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化学进展 2013, Vol. 25 Issue (12): 2159-2168 DOI: 10.7536/PC130549 前一篇   后一篇

• 综述与评论 •

负载型催化剂用于卤代有机污染物氢解去除

张云飞1, 杨波*1, 张鸿1, 余刚2, 邓述波2, 刘剑洪1   

  1. 1. 深圳大学化学与化工学院 深圳市功能高分子重点实验室 深圳 518060;
    2. 清华大学环境学院持久性有机污染物研究中心 北京 100084
  • 收稿日期:2013-05-01 修回日期:2013-07-01 出版日期:2013-12-15 发布日期:2013-09-17
  • 通讯作者: 杨波 E-mail:boyang@szu.edu.cn
  • 基金资助:

    国家自然科学基金项目（No. 21177089，11275130）和国家高技术研究发展计划（863）项目（No.2013AA062705）资助

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Degradation of Halogenated Organic Contaminants with Hydrodehalogenation Using Supported Catalysts

Zhang Yunfei1, Yang Bo*1, Zhang Hong1, Yu Gang2, Deng Shubo2, Liu Jianhong1   

  1. 1. College of Chemistry and Chemical Engineering, Shenzhen Key Laboratory of Functional Polymers, Shenzhen University, Shenzhen 518060, China;
    2. POPs Research Center, School of Environment, Tsinghua University, Beijing 100084, China
  • Received:2013-05-01 Revised:2013-07-01 Online:2013-12-15 Published:2013-09-17

卤代有机污染物（halogenated organic contaminants，HOCs）具有持久性强、难生物降解的特点，排放到环境后对生态安全及人类健康造成了巨大危害，在环境领域备受关注。负载型催化剂降解HOCs的反应条件温和易行，产物低毒易于降解或可重新作为原材料使用，成为环境污染化学降解技术研究的热点。本文综述了负载型催化剂降解HOCs的种类、反应机理和各种因素的影响机制，介绍了相关研究进展并讨论分析了该技术存在的问题，并提出了该技术的发展前景及今后重点研究方向。

关键词： 负载型催化剂, 有机卤代污染物, 加氢脱卤, 还原降解

Due to their highly persistent and biorefractory property in environment, halogenated organic contaminants (HOCs) possess the potential risk to ecological safety and human health after released into our surroundings so that their problems have attracted much attention in the concerned researches. Reductive hydrodehalogenation (HDH) by supported catalyst provides the practicable approach to decontaminate HOCs with mild reaction conditions, which forms the low toxic products easily for biodegradation or to recycle as chemical raw materials. So it has been in the spotlight of study on chemical treatment method for environment pollution. This paper reviews the degradation categories, HDH reaction pathway of HOCs with supported catalyst as well as the influential mechanisms of various relative factors. It is also introduced for the progress on these studies and further discussions about some remaining problems in the development of the catalytic HDH technology. In addition, the future trends for this method are prospected.

Contents
1 Introduction
2 The categories and mechanisms of HOC degradation using supported catalyst
3 Influencing factors on catalytic dehalogenation
3.1 Effect of the materials used for supported catalyst
3.2 Effect of preparation techniques for support catalyst
3.3 Effect of HOC categories
3.4 Effect of solvents
3.5 Effect of pH
3.6 Effect of other relative factors
3.7 Deactivation of supported catalyst
4 Conclusions and prospect

Key words: supported catalysts, halogenated organic contaminants (HOCs), hydrodehalogenation(HDH), reductive degradation

中图分类号: 

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