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化学进展 2014, Vol. 26 Issue (05): 820-833 DOI: 10.7536/PC131145 前一篇   后一篇

• 综述与评论 •

石墨烯及其复合材料在样品前处理中的应用

韩强1,2, 王宗花*2, 张晓琼1, 丁明玉*1   

  1. 1. 清华大学化学系 北京 100084;
    2. 青岛大学纤维新材料与现代纺织实验室 国家重点实验室培育基地 青岛 266071
  • 收稿日期:2013-11-01 修回日期:2013-12-01 出版日期:2014-05-15 发布日期:2014-03-13
  • 通讯作者: 丁明玉，e-mail：dingmy@mail.tsinghua.edu.cn；王宗花，e-mail：wangzonghua@qdu.edu.cn E-mail:dingmy@mail.tsinghua.edu.cn；wangzonghua@qdu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 21075074，21275082，81102411）；青岛市自然科学基金项目（No. 13-1-4-128-jch，13-1-4-202-jch）；山东省自然科学基金项目（No. ZR2011BZ004，ZR2011BQ005）；日本科学促进协会和中国国家自然科学基金中日合作与交流项目（No. 21111140014）；生命分析化学国家重点实验室开放基金（No. SKLACLS1110）及国家重点基础研究发展计划（973）项目（No. 2012CB722705）资助

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Graphene and Its Composites in Sample Preparation

Han Qiang1,2, Wang Zonghua*2, Zhang Xiaoqiong1, Ding Mingyu*1   

  1. 1. Department of Chemistry, Tsinghua University, Beijing 100084, China;
    2. Laboratory of Fiber Materials and Modern Textile, the Growing Base for State Key Laboratory, Qingdao University, Qingdao 266071, China
  • Received:2013-11-01 Revised:2013-12-01 Online:2014-05-15 Published:2014-03-13
  • Supported by:

    The work was supported by the National Natural Science Foundation of China (No.21075074,21275082, 81102411), the Natural Science Foundation of Qingdao (No.13-1-4-128-jch, 13-1-4-202-jch),the Natural Science Foundation of Shandong (No.ZR2011BZ004, ZR2011BQ005), JSPS and NSFC under the Japan-China Scientific Cooperation Program (No. 21111140014), the State Key Laboratory of Analytical Chemistry for Life Science (No. SKLACLS1110) and the National Basic Research Program of China(973 Program, Grant No. 2012CB722705)

样品前处理新技术与方法研究是现代分析化学的重要研究课题与发展方向之一。固相萃取是目前应用最为广泛的样品前处理技术，其技术核心是吸附材料，因此开发新型吸附材料是样品前处理领域的研究热点。石墨烯是一种新型碳纳米材料，由于其良好的物理化学性质，在短短几年内迅速成为众多学科的研究热点。其高比表面积、良好的化学稳定性和热稳定性使之在分离科学领域得到广泛的应用。本文系统综述了石墨烯及其复合材料在样品前处理中的应用研究，主要包括其作为固定相在固相萃取、固相微萃取、磁固相萃取等技术在环境、食品、生物等样品前处理中的应用。

关键词： 石墨烯, 复合材料, 样品前处理, 固相萃取, 固相微萃取, 磁固相萃取

Sample preparation procedure is crucial for the sensitivity, selectivity and accuracy of the quantitative analysis. The exploration and study of new technologies and methods in sample preparation have become important subject and direction in current analytical chemistry owing to its significance. Sorption-based extraction techniques are currently the most widely applied sample preparation techniques. The core component of the sorption-based extraction techniques is adsorbent material, which dominates the selectivity and sensitivity of the method. Therefore, the development of new adsorbent materials is a hot research topic in sample preparation. As a novel class of carbonaceous nanomaterials, graphene has attracted considerable interest in many subjects due to its excellent physical and chemical properties. Remarkably, the superior merits of graphene, for instance, large specific surface area, good thermal and chemical stability, entirely lead to its numerous applications in separation science. This article focuses on the application of graphene and its composites in many sample preparation technologies (including solid-phase extraction, solid-phase microextraction, magnetic solid-phase extraction and other technologies) in order to monitor the trace substances in different matrices (such as environmental, food, biological samples and so on). Finally the existing problem of graphene in sample preparation is summarized, and the possible challenges and future perspectives in this field are also described.

Contents
1 Introduction
2 Graphene and its composites in sample preparation
2.1 Graphene and its composites in solid-phase extraction
2.2 Graphene and its composites in solid-phase microextraction
2.3 Graphene and its composites in magnetic solid-phase extraction
2.4 Graphene and its composites in sample preparation technologies
3 Conclusions and outlook

Key words: graphene, composites, sample preparation, solid-phase extraction, solid-phase microextraction, magnetic solid-phase extraction

中图分类号: 

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