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化学进展 2013, Vol. 25 Issue (07): 1158-1165 DOI: 10.7536/PC121158 前一篇   后一篇

• 综述与评论 •

四氢呋喃的氧化

王猛, 惠永海, 张雪华, 魏雅娜, 史岷山, 王吉德*   

  1. 新疆大学 石油天然气精细化学品教育部重点实验室 乌鲁木齐 830046
  • 收稿日期:2012-11-01 修回日期:2013-01-01 出版日期:2013-07-25 发布日期:2013-04-16
  • 通讯作者: 王吉德 E-mail:awangjd@sina.cn
  • 基金资助:

    国家自然科学基金项目(No.20961010, 21162027)和新疆大学石油天然气精细化工重点实验室开放课题基金项目(No.XJDX0908-2010-03)资助

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Oxidation of Tetrahydrofuran

Wang Meng, Hui Yonghai, Zhang Xuehua, Wei Yana, Shi Minshan, Wang Jide*   

  1. Key Lab of Oil & Gas Fine Chemicals, Ministry of Education, Xinjiang University, Urumqi 830046, China
  • Received:2012-11-01 Revised:2013-01-01 Online:2013-07-25 Published:2013-04-16

四氢呋喃的氧化是一类重要的有机氧化反应,有关四氢呋喃的氧化研究将对其他有机物α位C-H的选择性活化提供借鉴和理论依据,同时四氢呋喃是一类重要的有机化工原料及精细化工原料,因此,四氢呋喃氧化反应的研究对有机合成和工业生产应用都有重要的意义。本文就近年来四氢呋喃氧化的研究进行了阐述,重点介绍了以氧气和过氧化氢为氧源催化氧化四氢呋喃的研究,概述了电化学方法以及其他方法在催化氧化四氢呋喃方面的研究进展,对一些重要的催化氧化方法可能的反应机理进行了讨论,并依据近年来有关四氢呋喃氧化研究的发展趋势,对今后的研究热点进行了展望。

关键词： 四氢呋喃, 催化氧化, 氧气, C-H选择性氧化, &gamma, -丁内酯

The oxidation of tetrahydrofuran is an important organic oxidation reaction, the studies of the oxidation of tetrahydrofuran would provide the references and theoretical basis of the α C-H selective activation to other organic matters. Tetrahydrofuran is also a kind of organic chemical raw materials and fine chemical raw materials, therefore the study of tetrahydrofuran oxidation is of very important significance in the field of organic synthesis and industrial production applications. In this paper, the recent progress on the oxidation of tetrahydrofuran is reviewed and the catalytic oxidations of tetrahydrofuran by dioxygen and hydrogen peroxide are introduced with emphasis. Electrochemical oxidation of tetrahydrofuran and several other catalytic oxidation methods of tetrahydrofuran are also summarized. Furthermore, the possible oxidation mechanisms of some important reactions are discussed. Based on the development trends related to the oxidation of tetrahydrofuran in recent years, the hotspots of future research are proposed. Contents
1 Introduction
2 Oxidation of tetrahydrofuran
2.1 Catalytic oxidation of tetrahydrofuran by oxygen
2.2 Catalytic oxidation of tetrahydrofuran by hydrogen peroxide
2.3 Catalytic oxidation of tetrahydrofuran by bromate
2.4 Oxidation of tetrahydrofuran by electrochemical methods
3 Conclusion and outlook

Key words: tetrahydrofuran, catalytic oxidation, oxygen, &, alpha, C-H selective oxidation, &gamma, -butyrolactone

中图分类号: 

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摘要

四氢呋喃的氧化