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化学进展 2014, Vol. 26 Issue (10): 1690-1700 DOI: 10.7536/PC140515 前一篇   后一篇

• 综述与评论 •

电场响应光子晶体

张慧捷1,2, 王世荣1,2, 肖殷1,2, 李祥高*1,2   

  1. 1. 天津大学化工学院 天津 300072;
    2. 天津化学化工协同创新中心 天津 300072
  • 收稿日期:2014-05-01 修回日期:2014-07-01 出版日期:2014-10-15 发布日期:2014-08-12
  • 通讯作者: 李祥高 E-mail:lixianggao@tju.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 21102098）和国家高技术研究发展计划（863）项目（No.2013AA032003）资助

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Electrically Responsive Photonic Crystals

Zhang Huijie1,2, Wang Shirong1,2, Xiao Yin1,2, Li Xianggao*1,2   

  1. 1. School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072;
    2. Collaborative Innovation Center of Chemical Science and Engineering, Tianjin 300072, China
  • Received:2014-05-01 Revised:2014-07-01 Online:2014-10-15 Published:2014-08-12
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No. 21102098) and the National High Technology Research and Development Program of China (863 Program, No. 2013AA032003)

光子晶体是一种介电常数周期变化、具有光子带隙、对光路可控的新型功能材料。将对外界刺激敏感性材料引入光子晶体空隙就得到可响应光子晶体。电场响应光子晶体是由电活性材料与光子晶体结构相结合所得，可以应用于反射型彩色显示并表现出其他显示技术所没有的独特优点。本文重点介绍了电场响应光子晶体器件的结构和响应机理，并按照引入电活性材料的不同将电场响应光子晶体分为基于液晶、聚电解质水凝胶、金属有机聚合物凝胶、导电聚合物以及核壳式电场响应光子晶体，总结了近几年各类电场响应光子晶体的研究进展，提出了在反射型彩色显示器件方面的应用以及存在的问题和展望。

关键词： 可响应光子晶体, 电场响应, 电活性材料, 反射型彩色显示

Photonic crystals are new functional materials with periodic dielectric constants and photonic bandgaps and they can control the transmission of light. Responsive photonic crystals can be prepared by introducing external stimuli -sensitive materials into the interspace of photonic crystals. Electrically responsive photonic crystals are formed by combining electroactive materials with photonic crystal structure. They can be applied to reflective full color display exhibiting unique advantages over other display technologies. In this review, the structure and the responsive mechanism of electrically responsive photonic crystal device are mainly introduced. Besides, according to different kinds of electroactive materials which are introduced into photonic crystals, the electrically responsive photonic crystals can be classified into liquid crystal-based, polyelectrolyte hydrogel-based, organometallic polymer gel-based, conductive polymer-based and core-shell electrically responsive photonic crystals. The development in recent years of all kinds of them are summarized. The application, existing problems and outlook in the field of reflective full color display device are presented.

Contents
1 Introduction
2 Responsive mechanism of responsive photonic crystals
3 Device structure of electrically responsive photonic crystals
3.1 Conductive substrate and electrolyte
3.2 Opal and inverse opal photonic crystal electroactive materials
4 Classification of electrically responsive photonic crystals
4.1 Liquid crystal-based electrically responsive photonic crystals
4.2 Polyelectrolyte hydrogel-based electrically responsive photonic crystals
4.3 Organometallic polymer gel-based electrically responsive photonic crystals
4.4 Conductive polymer-based electrically responsive photonic crystals
4.5 Core-shell electrically responsive photonic crystals
5 Application of electrically responsive photonic crystals
6 Existing problems and outlook

Key words: responsive photonic crystals, electric response, electroactive materials, reflective full color display

中图分类号: 

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摘要

电场响应光子晶体