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化学进展 2013, Vol. 25 Issue (12): 2169-2177 DOI: 10.7536/PC130432 前一篇   后一篇

• 综述与评论 •

天然有机质介导的汞生物地球化学循环：结合作用与分子转化

阴永光1, 李雁宾2, 马旭1, 刘景富*1, 江桂斌1   

  1. 1. 中国科学院生态环境研究中心 环境化学与生态毒理学国家重点实验室 北京 100085;
    2. 中国海洋大学 化学化工学院 青岛 266100
  • 收稿日期:2013-04-01 修回日期:2013-06-01 出版日期:2013-12-15 发布日期:2013-09-17
  • 通讯作者: 刘景富 E-mail:jfliu@rcees.ac.cn
  • 基金资助:

    国家重点基础研究发展计划（973）项目（No. 2013CB430002）和国家自然科学基金项目 （No. 21120102040，20937002，21025729）资助

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导出 被引次数 ( 9 )

Role of Natural Organic Matter in the Biogeochemical Cycle of Mercury：Binding and Molecular Transformation

Yin Yongguang1, Li Yanbin2, Ma Xu1, Liu Jingfu*1, Jiang Guibin1   

  1. 1. State Key Laboratory of Environmental Chemistry and Ecotoxicology, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China;
    2. College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China
  • Received:2013-04-01 Revised:2013-06-01 Online:2013-12-15 Published:2013-09-17

汞具有持久性、生物积累性及长距离传输特性，是一类重要的全球污染物。在陆地、湖泊、海洋等环境中，天然有机质是汞的重要络合配体，对汞的生物地球化学循环有重要作用，可显著影响汞的迁移、分布、生物累积与毒性。此外，天然有机质在硫化汞的分散及汞的分子转化如还原、氧化、甲基化、甲基汞的去甲基化中起着至关重要的作用。本文对天然有机质与汞的结合与分子转化的研究进展进行了总结，并提出了后续研究的重点。

关键词： 汞, 甲基汞, 天然有机质, 生物可给性, 生物地球化学循环, 甲基化, 去甲基化

Mercury is an important global pollutant, with the characteristics of persistence, bioaccumulation and long-distance transport. In the terrestrial, lakes and marine environment, natural organic matter (NOM) is important binding ligand for divalent inorganic mercury and methylmercury, which plays important roles in the biogeochemical cycling of mercury, including migration, distribution, bioaccumulation and toxicity. In addition, NOM plays crucial roles in the dispersion of HgS and molecular transformation of mercury and methylmercury, including reduction, oxidation, methylation of inorganic mercury and de-methylation of methylmercury. The research progress on the binding of mercury with NOM and its roles in the transformation of mercury is reviewed and future prospects in this field are discussed.

Contents
1 Introduction
2 Natural organic matter
3 Binding of Hg2+ and MeHg with natural organic matter
4 Molecular transformation of Hg mediated by natural organic matter
4.1 Reduction of Hg2+ mediated by natural organic matter
4.2 Oxidation of Hg0 mediated by natural organic matter
4.3 Methylation of inorganic Hg mediated by natural organic matter
4.4 Photo-demethylation of MeHg mediated by natural organic matter
5 Dispersion of HgS by natural organic matter
6 Conclusions and outlook

Key words: mercury, methylmercury, natural organic matter, bioavailability, biogeochemical cycle, methylation, demethylation

中图分类号: 

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[1] Boening D W. Chemosphere, 2000, 40 (12): 1335—1351
[2] Lindqvist O, Rodhe H. Tellus B, 1985, 37 (3): 136—159
[3] Ebinghaus R, Kock H H, Temme C, Einax J W, Lowe A G, Richter A, Burrows J P, Schroeder W H. Environ. Sci. Technol., 2002, 36 (6): 1238—1244
[4] Schroeder W H, Anlauf K G, Barrie L A, Lu J Y, Steffen A, Schneeberger D R, Berg T. Nature, 1998, 394 (6691): 331—332
[5] Zhang Q, Huang J, Wang F, Mark L, Xu J, Armstrong D, Li C, Zhang Y, Kang S. Environ. Sci. Technol., 2012, 46 (10): 5404—5413
[6] Watras C J, Back R C, Halvorsen S, Hudson R J M, Morrison K A, Wente S P. Sci. Total Environ., 1998, 219 (2/3): 183—208
[7] Poissant L, Dommergue A, Ferrari C P. J. Phys. IV, 2002, 12 (10): 143—160
[8] Pacyna E G, Pacyna J M, Steenhuisen F, Wilson S. Atmos. Environ., 2006, 40 (22): 4048—4063
[9] Gilmour C C, Henry E A, Mitchell R. Environ. Sci. Technol., 1992, 26 (11): 2281—2287
[10] Fleming E J, Mack E E, Green P G, Nelson D C. Appl. Environ. Microb., 2006, 72 (1): 457—464
[11] 吴丰昌(Wu F C), 王立英(Wang L Y), 黎文(Li W), 张润宇(Zhang R Y), 傅平青(Fu P Q), 廖海清(Liao H Q), 白英臣(Bai Y C), 郭建阳(Guo J Y), 王静(Wang J). 湖泊科学(Lake Science), 2008, 20 (1): 1—12
[12] Ghabbour E, Davies G. Humic Substances: Nature's Most Versatile Materials. Taylor & Francis, 2003
[13] Kalbitz K, Solinger S, Park J H, Michalzik B, Matzner E. Soil Sci., 2000, 165 (4): 277—304
[14] Jones M N, Bryan N D. Adv. Colloid Interface Sci., 1998, 78 (1): 1—48
[15] Borch T, Kretzschmar R, Kappler A, Van Cappellen P, Ginder-Vogel M, Voegelin A, Campbell K. Environ. Sci. Technol., 2010, 44 (1): 15—23
[16] 邰超(Tai C), 李雁宾(Li Y B), 阴永光(Yin Y G), 蔡勇(Cai Y), 江桂斌(Jiang G B). 化学进展(Progress in Chemistry), 2012, 24 (7): 1388—1397
[17] Gasper J D, Aiken G R, Ryan J N. Appl. Geochem., 2007, 22 (8): 1583—1597
[18] Khwaja A R, Bloom P R, Brezonik P L. Environ. Sci. Technol., 2006, 40 (3): 844—849
[19] Dong W, Bian Y, Liang L, Gu B. Environ. Sci. Technol., 2011, 45 (8): 3576—3583
[20] Haitzer M, Aiken G R, Ryan J N. Environ. Sci. Technol., 2003, 37 (11): 2436—2441
[21] Hintelmann H, Welbourn P M, Evans R D. Water Air Soil Poll., 1995, 80 (1/4): 1031—1034
[22] Khwaja A R, Bloom P R, Brezonik P L. Environ. Sci. Technol., 2010, 44 (16): 6151—6156
[23] Karlsson T, Skyllberg U. Environ. Sci. Technol., 2003, 37 (21): 4912—4918
[24] Gismera M J, Procopio J R, Sevilla M T. Electroanalysis, 2007, 19 (10): 1055—1061
[25] do Nascimento F H, Masini J C. Talanta, 2012, 100: 57—63
[26] Han S H, Gill G A, Lehman R D, Choe K Y. Mar. Chem., 2006, 98 (2/4): 156—166
[27] Benoit J M, Mason R P, Gilmour C C, Aiken G R. Geochim. Cosmochim. Acta, 2001, 65 (24): 4445—4451
[28] Lamborg C H, Tseng C M, Fitzgerald W F, Balcom P H, Hammerschmidt C R. Environ. Sci. Technol., 2003, 37 (15): 3316—3322
[29] Lu X Q, Jaffe R. Water Res., 2001, 35 (7): 1793—1803
[30] Hintelmann H, Welbourn P M, Evans R D. Environ. Sci. Technol., 1997, 31 (2): 489—495
[31] Bai Y C, Wu F C, Liu C Q, Li W, Guo J Y, Fu P Q, Xing B S, Zheng J. Anal. Chim. Acta, 2008, 616 (1): 115—121
[32] Tipping E. Appl. Geochem., 2007, 22 (8): 1624—1635
[33] Amirbahman A, Reid A L, Haines T A, Kahl J S, Arnold C. Environ. Sci. Technol., 2002, 36 (4): 690—695
[34] Reddy M M, Aiken G R. Water Air Soil Poll., 2001, 132 (1): 89—104
[35] Miller C L, Southworth G, Brooks S, Liang L, Gu B. Environ. Sci. Technol., 2009, 43 (22): 8548—8553
[36] Haitzer M, Aiken G R, Ryan J N. Environ. Sci. Technol., 2002, 36 (16): 3564—3570
[37] Drexel R T, Haitzer M, Ryan J N, Aiken G R, Nagy K L. Environ. Sci. Technol., 2002, 36 (19): 4058—4064
[38] Hesterberg D, Chou J W, Hutchison K J, Sayers D E. Environ. Sci. Technol., 2001, 35 (13): 2741—2745
[39] Qian J, Skyllberg U, Frech W, Bleam W F, Bloom P R, Petit P E. Geochim. Cosmochim. Acta, 2002, 66 (22): 3873—3885
[40] Yoon S J, Diener L M, Bloom P R, Nater E A, Bleam W F. Geochim. Cosmochim. Acta, 2005, 69 (5): 1111—1121
[41] Yin Y J, Allen H E, Huang C P, Sparks D L, Sanders P F. Environ. Sci. Technol., 1997, 31 (2): 496—503
[42] Schuster E. Water Air Soil Poll., 1991, 56: 667—680
[43] Lee S S, Nagy K L, Park C, Fenter P. Environ. Sci. Technol., 2009, 43 (14): 5295—5300
[44] Backstrom M, Dario M, Karlsson S, Allard B. Sci. Total Environ., 2003, 304 (1/3): 257—268
[45] Liang P, Li Y C, Zhang C, Wu S C, Cui H J, Yu S, Wong M H. J. Hazard. Mater., 2013, 244: 322—328
[46] Turner A, Millward G E, Le Roux S M. Environ. Sci. Technol., 2001, 35 (23): 4648—4654
[47] Bengtsson G, Picado F. Chemosphere, 2008, 73 (4): 526—531
[48] Lindberg S E, Harriss R C. Environ. Sci. Technol., 1974, 8 (5): 459—462
[49] Aiken G R, Gilmour C C, Krabbenhoft D P, Orem W. Crit. Rev. Environ. Sci. Technol., 2011, 41: 217—248
[50] Grigal D F. J. Environ. Qual., 2003, 32 (2): 393—405
[51] Hu K L, Zhang F R, Hong L, Feng H, Li B G. Pedosphere, 2006, 16 (6): 690—698
[52] Gagnon C, Pelletier E, Mucci A. Mar. Chem., 1997, 59 (1/2): 159—176
[53] Schuster P F, Shanley J B, Marvin-Dipasquale M, Reddy M M, Aiken G R, Roth D A, Taylor H E, Krabbenhoft D P, DeWild J F. Water Air Soil Poll., 2008, 187 (1/4): 89—108
[54] Brigham M E, Wentz D A, Aiken G R, Krabbenhoft D P. Environ. Sci. Technol., 2009, 43 (8): 2720—2725
[55] Schuster P F, Striegl R G, Aiken G R, Krabbenhoft D P, Dewild J F, Butler K, Kamark B, Dornblaser M. Environ. Sci. Technol., 2011, 45 (21): 9262—9267
[56] Hill J R, O'Driscoll N J, Lean D R S. Sci. Total Environ., 2009, 408 (2): 408—414
[57] Dittman J A, Shanley J B, Driscoll C T, Aiken G R, Chalmers A T, Towse J E. Environ. Pollut., 2009, 157 (6): 1953—1956
[58] Bergamaschi B A, Krabbenhoft D P, Aiken G R, Patino E, Rumbold D G, Orem W H. Environ. Sci. Technol., 2012, 46 (3): 1371—1378
[59] Henneberry Y K, Kraus T E C, Fleck J A, Krabbenhoft D P, Bachand P M, Horwath W R. Sci. Total Environ., 2011, 409 (3): 631—637
[60] Zhong H, Wang W X. Environ. Sci. Technol., 2009, 43 (23): 8998—9003
[61] Sjoblom A, Meili M, Sundbom M. Sci. Total Environ., 2000, 261 (1—3): 115—124
[62] Gorski P R, Armstrong D E, Hurley J P, Krabbenhoft D P. Environ. Pollut., 2008, 154 (1): 116—123
[63] Pickhardt P C, Fisher N S. Environ. Sci. Technol., 2007, 41 (1): 125—131
[64] Vigneault B, Percot A, Lafleur M, Campbell P G C. Environ. Sci. Technol., 2000, 34 (18): 3907—3913
[65] Jonsson S, Skyllberg U, Nilsson M B, Westlund P-O, Shchukarev A, Lundberg E, Bjoern E. Environ. Sci. Technol., 2012, 46 (21): 11653—11659
[66] Hammerschmidt C R, Fitzgerald W F. Environ. Sci. Technol., 2004, 38 (5): 1487—1495
[67] Hammerschmidt C R, Fitzgerald W F, Balcom P H, Visscher P T. Mar. Chem., 2008, 109 (1/2): 165—182
[68] Schartup A T, Mason R P, Balcom P H, Hollweg T A, Chen C Y. Environ. Sci. Technol., 2013, 47 (2): 695—700
[69] Tsui M T K, Finlay J C. Environ. Sci. Technol., 2011, 45 (14): 5981—5987
[70] Luengen A C, Fisher N S, Bergamaschi B A. Environ. Toxicol. Chem., 2012, 31 (8): 1712—1719
[71] Ndu U, Mason R P, Zhang H, Lin S, Visscher P T. Appl. Environ. Microb., 2012, 78 (20): 7276—7282
[72] Wang R, Wang W X. Environ. Sci. Technol., 2010, 44 (20): 7964—7969
[73] Alberts J J, Takacs M, Pattanayek M. Acta Hydrochim. Hydrob., 2001, 28 (7): 428—435
[74] Klinck J, Dunbar M, Brown S, Nichols J, Winter A, Hughes C, Playle R C. Aquat. Toxicol., 2005, 72 (1/2): 161—175
[75] Gorski P R, Armstrong D E, Hurley J P, Shafer M M. Environ. Toxicol. Chem., 2006, 25 (2): 534—540
[76] Mason R P, Morel F M M, Hemond H F. Water Air Soil Poll., 1995, 80 (1/4): 775—787
[77] Poulain A J, Amyot M, Findlay D, Telor S, Barkay T, Hintelmann H. Limnol. Oceanogr., 2004, 49 (6): 2265—2275
[78] Alberts J J, Schindler J E, Miller R W, Nutter D E. Science, 1974, 184 (4139): 895—896
[79] Tseng C M, Lamborg C, Fitzgerald W F, Engstrom D R. Geochim. Cosmochim. Acta, 2004, 68 (6): 1173—1184
[80] O'Driscoll N J, Lean D R S, Loseto L L, Carignan R, Siciliano S D. Environ. Sci. Technol., 2004, 38 (9): 2664—2672
[81] Fantozzi L, Ferrara R, Frontini F P, Dini F. Mar. Chem., 2007, 107 (1): 4—12
[82] Feng X B, Yan H Y, Wang S F, Qiu G L, Tang S L, Shang L H, Dai Q J, Hou Y M. Atmos. Environ., 2004, 38 (28): 4721—4732
[83] Mauclair C, Layshock J, Carpi A. Appl. Geochem., 2008, 23 (3): 594—601
[84] Zhang Y, Chen X, Yang Y, Wang D, Liu X. J. Environ. Sci. China, 2011, 23 (6): 912—917
[85] Amyot M, Mierle G, Lean D, McQueen D J. Geochim. Cosmochim. Acta, 1997, 61 (5): 975—987
[86] Garcia E, Amyot M, Ariya P A. Geochim. Cosmochim. Acta, 2005, 69 (8): 1917—1924
[87] Allard B, Arsenie I. Water Air Soil Poll., 1991, 56: 457—464
[88] Matthiessen A. Sci. Total Environ., 1998, 213 (1/3): 177—183
[89] Deng L, Deng N, Mou L, Zhu F. J. Environ. Sci. China, 2010, 22 (1): 76—83
[90] O'Driscoll N J, Siciliano S D, Peak D, Carignan R, Lean D R S. Sci. Total Environ., 2006, 366 (2/3): 880—893
[91] Rocha J C, Sargentini E, Zara L F, Rosa A H, dos Santos A, Burba P. Talanta, 2003, 61 (5): 699—707
[92] Si L, Ariya P A. Chemosphere, 2011, 84 (8): 1079—1084
[93] Berkovic A M, Bertolotti S G, Villata L S, Gonzalez M C, Pis Diez R, Martire D O. Chemosphere, 2012, 89 (10): 1189—1194
[94] He F, Zheng W, Liang L, Gu B. Sci. Total Environ., 2012, 416: 429—435
[95] Zheng W, Hintelmann H. J. Phys. Chem. A, 2010, 114 (12): 4246—4253
[96] Zheng W, Hintelmann H. Geochim. Cosmochim. Acta, 2009, 73 (22): 6704—6715
[97] Lalonde J D, Amyot M, Orvoine J, Morel F M M, Auclair J C, Ariya P A. Environ. Sci. Technol., 2004, 38 (2): 508—514
[98] Lalonde J D, Amyot M, Kraepiel A M L, Morel F M M. Environ. Sci. Technol., 2001, 35 (7): 1367—1372
[99] Garcia E, Poulain A J, Amyot M, Ariya P A. Chemosphere, 2005, 59 (7): 977—981
[100] Struyk Z, Sposito G. Geoderma, 2001, 102 (3/4): 329—346
[101] Gu B, Bian Y, Miller C L, Dong W, Jiang X, Liang L. P. Natl. Acad. Sci. U. S. A., 2011, 108 (4): 1479—1483
[102] Zheng W, Liang L, Gu B. Environ. Sci. Technol., 2012, 46 (1): 292—299
[103] Bouffard A, Amyot M. Chemosphere, 2009, 74 (8): 1098—1103
[104] Weber J H. Chemosphere, 1993, 26 (11): 2063—2077
[105] Falter R. Chemosphere, 1999, 39 (7): 1051—1073
[106] Falter R. Chemosphere, 1999, 39 (7): 1075—1091
[107] Bloom N S, Colman J A, Barber L. Fresenius J. Anal. Chem., 1997, 358 (3): 371—377
[108] Nagase H, Ose Y, Sato T, Ishikawa T. Sci. Total Environ., 1982, 25 (2): 133—142
[109] Nagase H, Ose Y, Sato T, Ishikawa T. Sci. Total Environ., 1984, 32 (2): 147—156
[110] Weber J H, Reisinger K, Stoeppler M. Environ. Technol. Lett., 1985, 6 (5): 203—208
[111] Lee Y H, Hultberg H, Andersson I. Water Air Soil Poll., 1985, 25 (4): 391—400
[112] Siciliano S D, O'Driscoll N J, Tordon R, Hill J, Beauchamp S, Lean D R S. Environ. Sci. Technol., 2005, 39 (4): 1071—1077
[113] Guevara S R, Queimalinos C P, Dieguez M d C, Arribere M. Chemosphere, 2008, 72 (4): 578—585
[114] Lehnherr I, St Louis V L, Hintelmann H, Kirk J L. Nat. Geosci., 2011, 4 (5): 298—302
[115] Li Y, Yin Y, Liu G, Tachiev G, Roelant D, Jiang G, Cai Y. Environ. Sci. Technol., 2012, 46 (11): 5885—5893
[116] Li Y, Mao Y, Liu G, Tachiev G, Roelant D, Feng X, Cai Y. Environ. Sci. Technol., 2010, 44 (17): 6661—6666
[117] Sellers P, Kelly C A, Rudd J W M, MacHutchon A R. Nature, 1996, 380 (6576): 694—697
[118] Hammerschmidt C R, Fitzgerald W F. Environ. Sci. Technol., 2006, 40 (4): 1212—1216
[119] Hammerschmidt C R, Fitzgerald W F. Environ. Sci. Technol., 2010, 44 (16): 6138—6143
[120] Lehnherr I, Louis V L S. Environ. Sci. Technol., 2009, 43 (15): 5692—5698
[121] Suda I, Suda M, Hirayama K. Arch. Toxicol., 1993, 67 (5): 365—368
[122] Yin Y, Chen B, Mao Y, Thanh W, Liu J, Cai Y, Jiang G. Chemosphere, 2012, 88 (1): 8—16
[123] Zhang T, Hsu-Kim H. Nat. Geosci., 2010, 3 (7): 473—476
[124] Black F J, Poulin B A, Flegal A R. Geochim. Cosmochim. Acta, 2012, 84: 492—507
[125] Bergquist B A, Blum J D. Science, 2007, 318 (5849): 417—420
[126] Malinovsky D, Latruwe K, Moens L, Vanhaecke F. J. Anal. Atom. Spectrom., 2010, 25 (7): 950—956
[127] Wolfenden S, Charnock J M, Hilton J, Livens F R, Vaughan D J. Environ. Sci. Technol., 2005, 39 (17): 6644—6648
[128] Aiken G R, Hsu-Kim H, Ryan J N. Environ. Sci. Technol., 2011, 45 (8): 3196—3201
[129] Ravichandran M, Aiken G R, Ryan J N, Reddy M M. Environ. Sci. Technol., 1999, 33 (9): 1418—1423
[130] Gerbig C A, Kim C S, Stegemeier J P, Ryan J N, Aiken G R. Environ. Sci. Technol., 2011, 45 (21): 9180—9187
[131] Deonarine A, Hsu-Kim H. Environ. Sci. Technol., 2009, 43 (7): 2368—2373
[132] Ravichandran M, Aiken G R, Reddy M M, Ryan J N. Environ. Sci. Technol., 1998, 32 (21): 3305—3311
[133] Waples J S, Nagy K L, Aiken G R, Ryan J N. Geochim. Cosmochim. Acta, 2005, 69 (6): 1575—1588
[134] Graham A M, Aiken G R, Gilmour C C. Environ. Sci. Technol., 2012, 46 (5): 2715—2723
[135] Zhang T, Kim B, Leyard C, Reinsch B C, Lowry G V, Deshusses M A, Hsu-Kim H. Environ. Sci. Technol., 2012, 46 (13): 6950—6958
[136] Latch D E, McNeill K. Science, 2006, 311(5768): 1743—1747
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