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
  • Received:2014-09-01 Revised:2014-10-01 Online:2015-03-15 Published:2014-12-22
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21271177), the National Basic Research Program of China (973 Program)(No. 2010CB934103) and the Foundation of Director of Technical Institute of Physics and Chemistry, CAS.

石英晶体微天平(quartz crystal microbalance, QCM)是一种对质量变化敏感的器件,具有灵敏度高、成本低廉、操作简单、可实时在线检测等优点,在气体传感领域受到了广泛关注。敏感材料是石英晶体微天平气体传感器的关键组成部分,本文综述了不同敏感材料包括有机聚合物、超分子化合物、离子液体和分子液体以及近年来备受关注的纳米材料修饰的QCM对特定气体传感检测的研究现状,详细介绍了纳米材料为敏感膜的QCM气体传感器对不同气体传感检测的研究现状及相关敏感机理。最后,在国内外研究现状的基础上,展望了敏感材料的发展前景。QCM作为一种成本低廉、操作方便、测量精度高的气体传感检测器件,将会有更加广阔的应用前景。

关键词： 石英晶体微天平, 气体传感器, 纳米材料

Quartz crystal microbalance (QCM) is a mass-sensitive device, and has been attracting intensive attention in the field of gas sensor because of its many advantages such as high sensitivity, low cost, easy installation and inherent ability to monitor analytes in real time. Sensing material is a key issue for the range of application of QCM sensors. This paper reviews the current research status of sensing materials for specific gases, including polymers, supermolecules, ionic liquids, molecular liquids and nanomaterials. The current status and sensing mechanisms of QCM sensors using nanomaterials as sensing layer are introduced in detail. On the basis of the research status, a prospect is given of sensing materials. As a low-cost, easy operation, high-accuracy gas detection device, QCM would be more widely applied in the future.

Contents
1 Introduction
2 Polymers functionalized QCM sensors
2.1 Humidity detection
2.2 Agent stimulant detection
2.3 VOCs detection
3 Supermolecules functionalized QCM sensors
3.1 Inorganic gas pollutants detection
3.2 VOCs detection
4 Ionic liquids and molecular liquids functionalized QCM sensors
4.1 VOCs detection
4.2 Non-volatility compounds detection
5 Nanomaterials functionalized QCM sensors
5.1 Humidity detection
5.2 Inorganic gas pollutants detection
5.3 VOCs detection
5.4 HCN and agent stimulant detection
6 Conclusion and outlook

Key words: quartz crystal microbalance, gas sensor, nanomaterials

中图分类号: 

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